Analyzing Variations in the Association of Eurasian Winter–Spring Snow Water Equivalent and Autumn Arctic Sea Ice

Because Eurasian snow water equivalent (SWE) is a key factor affecting the climate in the Northern Hemisphere, understanding the distribution characteristics of Eurasian SWE is important. Through empirical orthogonal function (EOF) analysis, we found that the first and second modes of Eurasian winter SWE present the distribution characteristics of an east–west dipole and north–south dipole, respectively. Moreover, the distribution of the second mode is caused by autumn Arctic sea ice, with the distribution of the north–south dipole continuing into spring. As the sea ice of the Barents–Kara Sea (BKS) decreases, a negative-phase Arctic oscillation (AO) is triggered over the Northern Hemisphere in winter, with warm and humid water vapor transported via zonal water vapor flux over the North Atlantic to southwest Eurasia, encouraging the accumulation of SWE in the southwest. With decreases in BKS sea ice, zonal water vapor transport in northern Eurasia is weakened, with meridional water vapor flux in northern Eurasia obstructing water vapor transport from the North Atlantic, discouraging the accumulation of SWE in northern Eurasia in winter while helping preserve the cold climate of the north. The distribution characteristics of Eurasian spring SWE are determined primarily by the memory effect of winter SWE. Whether analyzed through linear regression or support vector machine (SVM) methods, BKS sea ice is a good predictor of Eurasian winter SWE.

Investigation of the Side Chain Effect on Gas and Water Vapor Transport Properties of Anthracene-Maleimide Based Polymers of Intrinsic Microporosity

In the present work, a set of anthracene maleimide monomers with different aliphatic side groups obtained by Diels Alder reactions were used as precursors for a series of polymers of intrinsic microporosity (PIM) based homo- and copolymers that were successfully synthesized and characterized. Polymers with different sizes and shapes of aliphatic side groups were characterized by size-exclusion chromatography (SEC), (nuclear magnetic resonance) 1H-NMR, thermogravimetric (TG) analysis coupled with Fourier-Transform-Infrared (FTIR) spectroscopy (TG-FTIR) and density measurements. The TG-FTIR measurement of the monomer-containing methyl side group revealed that the maleimide group decomposes prior to the anthracene backbone. Thermal treatment of homopolymer methyl-100 thick film was conducted to establish retro-Diels Alder rearrangement of the homopolymer. Gas and water vapor transport properties of homopolymers and copolymers were investigated by time-lag measurements. Homopolymers with bulky side groups (i-propyl-100 and t-butyl-100) experienced a strong impact of these side groups in fractional free volume (FFV) and penetrant permeability, compared to the homopolymers with linear alkyl side chains. The effect of anthracene maleimide derivatives with a variety of aliphatic side groups on water vapor transport is discussed. The maleimide moiety increased the water affinity of the homopolymers. Phenyl-100 exhibited a high water solubility, which is related to a higher amount of aromatic rings in the polymer. Copolymers (methyl-50 and t-butyl-50) showed higher CO2 and CH4 permeability compared to PIM-1. In summary, the introduction of bulky substituents increased free volume and permeability whilst the maleimide moiety enhanced the water vapor affinity of the polymers.

The Characterization of Haze and Dust Processes Using MAX-DOAS in Beijing, China

Haze and dust pollution have a significant impact on human production, life, and health. In order to understand the pollution process, the study of these two pollution characteristics is important. In this study, a one-year observation was carried out at the Beijing Southern Suburb Observatory using the MAX-DOAS instrument, and the pollution characteristics of the typical haze and dust events were analyzed. First, the distribution of aerosol extinction (AE) and H2O concentrations in the two typical pollution events were studied. The results showed that the correlation coefficient (r) between H2O and AE at different heights decreased during dust processes and the correlation slope (|k|) increased, whereas r increased and |k| decreased during haze periods. The correlation slope increased during the dust episode due to low moisture content and increased O4 absorption caused by abundant suspended dry crustal particles, but decreased during the haze episode due to a significant increase of H2O absorption. Secondly, the gas vertical column density (VCD) indicated that aerosol optical depth (AOD) increased during dust pollution events in the afternoon, while the H2O VCD decreased; in haze pollution processes, both H2O VCD and AOD increased. There were significant differences in meteorological conditions during haze (wind speed (WD) was <2 m/s, and relative humidity (RH) was >60%) and dust pollution (WD was >4 m/s, and RH was <60%). Next, the vertical distribution characteristics of gases during the pollution periods were studied. The AE profile showed that haze pollution lasted for a long time and changed slowly, whereas the opposite was true for dust pollution. The pollutants (aerosols, NO2, SO2, and HCHO) and H2O were concentrated below 1 km during both these typical pollution processes, and haze pollution was associated with a strong temperature inversion around 1.0 km. Lastly, the water vapor transport fluxes showed that the water vapor transport from the eastern air mass had an auxiliary effect on haze pollution at the observation location. Our results are of significance for exploring the pollution process of tropospheric trace gases and the transport of water vapor in Beijing, and provide a basis for satellite and model verification.

