CaMoO4 nanosheet arrays for efficient and durable water oxidation electrocatalysis under alkaline conditions

2018 ◽  
Vol 54 (40) ◽  
pp. 5066-5069 ◽  
Author(s):  
Ying Gou ◽  
Qin Liu ◽  
Xifeng Shi ◽  
Abdullah M. Asiri ◽  
Jianming Hu ◽  
...  

CaMoO4 nanosheet arrays grown in situ on nickel foam (CaMoO4/NF) act as a superior 3D catalyst electrode for alkaline water oxidation with high long-term durability.

2020 ◽  
Vol 49 (15) ◽  
pp. 4956-4966 ◽  
Author(s):  
Jingbo Li ◽  
Yu Liu ◽  
Wei Cao ◽  
Nan Chen

A rapid in situ method was employed to synthesize the β-Ni(OH)2@NF integrated electrode for a high performance ASC device.


2020 ◽  
Vol 7 (18) ◽  
pp. 3465-3474
Author(s):  
Junjie Pan ◽  
Shaoyun Hao ◽  
Xingwang Zhang ◽  
Rongxin Huang

Fe, Nb co-doped β-Ni(OH)2 electrode exhibited excellent OER performance with an overpotential of 294 mV at 100 mA cm−2.


2016 ◽  
Vol 2 (10) ◽  
pp. e1600495 ◽  
Author(s):  
Bo-Quan Li ◽  
Cheng Tang ◽  
Hao-Fan Wang ◽  
Xiao-Lin Zhu ◽  
Qiang Zhang

Perovskite oxides with poor conductivity call for three-dimensional (3D) conductive scaffolds to demonstrate their superb reactivities for oxygen evolution reaction (OER). However, perovskite formation usually requires high-temperature annealing at 600° to 900°C in air, under which most of the used conductive frameworks (for example, carbon and metal current collectors) are reductive and cannot survive. We propose a preoxidization coupled electrodeposition strategy in which Co2+ is preoxidized to Co3+ through cobalt Fenton reaction in aqueous solution, whereas the reductive nickel framework is well maintained during the sequential annealing under nonoxidative atmosphere. The in situ–generated Co3+ is inherited into oxidized perovskites deposited on 3D nickel foam, rendering the monolithic perovskite electrocatalysts with extraordinary OER performance with an ultralow overpotential of 350 mV required for 10 mA cm−2, a very small Tafel slope of 59 mV dec−1, and superb stability in 0.10 M KOH. Therefore, we inaugurate a unique strategy for in situ hybridization of oxidative active phase with reductive framework, affording superb reactivity of perovskite electrocatalyst for efficient water oxidation.


2021 ◽  
Vol 880 ◽  
pp. 114918
Author(s):  
Hailong Li ◽  
Zhengwang Zhu ◽  
Yuanyuan Wang ◽  
Sen Chen ◽  
Chunming Liu ◽  
...  

2017 ◽  
Vol 5 (14) ◽  
pp. 6388-6392 ◽  
Author(s):  
Guilei Zhu ◽  
Ruixiang Ge ◽  
Fengli Qu ◽  
Gu Du ◽  
Abdullah M. Asiri ◽  
...  

A core–shell Fe–Co3O4@Fe–Co–Bi nanoarray (Fe–Co3O4@Fe–Co–Bi/CC) acts as a superior catalyst electrode for water oxidation, with the need of an overpotential of 420 mV to drive 10 mA cm−2 in 0.1 M K-Bi.


Small Methods ◽  
2021 ◽  
pp. 2100573
Author(s):  
Xuan Sun ◽  
Xiuxiu Zhang ◽  
Yuanli Li ◽  
Yanzhi Xu ◽  
Hui Su ◽  
...  

Nanoscale ◽  
2020 ◽  
Vol 12 (17) ◽  
pp. 9462-9470 ◽  
Author(s):  
Xin Ding ◽  
Hongli Liu ◽  
Jiangyao Chen ◽  
Meicheng Wen ◽  
Guiying Li ◽  
...  

Well-aligned Ni-MOF nanosheet arrays vertically grown on nickel foam were synthesized via a facile in situ solvothermal strategy, which exhibited remarkably improved photocatalytic activities to typical VOCs under visible light irradiation.


RSC Advances ◽  
2019 ◽  
Vol 9 (38) ◽  
pp. 21679-21684 ◽  
Author(s):  
Jianying Wang ◽  
Xue Teng ◽  
Yanli Niu ◽  
Lixia Guo ◽  
Jianfei Kong ◽  
...  

We report here a simple and cost-effective autologous growth method to prepare a NiFe-based integrated electrode for efficient electrocatalytic water oxidation.


2018 ◽  
Vol 2 (9) ◽  
pp. 1986-1994 ◽  
Author(s):  
Diego González-Flores ◽  
Katharina Klingan ◽  
Petko Chernev ◽  
Stefan Loos ◽  
Mohammad Reza Mohammadi ◽  
...  

NiFe oxyhydroxides are prime candidates for efficient alkaline water oxidation; their redox chemistry is tracked by X-ray spectroscopy.


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