scholarly journals Three-dimensional optimisation of a fuel gas channel of a proton exchange membrane fuel cell for maximum current density

2011 ◽  
Vol 37 (3) ◽  
pp. 228-241 ◽  
Author(s):  
Surajudeen Olanrewaju Obayopo ◽  
Tunde Bello-Ochende ◽  
Josua Petrus Meyer

2021 ◽  
Vol 118 (43) ◽  
pp. e2107332118
Author(s):  
Xian Wang ◽  
Yang Li ◽  
Ying Wang ◽  
Hao Zhang ◽  
Zhao Jin ◽  
...  

The CO electrooxidation is long considered invincible in the proton exchange membrane fuel cell (PEMFC), where even a trace level of CO in H2 seriously poisons the anode catalysts and leads to huge performance decay. Here, we describe a class of atomically dispersed IrRu-N-C anode catalysts capable of oxidizing CO, H2, or a combination of the two. With a small amount of metal (24 μgmetal⋅cm−2) used in the anode, the H2 fuel cell performs its peak power density at 1.43 W⋅cm−2. When operating with pure CO, this catalyst exhibits its maximum current density at 800 mA⋅cm−2, while the Pt/C-based cell ceases to work. We attribute this exceptional catalytic behavior to the interplay between Ir and Ru single-atom centers, where the two sites act in synergy to favorably decompose H2O and to further facilitate CO activation. These findings open up an avenue to conquer the formidable poisoning issue of PEMFCs.



Química Nova ◽  
2021 ◽  
Author(s):  
Shi Lei ◽  
Zheng Minggang

In this paper, the influence of the optimization for flow field size on the proton exchange membrane fuel cell (PEMFC) performance under the inadequate air supply of cathode was studied based on the three-dimensional, steady-state, and constant temperature PEMFC monomer model. Additionally, the effect of the optimization for hybrid factors, including length, width, depth and width-depth, on the PEMFC performance was also investigated. The results showed that the optimization of the flow field size can improve the performance of the PEMFC and ensure that it is close to the level under the normal gas supply.



Author(s):  
Utku Gulan ◽  
Hasmet Turkoglu ◽  
Irfan Ar

In this study, the fluid flow and cell performance in cathode side of a proton exchange membrane (PEM) fuel cell were numerically analyzed. The problem domain consists of cathode gas channel, cathode gas diffusion layer, and cathode catalyst layer. The equations governing the motion of air, concentration of oxygen, and electrochemical reactions were numerically solved. A computer program was developed based on control volume method and SIMPLE algorithm. The mathematical model and program developed were tested by comparing the results of numerical simulations with the results from literature. Simulations were performed for different values of inlet Reynolds number and inlet oxygen mole fraction at different operation temperatures. Using the results of these simulations, the effects of these parameters on the flow, oxygen concentration distribution, current density and power density were analyzed. The simulations showed that the oxygen concentration in the catalyst layer increases with increasing Reynolds number and hence the current density and power density of the PEM fuel cell also increases. Analysis of the data obtained from simulations also shows that current density and power density of the PEM fuel cell increases with increasing operation temperature. It is also observed that increasing the inlet oxygen mole fraction increases the current density and power density.



1999 ◽  
Author(s):  
C. Y. Wang ◽  
Z. H. Wang ◽  
Y. Pan

Abstract Proton exchange membrane (PEM) fuel cells have emerged, in the last decade, as a viable technology for power generation and energy conversion. Fuel cell (FC) engines for vehicular applications possess many attributes such as high fuel efficiency, low emission, quiet and low temperature operation, and modularity. An important phenomenon limiting fuel cell performance is the two-phase flow and transport of fuel and oxidant from flow channels to reaction sites. In this paper a mathematical model is presented to study the two-phase flow dynamics, multi-component transport and electrochemical kinetics in the air cathode, the most important component of the hydrogen PEM fuel cell. A major feature of the present model is that it unifies single- and two-phase analyses for low and high current densities, respectively, and it is capable of predicting the threshold current density corresponding to the onset of liquid water formation in the air cathode. A numerical study based on the finite volume method is then undertaken to calculate the detailed distributions of local current density, oxygen concentration, water vapor concentration and liquid water saturation as well as their effects on the cell polarization curve. The simulated polarization curve and predicted threshold current density corresponding to the onset of liquid water formation for a single-channel, 5cm2 fuel cell compare favorably with experimental results. Quantitative comparisons with experiments presently being conducted at our laboratory will be reported in a forthcoming paper.



2019 ◽  
Vol 969 ◽  
pp. 461-465
Author(s):  
Matha Prasad Adari ◽  
P. Lavanya ◽  
P. Hara Gopal ◽  
T.Praveen Sagar ◽  
S. Pavani

Proton exchange membrane fuel cell (PEMFC) system is an advanced power system for the future that is sustainable, clean and environmental friendly. The flow channels present in bipolar plates of a PEMFC are responsible for the effective distribution of the reactant gases. Uneven distribution of the reactants can cause variations in current density, temperature, and water content over the area of a PEMFC, thus reducing the performance of PEMFC. By using Serpentine flow field channel, the performance is increased. Two types of serpentine flow field channels are implemented such as curved serpentine flow field channel and normal serpentine flow field channels. The result shows that curved serpentine flow field channel gives better current density and power density, thus increasing the performance of PEMFC.



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