Kinetically Controlled, Scalable Synthesis of γ‐FeOOH Nanosheet Arrays on Nickel Foam toward Efficient Oxygen Evolution: The Key Role of In‐Situ‐Generated γ‐NiOOH

2021 ◽  
Vol 33 (11) ◽  
pp. 2005587
Author(s):  
Ke Wang ◽  
Hongfang Du ◽  
Song He ◽  
Lei Liu ◽  
Kai Yang ◽  
...  
2020 ◽  
Vol 7 (18) ◽  
pp. 3465-3474
Author(s):  
Junjie Pan ◽  
Shaoyun Hao ◽  
Xingwang Zhang ◽  
Rongxin Huang

Fe, Nb co-doped β-Ni(OH)2 electrode exhibited excellent OER performance with an overpotential of 294 mV at 100 mA cm−2.


2020 ◽  
Vol 49 (15) ◽  
pp. 4956-4966 ◽  
Author(s):  
Jingbo Li ◽  
Yu Liu ◽  
Wei Cao ◽  
Nan Chen

A rapid in situ method was employed to synthesize the β-Ni(OH)2@NF integrated electrode for a high performance ASC device.


2018 ◽  
Vol 54 (40) ◽  
pp. 5066-5069 ◽  
Author(s):  
Ying Gou ◽  
Qin Liu ◽  
Xifeng Shi ◽  
Abdullah M. Asiri ◽  
Jianming Hu ◽  
...  

CaMoO4 nanosheet arrays grown in situ on nickel foam (CaMoO4/NF) act as a superior 3D catalyst electrode for alkaline water oxidation with high long-term durability.


Author(s):  
Yuta Inoue ◽  
Yuto Miyahara ◽  
Kohei Miyazaki ◽  
Yasuyuki Kondo ◽  
Yuko Yokoyama ◽  
...  

Abstract Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) is a promising electrocatalyst for the oxygen evolution reaction (OER) in alkaline solution. The OER activities of BSCF are gradually enhanced by prolonging the duration of electrochemical operation at OER potentials, but the underlying cause is not fully understood. In this study, we investigated the role of chemical operation, equivalent to immersion in alkaline solution, in the time-course of OER enhancement of BSCF. Interestingly, the time-course OER enhancement of BSCF was promoted not only by electrochemical operation, which corresponds to potential cycling in the OER region, but also by chemical operation. In situ Raman measurements clarified that chemical operation had a lower rate of surface amorphization than electrochemical operation. On the other hand, the leaching behavior of A-site cations was comparable between chemical and electrochemical operations. Since the OER activity of BSCF was stabilized by saturating the electrolyte with Ba2+, “chemical” A-site leaching was key to inducing the time-course OER enhancement on perovskite electrocatalysts. Based on these results, we provide a fundamental understanding of the role of chemical operation in the OER properties of perovskites.


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