Characteristics of the Water Vapor Transport in the Canyon Area of the Southeastern Tibetan Plateau

Changes in the surface fluxes cause changes in the annular flow field over a region, and they affect the transport of water vapor. To study the influence of the changes in the surface flux on the water vapor transport in the upper layer in the canyon area of southeastern Tibet, in this study, the water vapor transport characteristics were analyzed using the HYSPLIT_v4 backward trajectory model at Danka and Motuo stations in the canyons in the southeastern Tibetan Plateau from November 2018 to October 2019. Then, using ERA-5 reanalysis data from 1989 to 2019 and the characteristics of the high-altitude water vapor transportation, the impact of the surface flux changes on the water vapor transportation was analyzed using singular value decomposition (SVD). The results show that the main sources of the water vapor in the study area were from the west and southwest during the non-Asian monsoon (non-AMS), while there was mainly southwest air flow and a small amount of southeast air flow in the lower layer during the Asian monsoon (AMS) at the stations in southeastern Tibet. The water vapor transmission channel of the westward airflow is higher than 3000 m, and the water vapor transmission channel of the southwestward and southeastward airflow is about 2000 m. The sensible heat and latent heat are negatively correlated with water vapor flux divergence. The southwest boundary of southeastern Tibet is a key area affecting water vapor flux divergence. When the sensible heat and latent heat exhibit downward trends during the non-Asian monsoon season, the eastward water vapor flux exhibits an upward trend. During the Asian monsoon season, when the sensible heat and latent heat in southeastern Tibet increase as a whole, the eastward water vapor flux in the total-column of southeastern Tibet increases.

Incorporating decadal climate variability information in the operation and design of water infrastructure

The high thermal and mechanical inertia of the oceans results in slow changes in sea surface temperatures (SSTs). Changes in SSTs, in turn, can impact atmospheric circulation including water vapor transport, precipitation, and temperatures throughout the world. The Pacific Decadal Oscillation (PDO), the tropical Atlantic SST gradient variability, and the West Pacific Warm Pool are patterns of natural climate variability that tend to persist over decadal time periods. There are current efforts to produce decadal climate predictions, but there is limited understanding if this information can be used in water resources management. Understanding the current state of decadal climate variability (DCV) phenomena and the probability of persisting in that state may be useful information for water managers. This information could improve forecasts that aid operations and short-term planning for reservoir management, domestic and industrial water supplies, flood risk management, energy production, recreation, inland navigation, and irrigation. If conditions indicate a higher likelihood of drought, reservoir managers could reduce flood storage space and increase storage for conservation purposes. Improved forecasts for irrigation could result in greater efficiencies by shifting crops and rotational crop patterns. The potential benefits of using a forecast must be balanced against the risk of damages if the forecast is wrong. Seasonal forecasts using DCV information could also be used to inform drought triggers. If DCV indices indicate that the climate has a higher probability of dry conditions, drought contingency plans could be triggered earlier. Understanding of DCV phenomena could also improve long-range water resources planning. DCV can manifest itself in relatively short-term hydrologic records as linear trends that complicate hydrologic frequency analysis, which has traditionally assumed that hydrologic records are stationary.

Modulation of coupled modes of Tibetan Plateau heating and Indian Summer Monsoon on summer rainfall over Central Asia

It has been suggested that summer rainfall over Central Asia (CA) is significantly correlated with the summer thermal distribution of the Tibetan Plateau (TP) and the Indian summer monsoon (ISM). However, relatively few studies have investigated their synergistic effects of different distribution. This study documents the significant correlations between precipitation in CA and the diabatic heating of TP and the ISM based on the results of statistical analysis and numerical simulation. Precipitation in CA is is dominated by two water vapor transport branches from the south which are related to the two primary modes of anomalous diabatic heating distribution related to the TP and ISM precipitation, that is, the “+-” dipole mode in the southeastern TP and the Indian subcontinent (IS), and the “+-+” tripole mode in the southeastern TP, the IS, and southern India. Both modes exhibit obvious mid-latitude Silk Road pattern (SRP) wave trains with cyclone anomalies over CA, but with different transient and stationary eddies over south Asia. The different locations of anomalous anticyclones over India govern two water vapor transport branches to CA, which are from the Arabian Sea and the Bay of Bengal. The water vapor flux climbs while being transported northward and can be transported to CA with the cooperation of cyclonic circulation. The convergent water vapor and ascending motion caused by cyclonic anomalies favor the precipitation in CA. Further analysis corroborates the negative South Indian Ocean Dipole (NSIOD) in February could affect the tripole mode distribution of TP heating and ISM via the atmospheric circulation, water vapor transport and an anomalous Hadley cell circulation. The results indicate a reliable prediction reference for precipitation in CA.

