Fabrication of PANI-modified PVDF nanofibrous yarn for pH sensor

In recent years, with the rise of an intelligent concept, oral and maxillofacial surgery smart dressing had also attracted the interest of researchers, especially for the pH sensor with flexible medium. In this study, polyvinylidene fluoride (PVDF) nanofibrous yarn was fabricated by a conjugate electrospinning process and modified with in situ polymerization of polyaniline (PANI) forming a PANI/PVDF yarn. By a weaving process, these yarns could be weaved into a fabric. It was found that both the PANI/PVDF yarn and the fabric showed a sensitivity to pH, about −48.53 mV per pH for yarn and −38.4 mVper pH for fabric, respectively, in the pH range of 4.0–8.0. These results indicated that the prepared PANI-modified PVDF yarn and fabric might have a potential application in intelligent oral and maxillofacial surgery dressings for monitoring wound healing.

Fabrication of flexible SiO2 nanofibrous yarn via a conjugate electrospinning process

Nowadays, different kinds of polymers, including ceramics, are electrospun into fibrous materials with different structures by electrospinning. Generally, the as-spun ceramic fibers are randomly oriented membranes and brittle without flexibility. Here, we report the fabrication of flexible SiO2 electrospun yarns using poly(vinyl alcohol) (PVA) as a template through a conjugate electrospinning process and calcination. It was found that the calcined as-spun fibers and yarns are obviously thinned with PVA component removal. Fourier transform infrared spectroscopy and energy-dispersive spectroscopy examinations suggested that the obtained yarn after calcination was SiO2 yarn. The SiO2 yarn showed good flexibility without cracking after 180° bending. The flexible ceramic yarn may have potential application in functional textiles.

All-organic, conductive and biodegradable yarns from core–shell nanofibers through electrospinning

A nanofibrous yarn that changes the electrical resistance instantaneously with the strain for multiple stretch and recovery cycles.

The fabrication and characterization of casein/PEO nanofibrous yarn via electrospinning

Casein, a natural protein, has been used as a biopolymer-based resource for producing fiber. This fiber provides high comfort properties with a pH close to human skin. This study focused on evaluating the production feasibility of casein nanofiber twisted yarn with the highest protein content in the hybrid yarn, obtaining suitable spinning conditions and desirable properties of the produced yarn. The desirable yarn achieved by composing 90% casein and 10% polyethylene oxide. The yarn strengthened using several types of cross-linking methods and the best technique was obtained to spin an optimized engineered yarn. Consequently, the biodegrading test conducted on the optimized yarn (90% casein and 10% polyethylene oxide blend) in the presence of 40% di-isocyanate as strengthener additive. Observations showed that after ten days, the sample mostly degraded in the solvent and its strength massively reduced so it could be considered as an environmentally friendly, biodegradable fiber.