scholarly journals 4D Printing: 3D-Printed Hydrogel Composites for Predictive Temporal (4D) Cellular Organizations and Patterned Biogenic Mineralization (Adv. Healthcare Mater. 1/2019)

2019 ◽  
Vol 8 (1) ◽  
pp. 1970001
Author(s):  
Joselle M. McCracken ◽  
Brittany M. Rauzan ◽  
Jacob C. E. Kjellman ◽  
Mikhail E. Kandel ◽  
Yu Hao Liu ◽  
...  
Keyword(s):  
4D Printing ◽  
3D Printed ◽  
Hydrogel Composites

scholarly journals Control-Based 4D Printing: Adaptive 4D-Printed Systems

2020 ◽  
Vol 10 (9) ◽  
pp. 3020 ◽  
Author(s):  
Ali Zolfagharian ◽  
Akif Kaynak ◽  
Mahdi Bodaghi ◽  
Abbas Z. Kouzani ◽  
Saleh Gharaie ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Advanced Manufacturing ◽  
Wearable Electronics ◽  
Stimuli Responsive ◽  
4D Printing ◽  
Control Units ◽  
Printed Sensors ◽  
3D Printed ◽  
Dynamic Structures ◽  
And Control

Building on the recent progress of four-dimensional (4D) printing to produce dynamic structures, this study aimed to bring this technology to the next level by introducing control-based 4D printing to develop adaptive 4D-printed systems with highly versatile multi-disciplinary applications, including medicine, in the form of assisted soft robots, smart textiles as wearable electronics and other industries such as agriculture and microfluidics. This study introduced and analysed adaptive 4D-printed systems with an advanced manufacturing approach for developing stimuli-responsive constructs that organically adapted to environmental dynamic situations and uncertainties as nature does. The adaptive 4D-printed systems incorporated synergic integration of three-dimensional (3D)-printed sensors into 4D-printing and control units, which could be assembled and programmed to transform their shapes based on the assigned tasks and environmental stimuli. This paper demonstrates the adaptivity of these systems via a combination of proprioceptive sensory feedback, modeling and controllers, as well as the challenges and future opportunities they present.

scholarly journals 4D Printing: The Dawn of “Smart” Drug Delivery Systems and Biomedical Applications

2021 ◽  
Vol 11 (5-S) ◽  
pp. 131-137
Author(s):  
Ahmar Khan ◽  
Mir Javid Iqbal ◽  
Saima Amin ◽  
Humaira Bilal ◽  
, Bilquees ◽  
...  
Keyword(s):  
Drug Delivery ◽  
3D Printing ◽  
Patient Compliance ◽  
Smart Materials ◽  
Healthcare Sector ◽  
Massachusetts Institute Of Technology ◽  
4D Printing ◽  
3D Printed ◽  
Smart Drug ◽  
Smart Drug Delivery

With the approval of first 3D printed drug “spritam” by USFDA, 3D printing is gaining acceptance in healthcare, engineering and other aspects of life. Taking 3D printing towards the next step gives birth to what is referred to as “4D printing”. The full credit behind the unveiling of 4D printing technology in front of the world goes to Massachusetts Institute of Technology (MIT), who revealed “time” in this technology as the fourth dimension.  4D printing is a renovation of 3D printing wherein special materials (referred to as smart materials) are incorporated which change their morphology post printing in response to a stimulus. Depending upon the applicability of this technology, there may be a variety of stimuli, most common among them being pH, water, heat, wind and other forms of energy.  The upper hand of 4D printing over 3D printing is that 3D printed structures are generally immobile, rigid and inanimate whereas 4D printed structures are flexible, mobile and able to interact with the surrounding environment based on the stimulus. This capability of 4D printing to transform 3D structures into smart structures in response to various stimuli promises a great potential for biomedical and bioengineering applications. The potential of 4D printing in developing pre-programmed biomaterials that can undergo transformations lays new foundations for enabling smart pharmacology, personalized medicine, and smart drug delivery, all of which can help in combating diseases in a smarter way. Hence, the theme of this paper is about the potential of 4D printing in creating smart drug delivery, smart pharmacology, targeted drug delivery and better patient compliance. The paper highlights the recent advancements of 4D printing in healthcare sector and ways by which 4D printing is doing wonders in creating smart drug delivery and tailored medicine. The major constraints in the approach have also been highlighted. Keywords: 4D printing, smart, drug delivery system, patient compliance, biomaterials, tailored medicine

