ChemInform Abstract: THE REACTION OF DILITHIUM CARBOXYLATES WITH ACYCLIC α,β-ENONES- A CONTINUOUS TRANSITION FROM 1.2- TO 1.4-ADDITION

1978 ◽  
Vol 9 (45) ◽  
Author(s):  
J. MULZER ◽  
G. HARTZ ◽  
U. KUEHL ◽  
G. BRUENTRUP
2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Dmitriy S. Shapiro

AbstractUnder nonequilibrium conditions, quantum optical systems reveal unusual properties that might be distinct from those in condensed matter. The fundamental reason is that photonic eigenstates can have arbitrary occupation numbers, whereas in electronic systems these are limited by the Pauli principle. Here, we address the steady-state transport of pseudothermal photons between two waveguides connected through a cavity with Bose–Hubbard interaction between photons. One of the waveguides is subjected to a broadband incoherent pumping. We predict a continuous transition between the regimes of Lorentzian and Gaussian chaotic light emitted by the cavity. The rich variety of nonequilibrium transport regimes is revealed by the zero-frequency noise. There are three limiting cases, in which the noise-current relation is characterized by a power-law, $$S\propto J^\gamma$$ S ∝ J γ . The Lorentzian light corresponds to Breit-Wigner-like transmission and $$\gamma =2$$ γ = 2 . The Gaussian regime corresponds to many-body transport with the shot noise ($$\gamma =1$$ γ = 1 ) at large currents; at low currents, however, we find an unconventional exponent $$\gamma =3/2$$ γ = 3 / 2 indicating a nontrivial interplay between multi-photon transitions and incoherent pumping. The nonperturbative solution for photon dephasing is obtained in the framework of the Keldysh field theory and Caldeira-Leggett effective action. These findings might be relevant for experiments on photon blockade in superconducting qubits, thermal states transfer, and photon statistics probing.


1998 ◽  
Vol 11 (1) ◽  
pp. 381-381
Author(s):  
A.V. Dorodnitsyn

We have considered a stationary outflowing envelope accelerated by the radiative force in arbitrary optical depth case. Introduced approximations provide satisfactory description of the behavior of the matter flux with partially separated radiation at arbitrary optical depths. The obtained systemof differential equations provides a continuous transition of the solution between optically thin and optically thick regions. We analytically derivedapproximate representation of the solution at the vicinity of the sonic point. Using this representation we numerically integrate the system of equations from the critical point to the infinity. Matching the boundary conditions we obtain solutions describing the problem system of differential equations. The theoretical approach advanced in this work could be useful for self-consistent simulations of massive star evolution with mass loss.


Science ◽  
2019 ◽  
Vol 366 (6464) ◽  
pp. 475-479 ◽  
Author(s):  
Guohua Dong ◽  
Suzhi Li ◽  
Mouteng Yao ◽  
Ziyao Zhou ◽  
Yong-Qiang Zhang ◽  
...  

Ferroelectrics are usually inflexible oxides that undergo brittle deformation. We synthesized freestanding single-crystalline ferroelectric barium titanate (BaTiO3) membranes with a damage-free lifting-off process. Our BaTiO3 membranes can undergo a ~180° folding during an in situ bending test, demonstrating a super-elasticity and ultraflexibility. We found that the origin of the super-elasticity was from the dynamic evolution of ferroelectric nanodomains. High stresses modulate the energy landscape markedly and allow the dipoles to rotate continuously between the a and c nanodomains. A continuous transition zone is formed to accommodate the variant strain and avoid high mismatch stress that usually causes fracture. The phenomenon should be possible in other ferroelectrics systems through domain engineering. The ultraflexible epitaxial ferroelectric membranes could enable many applications such as flexible sensors, memories, and electronic skins.


2018 ◽  
Vol 15 (3) ◽  
pp. 61-81
Author(s):  
Hisham M. Alsaghier ◽  
Shaik Shakeel Ahamad

This article describes how the exponential growth of mobile applications has changed the way healthcare services function, and mobile healthcare using the Cloud is the most promising technology for healthcare industry. The mobile healthcare industry is in a continuous transition phase that requires continual innovation. There has been identified some of the challenges in the area of security protocols for mobile health systems which still need to be addressed in the future to enable cost-effective, secure and robust mobile health systems. This article addresses these challenges by proposing a secure robust and privacy-enhanced mobile healthcare framework (SRPF) by adopting a Community Cloud (CC), WPKI cryptosystems, Universal Integrated Circuit Cards (UICCs) and a Trusted Platform Module (TPM). All the security properties are provided within this framework. SRPF overcomes replay attacks, Man in the Middle (MITM) Attacks, Impersonation attacks and Multi-Protocol attacks as SRPF was successfully verified using a scyther tool and by BAN logic.


2007 ◽  
Vol 95 (1) ◽  
Author(s):  
Zs. Szántó ◽  
É. Svingor ◽  
I. Futó ◽  
L. Palcsu ◽  
M. Molnár ◽  
...  

As part of the site characterisation program for the near surface radioactive waste treatment and disposal facility (RWTDF) at Püspökszilágy, Hungary, water quality and environmental isotope investigations have been carried out. Water samples for major ion chemistry, tritium,The chemical composition of groundwaters presented a continuous transition from waters situated on one side to waters on the top and on the other slope of the disposal suggesting the mixing of the three hydrochemical “endmembers”.Most of δ


1987 ◽  
Vol 01 (05n06) ◽  
pp. 239-244
Author(s):  
SERGE GALAM

A new mechanism to explain the first order ferroelastic—ferroelectric transition in Terbium Molybdate (TMO) is presented. From group theory analysis it is shown that in the two-dimensional parameter space ordering along either an axis or a diagonal is forbidden. These symmetry-imposed singularities are found to make the unique stable fixed point not accessible for TMO. A continuous transition even if allowed within Landau theory is thus impossible once fluctuations are included. The TMO transition is therefore always first order. This explanation is supported by experimental results.


1999 ◽  
Vol 315 (3-4) ◽  
pp. 159-165 ◽  
Author(s):  
A.K Pradhan ◽  
S Shibata ◽  
T Machi ◽  
K Nakao ◽  
N Koshizuka

2021 ◽  
Vol 103 (2) ◽  
Author(s):  
N. A. Panov ◽  
D. E. Shipilo ◽  
I. A. Nikolaeva ◽  
V. O. Kompanets ◽  
S. V. Chekalin ◽  
...  

2021 ◽  
Author(s):  
Xu Li ◽  
Tingting Xue ◽  
Yu Sun ◽  
Jingfang Fan ◽  
Hui Li ◽  
...  

Abstract Living systems are full of astonishing diversity and complexity of life. Despite differences in the length scales and cognitive abilities of these systems, collective motion of large groups of individuals can emerge. It is of great importance to seek for the fundamental principles of collective motion, such as phase transitions and their natures. Via an eigen microstate approach, we have found a discontinuous transition of density and a continuous transition of velocity in the Vicsek models of collective motion, which are identified by the finite-size scaling form of order-parameter. At strong noise, living systems behave like gas. With the decrease of noise, the interactions between the particles of a living system become stronger and make them come closer. The living system experiences then a discontinuous gas-liquid like transition of density. The even stronger interactions at smaller noise make the velocity directions of particles become ordered and there is a continuous phase transition of collective motion in addition.


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