ChemInform Abstract: Reactivity and Mechanistic Insight into the Cross Coupling Reaction Between Isochromans and β-Keto Esters Through C-H Bond Activation under Visible Light Irradiation.

ChemInform ◽  
2016 ◽  
Vol 47 (32) ◽  
Author(s):  
Ming Xiang ◽  
Qing-Yuan Meng ◽  
Xue-Wang Gao ◽  
Tao Lei ◽  
Bin Chen ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Bond Activation ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Light Irradiation ◽  
Keto Esters ◽  
Mechanistic Insight ◽  
Cross Coupling Reaction ◽  
Insight Into

Reactivity and mechanistic insight into the cross coupling reaction between isochromans and β-keto esters through C–H bond activation under visible light irradiation

2016 ◽  
Vol 3 (4) ◽  
pp. 486-490 ◽  
Author(s):  
Ming Xiang ◽  
Qing-Yuan Meng ◽  
Xue-Wang Gao ◽  
Tao Lei ◽  
Bin Chen ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Bond Activation ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Keto Esters ◽  
Mechanistic Insight ◽  
Cross Coupling Reaction ◽  
Insight Into

The formation of a C(sp3)–C(sp3) bond next to an oxygen atom from two different C–H bonds is realized by oxidative photocatalysis.

Photocatalytic hydrogen evolution using a Ru(ii)-bound heteroaromatic ligand as a reactive site

2020 ◽  
Vol 49 (47) ◽  
pp. 17230-17242
Author(s):  
Takuya Sawaki ◽  
Tomoya Ishizuka ◽  
Nanase Namura ◽  
Dachao Hong ◽  
Mayuko Miyanishi ◽  
...  
Keyword(s):  
Visible Light ◽  
Hydrogen Evolution ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Organic Substrates ◽  
Reactive Site ◽  
Photocatalytic Hydrogen Evolution ◽  
Mechanistic Insight ◽  
Diimine Ligand ◽  
Insight Into

A RuII complex with a π-expanded diimine ligand performs photocatalytic H2 evolution and hydrogenation of organic substrates under visible-light irradiation, involving an intermediate with the dihydrogenated ligand; a mechanistic insight into the H2 evolution is also gained.

Efficient visible-light-driven Suzuki coupling reaction over Co-doped BiOCl/Ce-doped Bi2O2CO3 composites

2021 ◽  
Author(s):  
Dan-Xia Zhao ◽  
Guo-Ping Lu ◽  
Chun Cai
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Phenylboronic Acid ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Suzuki Coupling ◽  
Light Irradiation ◽  
Suzuki Coupling Reaction ◽  
Visible Light Driven ◽  
Co Doped

The proposed mechanism of the photocatalytic Suzuki cross-coupling of bromobenzene and phenylboronic acid under visible-light irradiation.

Synthesis of aromatic β-keto esters via a carbonylative Suzuki–Miyaura coupling reaction of α-iodo esters with arylboronic acids

2015 ◽  
Vol 2 (9) ◽  
pp. 1085-1087 ◽  
Author(s):  
Shuhei Sumino ◽  
Takahito Ui ◽  
Ilhyong Ryu
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Catalytic Amount ◽  
Pd Catalyst ◽  
Arylboronic Acids ◽  
Keto Esters ◽  
Cross Coupling Reaction ◽  
Alkyl Iodides

Aromatic β-keto esters were synthesized via a carbonylative cross-coupling reaction of alkyl iodides and arylboronic acids in the presence of a catalytic amount of Pd catalyst.

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