The crystal structures of two face-to-face diporphyrin compounds based upon the DPA ligand (1,8-bis(5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl-porphyrinyl))anthracene), i.e. H 4( DPA ) and ( DPA ) Co 2 are reported. The structural data are compared to that of other bimetallic DPA systems, and diporphyrinic Co complexes. In addition, the luminescence properties of ( OEP ) Co ( OEP = 2,3,7,8,12,13,17,18-octaethylporphyrin), H 2( DPA ) Co , H 2( DPA )( CoIm ) O 2, ( DPA ) Co 2, ( DPA )( CoIm )2 O 2 are reported, where Im is 1-t-butyl-5-phenyl imidazole. Contrary to previous literature reports, the Co (II) species are found to be weakly luminescent, where fluorescence is detected for both the mono- and diporphyrinic systems, and is assigned to emissions arising from the lowest 1 Q (ππ*) states, while phosphorescence is detected at 77 K only for the monoporphyrin species, ( OEP ) Co . On the other hand, the Co (III) complexes are not luminescent.