4D Printing of Complex Ceramic Structures via Controlling Zirconia Contents and Patterns

2021 ◽  
Author(s):  
Zhicheng Rong ◽  
Chang Liu ◽  
Yingbin Hu
Keyword(s):  
3D Printing ◽  
Shape Memory ◽  
Shape Change ◽  
Three Dimensional ◽  
Ceramic Materials ◽  
Full Potential ◽  
Sintering Process ◽  
4D Printing ◽  
3D Printed ◽  
Dynamic Components

Abstract In recent years, more and more attentions have been attracted on integrating three-dimensional (3D) printing with fields (such as magnetic field) or innovating new methods to reap the full potential of 3D printing in manufacturing high-quality parts and processing nano-scaled composites. Among all of newly innovated methods, four-dimensional (4D) printing has been proved to be an effective way of creating dynamic components from simple structures. Common feeding materials in 4D printing include shape memory hydrogels, shape memory polymers, and shape memory alloys. However, few attempts have been made on 4D printing of ceramic materials to shape ceramics into intricate structures, owing to ceramics’ inherent brittleness nature. Facing this problem, this investigation aims at filling the gap between 4D printing and fabrication of complex ceramic structures. Inspired by swelling-and-shrinking-induced self-folding, a 4D printing method is innovated to add an additional shape change of ceramic structures by controlling ZrO2 contents and patterns. Experimental results evidenced that by deliberately controlling ZrO2 contents and patterns, 3D-printed ceramic parts would undergo bending and twisting during the sintering process. To demonstrate the capabilities of this method, more complex structures (such as a flower-like structure) were fabricated. In addition, functional parts with magnetic behaviors were 4D-printed by incorporating iron into the PDMS-ZrO2 ink.

Functional applications of 4D printing: A review

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Shubham Shankar Mohol ◽  
Varun Sharma
Keyword(s):  
Smart Materials ◽  
Self Assembly ◽  
Research Study ◽  
Rapid Development ◽  
Raw Material ◽  
4D Printing ◽  
Content Type ◽  
Functional Applications ◽  
Significant Research ◽  
3D Printed

Purpose Additive manufacturing has rapidly developed in terms of technology and its application in various types of industries. With this rapid development, there has been significant research in the area of materials. This has led to the invention of Smart Materials (SMs). The 4D printing is basically 3D printing of these SMs. This paper aims to focus on novel materials and their useful application in various industries using the technology of 4D printing. Design/methodology/approach Research studies in 4D printing have increased since the time when this idea was first introduced in the year 2013. The present research study will deeply focus on the introduction to 4D printing, types of SMs and its application based on the various types of stimulus. The application of each type of SM has been explained along with its functioning with respect to the stimulus. Findings SMs have multiple functional applications pertaining to appropriate industries. The 4D printed parts have a distinctive capability to change its shape and self-assembly to carry out a specific function according to the requirement. Afterward, the fabricated part can recover to its 3D printed “memorized” shape once it is triggered by the stimulus. Originality/value The present study highlights the various capabilities of SMs, which is used as a raw material in 4D printing. Graphical abstract

A review on 3D printed smart devices for 4D printing

2017 ◽  
Vol 4 (3) ◽  
pp. 373-383 ◽  
Author(s):  
Jeongwoo Lee ◽  
Ho-Chan Kim ◽  
Jae-Won Choi ◽  
In Hwan Lee
Keyword(s):  
Smart Devices ◽  
4D Printing ◽  
3D Printed

scholarly journals Out-of-Plane 3D-Printed Microfibers Improve the Shear Properties of Hydrogel Composites

Small ◽  
2017 ◽  
Vol 14 (8) ◽  
pp. 1702773 ◽  
Author(s):  
Mylène de Ruijter ◽  
Andrei Hrynevich ◽  
Jodie N. Haigh ◽  
Gernot Hochleitner ◽  
Miguel Castilho ◽  
...  
Keyword(s):  
Shear Properties ◽  
Out Of Plane ◽  
3D Printed ◽  
Hydrogel Composites

scholarly journals Comprehensive Study on Shape Shifting Behaviors of Thermally Activated Hinges in FDM-based 4D Printing

