scholarly journals Black Carbon and Thermally Altered (Pyrogenic) Organic Matter: Chemical Characteristics and the Role in the Environment

Author(s):  
H. Knicker
2021 ◽  
Author(s):  
Emily Graham ◽  
Hyun-Seob Song ◽  
Samantha Grieger ◽  
Vanessa Garayburu-Caruso ◽  
James Stegen ◽  
...  

<p>Wildfires are increasing in frequency, severity, and area burned in response to pervasive hotter and drier conditions, creating a multitude of negative consequences for aquatic ecosystems. Pyrogenic materials generated by wildfires are transported across terrestrial landscapes into inland waters, where approximately 10% of organic matter pools is comprised of black carbon. While recent work suggests pyrogenic organic matter (PyOM) is more bioavailable than indicated by traditional paradigms, the heterogeneity of PyOM pools generated through various feedstocks and combustion scenarios complicates our efforts to understand its bioavailability. Here, we use a mathematical model to predict the energy content, metabolic efficiency, and rate of aerobic decomposition of representative PyOM compounds. We compare these metrics to model outputs derived from measured natural organic matter in global surface waters and sediments to assess differences in bioavailability. We find that PyOM generally has a similar range of bioavailabilities to that of natural systems. However, phenols and black carbon (defined as highly condensed molecules with high solubility) have lower metabolic efficiency than most representative PyOM classes and natural organic matter pools, denoted by higher lambda and lower carbon use efficiency. Rates of aerobic metabolism of phenols and black carbon are also less negatively impacted by oxygen limitation than any other group. Overall, our work suggests that PyOM may be more bioavailable than previously thought and could be an unrecognized contributor to global C emissions as the prevalence of wildfires increases.</p>


Chemosphere ◽  
2021 ◽  
Vol 271 ◽  
pp. 129824
Author(s):  
Youhei Yamashita ◽  
Daiki Kojima ◽  
Natsumi Yoshida ◽  
Hideaki Shibata

2014 ◽  
Vol 20 (5) ◽  
pp. 1629-1642 ◽  
Author(s):  
Nimisha Singh ◽  
Samuel Abiven ◽  
Bernardo Maestrini ◽  
Jeffrey A. Bird ◽  
Margaret S. Torn ◽  
...  

2016 ◽  
Vol 869 ◽  
pp. 112-115 ◽  
Author(s):  
Francisca Pereira de Araújo ◽  
Edson Cavalcanti Silva Filho ◽  
João Sammy Nery de Souza ◽  
Josy Anteveli Osajima ◽  
Marcelo Barbosa Furtini

Soil-cement bricks are good examples of environmentally friendly products. This brick is the combination of soil with compacted cement with no combustion in its production. In this work the physical chemical characteristics of the soil from Piaui for producing this material were investigated. Samples of the soil were collected in three potteries from the county of Bom Jesus and pH analysis were carried out, as well as the rate of organic matter, texture, particle density, limits of liquidity and plasticity rates. The results have shown that the soils have acid tones (pH 5,49 a 6,11), which can be neutralized by adding cement, and organic matter percentages up to 1%. The samples have shown predominantly clay-rich textures with adequate plasticity limits, however, values of liquidity limits and particle density above recommended. Altogether, these soils tend to present viability concerning soil-cement brick production, provided that corrections with additives are made in order to minimize this effect.


2009 ◽  
Vol 43 (13) ◽  
pp. 4973-4978 ◽  
Author(s):  
Yuping Qiu ◽  
Xiaoyu Xiao ◽  
Haiyan Cheng ◽  
Zunlong Zhou ◽  
G. Daniel Sheng

2019 ◽  
Vol 241 ◽  
pp. 558-566 ◽  
Author(s):  
Cecilia María Armas-Herrera ◽  
Fernando Pérez-Lambán ◽  
David Badía-Villas ◽  
José Luis Peña-Monné ◽  
José Antonio González-Pérez ◽  
...  

2012 ◽  
Vol 25 (1) ◽  
pp. 11-18 ◽  
Author(s):  
Juliana Vanir De Souza Carvalho ◽  
Eduardo De Sá Mendonça ◽  
Newton La Scala ◽  
César Reis ◽  
Efrain Lázaro Reis ◽  
...  

AbstractPolar Regions are the most important soil carbon reservoirs on Earth. Monitoring soil carbon storage in a changing global climate context may indicate possible effects of climate change on terrestrial environments. In this regard, we need to understand the dynamics of soil organic matter in relation to its chemical characteristics. We evaluated the influence of chemical characteristics of humic substances on the process of soil organic matter mineralization in selected Maritime Antarctic soils. A laboratory assay was carried out with soils from five locations from King George Island. We determined the contents of total organic carbon, oxidizable carbon fractions of soil organic matter, and humic substances. Two in situ field experiments were carried out during two summers, in order to evaluate the CO2-C emissions in relation to soil temperature variations. The overall low amounts of soil organic matter in Maritime Antarctic soils have a low humification degree and reduced microbial activity. CO2-C emissions showed significant exponential relationship with temperature, suggesting a sharp increase in CO2-C emissions with a warming scenario, and Q10 values (the percentage increase in emission for a 10°C increase in soil temperature) were higher than values reported from elsewhere. The sensitivity of the CO2-C emission in relation to temperature was significantly correlated with the humification degree of soil organic matter and microbial activity for Antarctic soils.


2018 ◽  
Vol 238 ◽  
pp. 329-342 ◽  
Author(s):  
Silene DeCiucies ◽  
Thea Whitman ◽  
Dominic Woolf ◽  
Akio Enders ◽  
Johannes Lehmann

Author(s):  
Songyan Li ◽  
Meng Li ◽  
Guoxi Wang ◽  
Xiaolei Sun ◽  
Beidou Xi ◽  
...  

Abstract Background Exploration of composition and chemical characteristics of soil dissolved organic matter (DOM) is significant to understand its biogeochemical role in terrestrial ecosystems. A total of 43 cropped and 16 natural soils (0–20 cm) under four soil types (cinnamon, chernozem, red and paddy soils) across China were collected to investigate the spectral characteristics of DOM using UV–Vis and 3D-EEM spectroscopy. Results The chernozem soils exhibited the highest aromaticity and humification degree among the four soil types. Ranges of biological index (BIX, 0.53–1.17) and fluorescence index (FI, 1.55–2.10) were found in the investigated DOM, showing joint contribution from allochthonous and autochthonous sources. Higher BIX and FI in the DOM of the paddy and red soils indicated a greater reliance on autochthonous sources for these two soil types. The cropped soils showed no significant differences in chemical characteristics and sources from the natural soils for the cinnamon, chernozem and red soils. UVA (16.2–47.9%) and UVC fulvic-like substances (15.4–40.5%) were the prevailing DOM components, which were highest in the chernozem soils. Additionally, the cropped soils had a higher proportion of humic-like substances than the natural soils in the DOM. Conclusions Both soil type and land-use strongly affected the chemical characteristics of soil DOM, but only soil type had an impact on the DOM composition for the collected soils. These findings may contribute to the prediction of the biochemical behavior of soil DOM under different soil types and land-uses in terrestrial ecosystems.


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