Directed Self-Assembly of Spherical Particles on Patterned Electrodes by an Applied Electric Field

2005 ◽  
Vol 17 (12) ◽  
pp. 1507-1511 ◽  
Author(s):  
A. Winkleman ◽  
B. D. Gates ◽  
L. S. McCarty ◽  
G. M. Whitesides
Author(s):  
M. Janjua ◽  
S. Nudurupati ◽  
I. Fischer ◽  
P. Singh ◽  
N. Aubry

It was recently shown by us that spherical particles floating on a fluid-fluid interface can be self-assembled, and the lattice between them can be controlled, using an electric field. In this paper we show that the technique can also be used to self assemble rod-like particles on fluid-fluid interfaces. The method consists of sprinkling particles at a liquid interface and applying an electric field normal to the interface, thus resulting in a combination of hydrodynamic (capillary) and electrostatic forces acting on the particles. A rod floating on the fluid interface experiences both a lateral force and a torque normal to the interface due to capillarity, and in the presence of an electric field, it is also subjected to an electric force and torque. The electric force affects the rods’ approach velocity and the torque aligns the rods parallel to each other. In the absence of an electric field, two rods that are initially more than one rod length away from each other come in contact so that they are either perpendicular or parallel to the line joining their centers, depending on their initial orientations. In the latter case, their ends are touching. Our experiments show that in an electric field of sufficiently large strength, only the latter arrangement is stable. Experiments also show that in this case the electric field causes the rods of the monolayer to align parallel to one another and that the lattice spacing of a self-assembled monolayer of rods increases.


Author(s):  
N. Aubry ◽  
S. Nudurupati ◽  
M. Janjua ◽  
P. Singh

It was recently shown in [1–3] that spherical particles floating on a fluid-fluid interface can be self-assembled, and the lattice between them can be controlled, using an electric field. The technique works for a broad range of fluids and particles, including electrically neutral (i.e., uncharged) particles and small particles (micro- and nano-sized particles). In this paper we show that the technique also works for rod-like and cubical particles floating on fluid-fluid interfaces. The method consists of sprinkling particles at a liquid interface and applying an electric field normal to the interface, thus resulting in a combination of hydrodynamic (capillary) and electrostatic forces acting on the particles. It is shown that the relative orientation of two rod-like particles can be controlled by applying an electric field normal to the interface. The lattice spacing of the self-assembled monolayer of rods can be increased by increasing the electric field strength. Furthermore, experiments show that there is a tendency for the rods to align so that they are parallel to each other. The alignment however is not complete. Similarly, the spacing between two cubes, as well as the spacing of a monolayer of cubes, can be adjusted by controlling the electric field strength.


Author(s):  
Mo Yang ◽  
Cengiz S. Ozkan ◽  
Huajian Gao

Amethod has been developed for fabricating polymer microstructures based on electric field induced self assembly and pattern formation. A dielectric fluid placed in between two conductive plates experience a force in an applied electric field gradient across the plates, which can induce a diffusive surface instability and self construction of the fluid surface. This process is exploited for the fabrication of self assembled polymer microstructures as well as replicated patterns through the use of pre-patterned plates or electrodes. FEM simulation is used to decide the minimum wavelength and electric gradient distribution of polymer structures. A variety of structures in the micron and nanometer scales including bio-fluidic MEMS, polymer optoelectronic devices can be fabricated using this method.


1972 ◽  
Vol 33 (C1) ◽  
pp. C1-63-C1-67 ◽  
Author(s):  
M. BERTOLOTTI ◽  
B. DAINO ◽  
P. Di PORTO ◽  
F. SCUDIERI ◽  
D. SETTE

2012 ◽  
Vol 15 (2-3) ◽  
pp. 127-139
Author(s):  
Tung Tran Anh ◽  
Laurent Berquez ◽  
Laurent Boudou ◽  
Juan Martinez-Vega ◽  
Alain Lacarnoy