2021 ◽  
Author(s):  
Iman Salimi Nezhad ◽  
Mohammad Golzar ◽  
Amirhossein Behravesh ◽  
Shahabaddin Zare
Keyword(s):  
Layer Structure ◽  
Single Layer ◽  
4D Printing ◽  
Thermally Activated ◽  
Proposed Model ◽  
3D Printed ◽  
Beam Bending ◽  
Nozzle Temperature ◽  
Fractional Zener Model ◽  
Semi Empirical

Abstract 4D printing of shape shifting structures, aka “hinges”, has raised a new standard in many fields. By using these hinges in certain parts of a 3D printed structures, a pre designed complex 3D shape with potential multifunctional application can be achieved from flat structure. This paper proposes a comprehensive semi-empirical model to predict the final shape shifting behavior and magnitude of the hinges printed by FDM process. First, all FDM main parameters are selected and reduced by design of experiment to printing speed, lamina thickness, nozzle temperature as well as printing pattern. In order to develop the model, a time-dependent constitutive model with these four process parameters were extracted for strain of an SMP homogeneous single layer structure using a fractional Zener model accompanied with Multiple Linear Regression (MLR) technique. Thereafter, the mathematical relations for shape shifting behavior of bilayer 4D printed structures were developed for beam bending and twisting by modifying Timoshenko’s constitutive equations. A comprehensive shape-shifting model was established including 3D printing parameters, angles, thickness ratios, activation time and temperature which was compared to the experimental data and results predicted both shape shifting behavior and magnitude of the hinges with good agreement. In addition, a novel flowchart was suggested to design and achieve the desired shape shifting behaviors. The proposed model and flowchart are novel tools to design 4D structures through desired shape-shifting of the hinges.

Frontally polymerizable shape memory polymer for 3D printing of free-standing structures

2021 ◽  
Author(s):  
Yongsan An ◽  
Joon Hyeok Jang ◽  
Ji Ho Youk ◽  
Woong-Ryeol Yu
Keyword(s):  
Shape Memory ◽  
Memory Performance ◽  
Shape Memory Polymer ◽  
Three Dimensional ◽  
Frontal Polymerization ◽  
4D Printing ◽  
Free Standing ◽  
Time Shape ◽  
Standing Structure ◽  
3D Printed

Abstract Four-dimensional (4D) printing is used to describe three-dimensional (3D)-printed objects with properties that change over time. Shape memory polymers (SMPs) are representative materials for 4D printing technologies. The ability to print geometrically complex, free-standing forms with SMPs is crucial for successful 4D printing. In this study, an SMP capable of frontal polymerization featuring exothermic self-propagation was synthesized by adding cyclooctene to a poly(dicyclopentadiene) network, resulting in switching segments. The rheological properties of this SMP were controlled by adjusting incubation time. A nozzle system was designed such that the SMP could be printed with simultaneous polymerization to yield a free-standing structure. The printing speed was set to 3 cm/min according to the frontal polymerization speed. A free-standing, hexagonal spiral was successfully printed and printed spiral structure showed excellent shape memory performance with a fixity ratio of about 98% and a recovery ratio of 100%, thereby demonstrating the 3D printability and shape memory performance of frontally polymerizable SMPs.

3D Printing and Growth Induced Bending based on PET-RAFT Polymerization

2020 ◽  
Author(s):  
Chris Bainbridge ◽  
Kyle Engel ◽  
Jianyong Jin
Keyword(s):  
3D Printing ◽  
Surface Properties ◽  
Raft Polymerization ◽  
Advanced Manufacturing ◽  
3D Printer ◽  
4D Printing ◽  
Printing Process ◽  
Raft Agent ◽  
3D Printed ◽  
First Time

4D printing has steadily become an emerging area of advanced manufacturing research and has produced some truly fantastic innovations. Previously we have demonstrated the 3D printing process based on PET-RAFT polymerization, and its subsequent capability in the post-production modification of surface properties. In this work, (1) we further optimized the PET-RAFT 3D printing formulation by replacing RAFT agent CDTPA with BTPA and adjusting the monomers composition; (2) we also observed the photodegradation of the photocatalysts EB and EY under 405nm light and the effects this has on 3D printing; (3) we then did successful 3D printing using a commercial 405nm DLP 3D printer, with an improved build speed of up to 2286 µm/hr; (4) lastly, for the first time we have demonstrated a method for growth induced bending of a 3D printed strip, where the growth on one side of the strip causes stress and the strip bends accordingly to reach a more comfortable position.

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