High‐Performance n ‐Type Organic Electrochemical Transistors Enabled by Aqueous Solution Processing of Amphiphilicity‐Driven Polymer Assembly

2022 ◽  
pp. 2111950
Author(s):  
Dahyun Jeong ◽  
Il‐Young Jo ◽  
Seungjin Lee ◽  
Ji Hwan Kim ◽  
Youngseok Kim ◽  
...  
2020 ◽  
Vol 16 ◽  
Author(s):  
Kirubanandam Grace Pavithra ◽  
Vasudevan Jaikumar ◽  
Ponnusamy Senthil Kumar ◽  
PanneerSelvam SundarRajan

Background: Many antibiotics were widely used as medication based on their distinctive features. Among them, sulphonamides were commonly used, however their recalcitrant nature makes them difficult to dispose. Hence, their interaction with environment and analytic technique requires considerable attention globally. Objective: Therefore, this review aimed to provide detailed discussion about environmental as well as human health behaviour and analytic techniques corresponding to sulphonamides. Methods: Various results and discussion were extracted from technical journals and books published by different researchers from all over the world. The cited bibliographic references were intentionally investigated in order to extract relevant information related to proposed work. Results: In this review, the determination techniques such as UV-spectroscopy, Enthalpimetry, Immunosensor, Chromatography, Chemiluminescence, Photoinduced fluorometric determination, Capillary electrophoresis for sulphonamide determination were discussed in detail. Among them, High performance liquid chromatography (HPLC) and UV-spectroscopy was effective and extensively used for screening sulphonamide. Conclusion: Knowing the quantification and behaviour of sulphonamide in aqueous solution is mandatory to opt the suitable wastewater treatment required. Hence, choosing appropriate high precision and feasible screening techniques is necessary, which can be attained with this review.


Author(s):  
Xiaofei Luo ◽  
Shuai Hu ◽  
Jingyou Yuan ◽  
Huan Yang ◽  
Shaoyun Shan ◽  
...  

The increasingly severe issues of antibiotic-induced pollution greatly stimulate the development of high-performance advanced adsorbents. In this contribution, a novel Fe-centered metal-organic aerogel (Fe-MOA) was synthesized through the use of...


Author(s):  
Shikai Yan ◽  
Sheng Tang ◽  
Manman Luo ◽  
Lu Xue ◽  
Shilin Liu ◽  
...  

CsPbBr3-based photodetectors (PDs) have aroused enormous attention owing to their low-cost solution processing, outstanding optoelectronic properties, and remarkable stability. However, their performances remain a big challenge to meet the requirement...


RSC Advances ◽  
2021 ◽  
Vol 11 (17) ◽  
pp. 10300-10308
Author(s):  
Hui Feng ◽  
Siqi Feng ◽  
Niu Tang ◽  
Songbai Zhang ◽  
Xiangyang Zhang ◽  
...  

New idea for the low cost synthesis of high performance photocatalysts for the photodegradation of organic pollutants in aqueous solution.


2003 ◽  
Vol 81 (10) ◽  
pp. 1044-1050 ◽  
Author(s):  
Zhirong Zhu ◽  
Ruan Tain ◽  
Colin Rhodes

In this paper, the decomposition of H3PW12O40 in aqueous solution or in mixed solutions of water–ethanol or water–acetone is investigated by potentiometric titration and 31P NMR. Identification of the products from H3PW12O40 decomposition over a pH range of 1–12 was achieved using preparation high performance liquid chromatography (Pre-HPLC) combined with IR, UV–vis spectroscopy, and inductively coupled plasma atomic emission spectroscopy (ICP). It is found that H3PW12O40 in aqueous solution decomposes in a stepwise fashion with increasing pH, with the following solution compositions: [PW12O40]3– (at pH ~ 1) [Formula: see text] [PW12O40]3– + [P2W21O71]6– + [PW11O39]7– (at pH 2.2) [Formula: see text] [PW12O40]3– + [P2W21O71]6– + [PW11O39]7– + [P2W18O62]6– + [P2W19O67]10– (at pH 3.5) [Formula: see text] [P2W21O71]6– + [PW11O39]7– + [P2W18O62]6– (at pH 5.4) [Formula: see text] [PW9O34]9– (at pH 7.3) [Formula: see text] PO43– + WO42– (pH > 8.3). In the first stages at pH < 8, H3PW12O40 decomposes partially with removal of W=O units. In the second stage at pH > 8, tungstophosphoric completely decomposes to PO43–. In contrast, the decomposition of H3PW12O40 is reduced, or the stability of the [PW12O40]3– anion is enhanced, in ethanol–water or acetone solution at pH < 8. Key words: 12-tungstophosphate heteropolyacid, decomposition behaviour, potentiometric titration, 31P NMR, preparation high performance liquid chromatography.


2021 ◽  
Vol 21 ◽  
pp. 100533
Author(s):  
R. Ediati ◽  
W. Aulia ◽  
B.A. Nikmatin ◽  
A.R.P. Hidayat ◽  
U.M. Fitriana ◽  
...  

Author(s):  
Te-Fu L. Ho ◽  
James R. Bolton ◽  
Ewa Lipczynska-Kochany

AbstractA broadband method has been applied to determine the quantum yields for the photochemical removal of three common pollutants: phenol, 4-chlorophenol and N-nitrosodimethylamine (NDMA) in dilute aqueous solution. Flash photolysis (xenon flash lamps) was used to cause a significant amount of photolysis without photolyzing intermediates. The analysis of reactant depletion following a single flash was carried out by high- performance liquid chromatography (HPLC) or UV/visible absorption spectroscopy. The method for determining quantum-yields employed p-benzoquinone as an actinometer and was validated by determining the average (200-400 nm) quantum yield for the generation of hydroxyl radicals from the photolysis of hydrogen peroxide (0.90 ± 0.10) and the quantum yields for the photolysis of phenol (0.13 ± 0.02) and 4-chlorophenol (0.24 ± 0.04). The values determined agree very well with the literature ones obtained with monochromatic radiation. The quantum yield for the direct photolysis of NDMA was found to be 0.11 ± 0.03 at neutral pH and 0.27 ± 0.02 at pH 2-4. Under conditions where hydrogen peroxide is the principal absorber, the NDMA quantum yield is 0.32 ± 0.04, independent of pH in the range 2-8.


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