scholarly journals Boosting capacitive deionization performance of commercial carbon fibers cloth via structural regulation based on catalytic‐etching effect

Author(s):  
Chunjie Zhang ◽  
Dong Wang ◽  
Zhen Wang ◽  
Guangshuai Zhang ◽  
Zhichao Liu ◽  
...  

1989 ◽  
Vol 170 ◽  
Author(s):  
J. A. Hinkley ◽  
W. D. Bascom ◽  
R. E. Allred

AbstractThe surfaces of commercial carbon fibers are generally chemically cleaned or oxidized and then coated with an oligomeric sizing to optimize their adhesion to epoxy matrix resins. Evidence from fractography, from embedded fiber testing and from fracture energies suggests that these standard treatments are relatively ineffective for thermoplastic matrices. This evidence is reviewed and model thermoplastic composites (polyphenylene oxide/high strain carbon fibers) are used to demonstrate how differences in adhesion can lead to a two-fold change in interlaminar fracture toughness.The potential for improved adhesion via plasma modification of fiber surfaces is discussed. Finally, a surprising case of fiber-catalyzed resin degradation is described.



2011 ◽  
Vol 55 (5) ◽  
pp. 819-823 ◽  
Author(s):  
Dae-Ho Kim ◽  
Bo-Hye Kim ◽  
Kap-Seung Yang ◽  
Yun-Hyuk Bang ◽  
Sung-Ryong Kim ◽  
...  


2020 ◽  
Vol 117 (14) ◽  
pp. 7658-7664 ◽  
Author(s):  
Wilhelm Johannisson ◽  
Ross Harnden ◽  
Dan Zenkert ◽  
Göran Lindbergh

Structures that are capable of changing shape can increase efficiency in many applications, but are often heavy and maintenance intensive. To reduce the mass and mechanical complexity solid-state morphing materials are desirable but are typically nonstructural and problematic to control. Here we present an electrically controlled solid-state morphing composite material that is lightweight and has a stiffness higher than aluminum. It is capable of producing large deformations and holding them with no additional power, albeit at low rates. The material is manufactured from commercial carbon fibers and a structural battery electrolyte, and uses lithium-ion insertion to produce shape changes at low voltages. A proof-of-concept material in a cantilever setup is used to show morphing, and analytical modeling shows good correlation with experimental observations. The concept presented shows considerable promise and paves the way for stiff, solid-state morphing materials.



Author(s):  
Jie Zhang ◽  
Hao Zhang ◽  
Wenli Li ◽  
Guangwen Xu ◽  
Yanbin Cui

Carbon fiber cloth with high utilization is urgently needed for portable and wearable electronics. We report herein an interconnected 3D primitive outerlayer by utilizing two disparate catalytic etching behaviors based...



1982 ◽  
Vol 53 (7) ◽  
pp. 1092-1093 ◽  
Author(s):  
R. Prohaska ◽  
A. Fisher


2021 ◽  
Author(s):  
Joon Hyuk Lee ◽  
Soon Hong Lee ◽  
Dong Hack Suh

Abstract Using petroleum pitch is touted as a sustainable method to fabricate carbon fibers, yet requires further advances in inevitable pore decrease after post-treatment. In an effort to circumvent this upper limit, renewable resources are widely used in the production of commercial carbon fibers. Here we show that dissolved micro-nanobubbles of CO2 in pretreatment may aid in the pore-growth of carbon fibers during activation. The results confirm that micro-nanobubbles increase specific surface (39.21 %) and micropore (16.44 %) areas of a sample. The chemical state of the elements revealed that there were no marked impurities. The observed behaviors can be understood by the following; 1) Partial O atoms released from dissolved micro-nanobubbles may attach to surrounding CO during activation, thereafter results in a higher mass of CO2. 2) Partial O atoms may directly interact with C from unmatured crystallites and form additional CO. We further denote optimized conditions based on the derived mechanism. This study provides a new strategy for the development of highly surface carbonaceous materials, thus possibly stimulating more research on advanced performance adsorbents or electrode materials.



2013 ◽  
Vol 51 (12) ◽  
pp. 913-920 ◽  
Author(s):  
Han-Ik Joh ◽  
Hae Kyung Song ◽  
Ki-Young Kim ◽  
Bon-Cheol Ku ◽  
Phil-Hyun Kang ◽  
...  


2020 ◽  
Vol 6 (16) ◽  
pp. eaaz0906 ◽  
Author(s):  
Tianyu Liu ◽  
Joel Serrano ◽  
John Elliott ◽  
Xiaozhou Yang ◽  
William Cathcart ◽  
...  

Capacitive deionization (CDI) is energetically favorable for desalinating low-salinity water. The bottlenecks of current carbon-based CDI materials are their limited desalination capacities and time-consuming cycles, caused by insufficient ion-accessible surfaces and retarded electron/ion transport. Here, we demonstrate porous carbon fibers (PCFs) derived from microphase-separated poly(methyl methacrylate)-block-polyacrylonitrile (PMMA-b-PAN) as an effective CDI material. PCF has abundant and uniform mesopores that are interconnected with micropores. This hierarchical porous structure renders PCF a large ion-accessible surface area and a high desalination capacity. In addition, the continuous carbon fibers and interconnected porous network enable fast electron/ion transport, and hence a high desalination rate. PCF shows desalination capacity of 30 mgNaCl g−1PCF and maximal time-average desalination rate of 38.0 mgNaCl g−1PCF min−1, which are about 3 and 40 times, respectively, those of typical porous carbons. Our work underlines the promise of block copolymer–based PCF for mutually high-capacity and high-rate CDI.



2017 ◽  
Vol 245 ◽  
pp. 166-170 ◽  
Author(s):  
Davide Calestani ◽  
Marco Villani ◽  
Maurizio Culiolo ◽  
Davide Delmonte ◽  
Nicola Coppedè ◽  
...  


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