scholarly journals What controls the isotopic composition of tropical tropospheric water vapor? Results from general circulation models and large-eddy simulations, and thoughts on the usefulness of the isotopic tool

2020 ◽  
Author(s):  
Camille Risi ◽  
Caroline Muller ◽  
Peter Blossey
Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4468
Author(s):  
Yalalt Nyamgerel ◽  
Yeongcheol Han ◽  
Minji Kim ◽  
Dongchan Koh ◽  
Jeonghoon Lee

The triple oxygen isotopes (16O, 17O, and 18O) are very useful in hydrological and climatological studies because of their sensitivity to environmental conditions. This review presents an overview of the published literature on the potential applications of 17O in hydrological studies. Dual-inlet isotope ratio mass spectrometry and laser absorption spectroscopy have been used to measure 17O, which provides information on atmospheric conditions at the moisture source and isotopic fractionations during transport and deposition processes. The variations of δ17O from the developed global meteoric water line, with a slope of 0.528, indicate the importance of regional or local effects on the 17O distribution. In polar regions, factors such as the supersaturation effect, intrusion of stratospheric vapor, post-depositional processes (local moisture recycling through sublimation), regional circulation patterns, sea ice concentration and local meteorological conditions determine the distribution of 17O-excess. Numerous studies have used these isotopes to detect the changes in the moisture source, mixing of different water vapor, evaporative loss in dry regions, re-evaporation of rain drops during warm precipitation and convective storms in low and mid-latitude waters. Owing to the large variation of the spatial scale of hydrological processes with their extent (i.e., whether the processes are local or regional), more studies based on isotopic composition of surface and subsurface water, convective precipitation, and water vapor, are required. In particular, in situ measurements are important for accurate simulations of atmospheric hydrological cycles by isotope-enabled general circulation models.


2019 ◽  
Author(s):  
Camille Risi ◽  
Joseph Galewsky ◽  
Gilles Reverdin ◽  
Florent Brient

Abstract. Understanding what controls the water vapor isotopic composition of the sub-cloud layer (SCL) over tropical oceans (δD0) is a first step towards understanding the water vapor isotopic composition everywhere in the troposphere. We propose an analytical model to predict δD0 as a function of sea surface conditions, humidity and temperature profiles, and the altitude from which the free tropospheric air originates (zorig). To do so, we extend previous studies by (1) prescribing the shape of δD0 vertical profiles, and (2) linking δD0 to zorig. The model relies on the hypotheses that δD0 profiles are steeper than mixing lines and no clouds are precipitating. We show that δD0 does not depend on the intensity of entrainment, dampening hope that δD0 measurements could help constrain this long-searched quantity. Based on an isotope-enabled general circulation model simulation, we show that δD0 variations are mainly controlled by mid-tropospheric depletion and rain evaporation in ascending regions, and by sea surface temperature and zorig in subsiding regions. When the air mixing into the SCL is lower in altitude, it is moister, and thus it depletes more efficiently the SCL. In turn, could δD0 measurements help estimate zorig and thus discriminate between different mixing processes? Estimates that are accurate enough to be useful would be difficult to achieve in practice, requiring measuring daily δD profiles, and measuring δD0 with an accuracy of 0.1 ‰ and 0.4 ‰ in trade-wind cumulus and strato-cumulus clouds respectively.


2007 ◽  
Vol 20 (4) ◽  
pp. 739-756 ◽  
Author(s):  
M. M. Helsen ◽  
R. S. W. Van de Wal ◽  
M. R. Van den Broeke

Abstract The isotopic composition of present-day Antarctic snow is simulated for the period September 1980–August 2002 using a Rayleigh-type isotope distillation model in combination with backward trajectory calculations with 40-yr European Centre for Medium-Range Weather Forecasts (ECMWF) Re-Analysis (ERA-40) data as meteorological input. Observed spatial isotopic gradients are correctly reproduced, especially in West Antarctica and in the coastal areas. However, isotopic depletion of snow on the East Antarctic plateau is underestimated, a problem that is also observed in general circulation models equipped with isotope tracers. The spatial isotope–temperature relation varies strongly, which indicates that this widely used relation is not applicable to all sites and temporal scales. Spatial differences in the seasonal amplitude are identified, with maximum values in the Antarctic interior and hardly any seasonal isotope signature in Marie Byrd Land, West Antarctica. The modeled signature of deuterium excess remains largely preserved during the last phase of transport, though the simulated relation of deuterium excess with δ18O suggests that parameterizations of kinetic isotopic fractionation can be improved.


2004 ◽  
Vol 39 ◽  
pp. 293-299 ◽  
Author(s):  
Michiel M. Helsen ◽  
Roderik S. W. Van De Wal ◽  
Michiel R. Van Den Broeke ◽  
Erik R. Th. Kerstel ◽  
Valérie Masson-Delmotte ◽  
...  

