As various information technologies are penetrating everyday life, private and business matters inevitably mingle. Separating private and business past records, public information, actions or identities may, however, be crucial for an employee in certain situations. In this chapter we review the interrelated areas of employee privacy, and analyze in detail two areas of special importance from the viewpoint of the separation: web and social network privacy. In relation to these areas we discuss threats and solutions in parallel, and besides surveying the relevant literature, we also present current Privacy Enhancing Technologies applicable in each area. Additionally, we briefly review other means of workplace surveillance, providing some insight into the world of smartphones, where we expect the rise of new privacy-protecting technologies as these devices are getting capable of taking over the functions of personal computers.