Phase Change Energy Storage Elastic Fiber: A Simple Route to Personal Thermal Management

A novel thermoplastic polyurethane (TPU) PCFs possessing a high loaded ratio and high elasticity was simply prepared by vacuum absorption following wet spinning, then coated by waterborne polyurethane (WPU). Octadecane (OCC), hexadecanol (HEO), and stearic acid (SA), which have different tendencies to form hydrogen bonds with TPU, were selected as PCMs, and their thermal behavior, thermal storge properties, and elasticity were systematically studied, respectively. The hierarchical pore structure though from the sheath to the core part of TPU filaments weakened the influence of the nonfreezing layer and hydrogen bond on the crystallization behavior of PCMs. The resulting HEO/TPU fiber has the highest enthalpy of 208.1 J/g compared with OCC and SA. Moreover, the HEO/TPU fiber has an elongation at break of 354.8% when the phase change enthalpy is as high as 177.8 J/g and the phase change enthalpy is still 174.5 J/g after fifty cycles. After ten tensile recovery cycles, the elastic recovery rate of HEO/TPU fiber was only 71.3%. When the HEO in the fiber was liquid state, the elastic recovery rate of HEO/TPU fiber promoted to 91.6%. This elastic PCFs have excellent thermal cycle stability, elastic recovery, and temperature sensitivity. It has great application potential in the fields of flexible wearable devices, intelligent fabrics, and temperature sensors.

Infill Designs for 3D-Printed Shape-Memory Objects

Shape-memory polymers (SMPs) can be deformed, cooled down, keeping their new shape for a long time, and recovered into their original shape after being heated above the glass or melting temperature again. Some SMPs, such as poly(lactic acid) (PLA), can be 3D printed, enabling a combination of 3D-printed shapes and 2D-printed, 3D-deformed ones. While deformation at high temperatures can be used, e.g., to fit orthoses to patients, SMPs used in protective equipment, bumpers, etc., are deformed at low temperatures, possibly causing irreversible breaks. Here, we compare different typical infill patterns, offered by common slicing software, with self-designed infill structures. Three-point bending tests were performed until maximum deflection as well as until the maximum force was reached, and then the samples were recovered in a warm water bath and tested again. The results show a severe influence of the infill pattern as well as the printing orientation on the amount of broken bonds and thus the mechanical properties after up to ten test/recovery cycles.