AbstractWe consider a specific accumulation event that occurred in January 2002 in western Dronning Maud Land, Antarctica. Snow samples were obtained a few days after accumulation. We combine meteorological analyses and isotopic modelling to describe the isotopic composition of moisture during transport. Backward trajectories were calculated, based on European Centre for Medium-Range Weather Forecasts operational archive data so that the history of the air parcels transporting water vapour to the accumulation site could be reconstructed. This trajectory study showed that the air masses were not (super)saturated along most of the transport path, which is in contrast with assumptions in Lagrangian fractionation models and probably true for most precipitation events in Antarctica. The modelled fractionation along the trajectories was too limited to explain the measured isotopic content of the snow. It is shown that the observed isotopic composition of precipitation resulted from fractionation of initially more depleted water. This lower initial isotopic composition of water vapour might result from atmospheric mixing with more depleted air along the trajectory or from earlier condensation cycles, not captured by the trajectories. This is in accordance with isotope fields resulting from general circulation models, indicating a gradient in isotopic composition from the Equator to Antarctica.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Xiaoxin Yang ◽  
Tandong Yao

Abstract This study integrated isotopic composition in precipitation at 50 stations on and around the Tibetan Plateau (TP) and demonstrated the distinct seasonality of isotopic composition in precipitation across the study period. The potential effect of water vapor isotopes on precipitation isotopes is studied by comparing the station precipitation data with extensive isotopic patterns in atmospheric water vapor, revealing the close linkage between the two. The analysis of contemporary water vapor transport and potential helps confirm the different mechanisms behind precipitation isotopic compositions in different areas, as the southern TP is more closely related to large-scale atmospheric circulation such as local Hadley and summer monsoon circulations during other seasons than winter, while the northern TP is subject to the westerly prevalence and advective moisture supply and precipitation processes. The new data presented in this manuscript also enrich the current dataset for the study of precipitation isotopes in this region and together provide a valuable database for verification of the isotope-integrated general circulation model and explanation of related physical processes.


Author(s):  
Subin Thomas ◽  
Prasanth Prabhakaran ◽  
Will Cantrell ◽  
Raymond A. Shaw

AbstractWater vapor supersaturation in the atmosphere is produced in a variety of ways, including the lifting of a parcel or via isobaric mixing of parcels. However, irrespective of the mechanism of production, the water vapor supersaturation in the atmosphere has typically been modeled as a Gaussian distribution. In the current theoretical and numerical study, the nature of supersaturation produced by mixing processes is explored. The results from large eddy simulation and a Gaussian mixing model reveal the distribution of supersaturations produced by mixing to be negatively skewed. Further, the causes of skewness are explored using large eddy simulations (LES) and the Gaussian mixing model (GMM). The correlation in forcing of temperature and water vapor fields is recognized as playing a key role.


2012 ◽  
Vol 25 (11) ◽  
pp. 3755-3770 ◽  
Author(s):  
Anthony D. Del Genio ◽  
Yonghua Chen ◽  
Daehyun Kim ◽  
Mao-Sung Yao

The relationship between convective penetration depth and tropospheric humidity is central to recent theories of the Madden–Julian oscillation (MJO). It has been suggested that general circulation models (GCMs) poorly simulate the MJO because they fail to gradually moisten the troposphere by shallow convection and simulate a slow transition to deep convection. CloudSat and Cloud–Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) data are analyzed to document the variability of convection depth and its relation to water vapor during the MJO transition from shallow to deep convection and to constrain GCM cumulus parameterizations. Composites of cloud occurrence for 10 MJO events show the following anticipated MJO cloud structure: shallow and congestus clouds in advance of the peak, deep clouds near the peak, and upper-level anvils after the peak. Cirrus clouds are also frequent in advance of the peak. The Advanced Microwave Scanning Radiometer for Earth Observing System (EOS) (AMSR-E) column water vapor (CWV) increases by ~5 mm during the shallow–deep transition phase, consistent with the idea of moisture preconditioning. Echo-top height of clouds rooted in the boundary layer increases sharply with CWV, with large variability in depth when CWV is between ~46 and 68 mm. International Satellite Cloud Climatology Project cloud classifications reproduce these climatological relationships but correctly identify congestus-dominated scenes only about half the time. A version of the Goddard Institute for Space Studies Model E2 (GISS-E2) GCM with strengthened entrainment and rain evaporation that produces MJO-like variability also reproduces the shallow–deep convection transition, including the large variability of cloud-top height at intermediate CWV values. The variability is due to small grid-scale relative humidity and lapse rate anomalies for similar values of CWV.


2020 ◽  
Author(s):  
David R. Thompson ◽  
Brian H. Kahn ◽  
Philip G. Brodrick ◽  
Matthew D. Lebsock ◽  
Mark Richardson ◽  
...  

Abstract. Understanding the subgrid spatial variability of water vapor is important for parameterizing and simulating cloud processes in General Circulation Models (GCMs). This study maps sub-kilometer spatial structures in total atmospheric column water vapor with Visible to Shortwave Infrared (VSWIR) imaging spectroscopy. We describe our inversion approach and validate its accuracy with coincident measurements by airborne imaging spectrometers and the AERONET ground-based observation network. Next, data from NASA’s AVIRIS-NG spectrometer enables the highest resolution measurement to date of water vapor’s spatial variability and scaling properties. We find second order structure function scaling exponents consistent with prior studies of convective atmospheres. Finally, we conclude by discussing the implications of these measurements and paths toward future campaigns to build upon these results.


2012 ◽  
Vol 117 (D5) ◽  
pp. n/a-n/a ◽  
Author(s):  
Camille Risi ◽  
David Noone ◽  
John Worden ◽  
Christian Frankenberg ◽  
Gabriele Stiller ◽  
...  

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