2008 ◽  
Vol 75 (1) ◽  
Author(s):  
Q. Li ◽  
Y. H. Chen

A semi-permeable interface crack in infinite elastic dielectric/piezoelectric bimaterials under combined electric and mechanical loading is studied by using the Stroh complex variable theory. Attention is focused on the influence induced from the permittivity of the medium inside the crack gap on the near-tip singularity and on the energy release rate (ERR). Thirty five kinds of such bimaterials are considered, which are constructed by five kinds of elastic dielectrics and seven kinds of piezoelectrics, respectively. Numerical results for the interface crack tip singularities are calculated. We demonstrate that, whatever the dielectric phase is much softer or much harder than the piezoelectric phase, the structure of the singular field near the semi-permeable interface crack tip in such bimaterials always consists of the singularity r−1∕2 and a pair of oscillatory singularities r−1∕2±iε. Calculated values of the oscillatory index ε for the 35 kinds of bimaterials are presented in tables, which are always within the range between 0.046 and 0.088. Energy analyses for five kinds of such bimaterials constructed by PZT-4 and the five kinds of elastic dielectrics are studied in more detail under four different cases: (i) the crack is electrically conducting, (ii) the crack gap is filled with air/vacuum, (iii) the crack gap is filled with silicon oil, and (iv) the crack is electrically impermeable. Detailed comparisons on the variable tendencies of the crack tip ERR against the applied electric field are given under some practical electromechanical loading levels. We conclude that the different values of the permittivity have no influence on the crack tip singularity but have significant influences on the crack tip ERR. We also conclude that the previous investigations under the impermeable crack model are incorrect since the results of the ERR for the impermeable crack show significant discrepancies from those for the semi-permeable crack, whereas the previous investigations under the conducting crack model may be accepted in a tolerant way since the results of the ERR show very small discrepancies from those for the semi-permeable crack, especially when the crack gap is filled with silicon oil. In all cases under consideration the curves of the ERR for silicon oil are more likely tending to those for the conducting crack rather than to those for air or vacuum. Finally, we conclude that the variable tendencies of the ERR against the applied electric field have an interesting load-dependent feature when the applied mechanical loading increases. This feature is due to the nonlinear relation between the normal electric displacement component and the applied electromechanical loadings from a quadratic equation.


2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Chunzheng Lv ◽  
Lirong He ◽  
Jiahong Tang ◽  
Feng Yang ◽  
Chuhong Zhang

AbstractAs an important photoconductive hybrid material, perylene/ZnO has attracted tremendous attention for photovoltaic-related applications, but generally faces a great challenge to design molecular level dispersed perylenes/ZnO nanohybrids due to easy phase separation between perylenes and ZnO nanocrystals. In this work, we reported an in-situ reaction method to prepare molecular level dispersed H-aggregates of perylene bisimide/ZnO nanorod hybrids. Surface photovoltage and electric field-induced surface photovoltage spectrum show that the photovoltage intensities of nanorod hybrids increased dramatically for 100 times compared with that of pristine perylene bisimide. The enhancement of photovoltage intensities resulting from two aspects: (1) the photo-generated electrons transfer from perylene bisimide to ZnO nanorod due to the electric field formed on the interface of perylene bisimide/ZnO; (2) the H-aggregates of perylene bisimide in ZnO nanorod composites, which is beneficial for photo-generated charge separation and transportation. The introduction of ordered self-assembly thiol-functionalized perylene-3,4,9,10-tetracarboxylic diimide (T-PTCDI)/ ZnO nanorod composites induces a significant improvement in incident photo-to-electron conversion efficiency. This work provides a novel mentality to boost photo-induced charge transfer efficiency, which brings new inspiration for the preparation of the highly efficient solar cell.


The Analyst ◽  
2020 ◽  
Vol 145 (6) ◽  
pp. 2412-2419 ◽  
Author(s):  
Rachel N. Deraney ◽  
Lindsay Schneider ◽  
Anubhav Tripathi

NA extraction and purification utilitzing a microfluidic chip with applied electric field to induce electroosmotic flow opposite the magnetic NA-bound bead mix.


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