Atmospheric River Representation in the Energy Exascale Earth System Model (E3SM) Version 1.0

The Energy Exascale Earth System Model (E3SM) Project is an ongoing, state-of-the-science Earth system modeling, simulation, and prediction project developed by the U.S. Department of Energy (DOE). With an emphasis on supporting DOE's energy mission, understanding and quantifying how well the model simulates water cycle processes is of particular importance. Here, we evaluate E3SM version v1.0 for its ability to represent atmospheric rivers (ARs), which play significant roles in water vapor transport and precipitation. The characteristics and precipitation associated with global ARs in E3SM at standard resolution (1° × 1°) are compared to the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA2). Global pattern of AR frequencies in E3SM show high degrees of correlation (>= 0.97) with MERRA2 and low mean absolute errors (< 1 %) annually, seasonally, and across different ensemble members. However, some large-scale condition biases exist leading to AR biases - most significant of which are: the double-ITCZ, a stronger and/or equatorward shifted subtropical jet during boreal and austral winter, and enhanced northern hemisphere westerlies during summer. By comparing atmosphere-only and fully coupled simulations, we attribute the sources of the biases to the atmospheric component or to a coupling response. Using relationships revealed in Dong et al. (2021), we provide evidence showing the stronger north Pacific jet in winter and enhanced northern hemisphere westerlies during summer associated with E3SM's double-ITCZ and related weaker AMOC, respectively, are the sources of much of the AR biases found in the coupled simulations.

Melatonin and Pathological Cell Interactions: Mitochondrial Glucose Processing in Cancer Cells

The Tibetan Plateau (TP), atmosphere, and Indo-Pacific warm pool (IPWP) together constitute a regional land–atmosphere–ocean water vapor transport system. This study uses remote sensing data, reanalysis data, and observational data to explore the spatiotemporal variations of the summer atmospheric water cycle over the TP and its possible response to the air–sea interaction in the IPWP during the period 1958–2019. The results reveal that the atmospheric water cycle process over the TP presented an interannual and interdecadal strengthening trend. The climatic precipitation recycle ratio (PRR) over the TP was 18%, and the stronger the evapotranspiration, the higher the PRR. On the interdecadal scale, the change in evapotranspiration has a significant negative correlation with the Pacific Decadal Oscillation (PDO) index. The variability of the water vapor transport (WVT) over the TP was controlled by the dynamic and thermal conditions inside the plateau and the external air–sea interaction processes of the IPWP. When the summer monsoon over the TP was strong, there was an anomalous cyclonic WVT, which increased the water vapor budget (WVB) over the TP. The central and eastern tropical Pacific, the maritime continent and the western Indian Ocean together constituted the triple Sea Surface Temperature (SST) anomaly, which enhanced the convective activity over the IPWP and induced a significant easterly wind anomaly in the middle and lower troposphere, and then generated pronounced easterly WVT anomalies from the tropical Pacific to the maritime continent and the Bay of Bengal. Affected by the air–sea changes in the IPWP, the combined effects of the upstream strengthening and the downstream weakening in the water vapor transport process, directly and indirectly, increased the water vapor transport and budget of TP.

The Variability of Summer Atmospheric Water Cycle over the Tibetan Plateau and Its Response to the Indo-Pacific Warm Pool

The Tibetan Plateau (TP), atmosphere, and Indo-Pacific warm pool (IPWP) together constitute a regional land–atmosphere–ocean water vapor transport system. This study uses remote sensing data, reanalysis data, and observational data to explore the spatiotemporal variations of the summer atmospheric water cycle over the TP and its possible response to the air-sea interaction in the IPWP during the period 1958–2019. The results reveal that the atmospheric water cycle process over the TP presented an interannual and interdecadal strengthening trend. The climatic precipitation recycle ratio (PRR) over the TP was 18%, and the stronger the evapotranspiration, the higher the PRR. On the interdecadal scale, the change in evapotranspiration has a significant negative correlation with the Pacific Decadal Oscillation (PDO) index. The variability of the water vapor transport (WVT) over the TP was controlled by the dynamic and thermal conditions inside the plateau and the external air-sea interaction processes of the IPWP. When the summer monsoon over the TP was strong, there was an anomalous cyclonic WVT, which increased the water vapor budget (WVB) over the TP. The central and eastern tropical Pacific, the maritime continent and the western Indian Ocean together constituted the triple Sea Surface Temperature (SST) anomaly, which enhanced the convective activity over the IPWP and induced a significant easterly wind anomaly in the middle and lower troposphere, and then generated pronounced easterly WVT anomalies from the tropical Pacific to the maritime continent and the Bay of Bengal. Affected by the air-sea changes in the IPWP, the combined effects of the upstream strengthening and the downstream weakening in the water vapor transport process, directly and indirectly, increased the water vapor transport and budget of TP.