scholarly journals Matrix Diffusion as a Mechanism Contributing to Fractal Stream Chemistry

2021 ◽  
Author(s):  
Harihar Rajaram
1992 ◽  
Vol 23 (1) ◽  
pp. 13-26 ◽  
Author(s):  
W. H. Hendershot ◽  
L. Mendes ◽  
H. Lalande ◽  
F. Courchesne ◽  
S. Savoie

In order to determine how water flowpath controls stream chemistry, we studied both soil and stream water during spring snowmelt, 1985. Soil solution concentrations of base cations were relatively constant over time indicating that cation exchange was controlling cation concentrations. Similarly SO4 adsorption-desorption or precipitation-dissolution reactions with the matrix were controlling its concentrations. On the other hand, NO3 appeared to be controlled by uptake by plants or microorganisms or by denitrification since their concentrations in the soil fell abruptly as snowmelt proceeded. Dissolved Al and pH varied vertically in the soil profile and their pattern in the stream indicated clearly the importance of water flowpath on stream chemistry. Although Al increased as pH decreased, the relationship does not appear to be controlled by gibbsite. The best fit of calculated dissolved inorganic Al was obtained using AlOHSO4 with a solubility less than that of pure crystalline jurbanite.


2004 ◽  
Vol 3 (1) ◽  
pp. 312 ◽  
Author(s):  
H. H. Liu ◽  
G. S. Bodvarsson ◽  
G. Zhang

Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1464
Author(s):  
Haiping Wang ◽  
Dong Liu ◽  
Jianguo Wang ◽  
Yanhui Yang ◽  
Haodong Rao ◽  
...  

The formation of the irregular γ′ precipitates in the nickel-based superalloy Waspaloy was investigated during the continuous cooling, which is relevant to the cooling rates and interrupted temperature. The morphology of the γ′ precipitates was observed to change from a dispersed sphere to the flower-like one with the decreasing of the cooling rates. It was found that there are three modes of transportation of the solute atoms involved in relation to the γ′ precipitates: dissolution from the small γ′ precipitates to the γ matrix, diffusion to the large γ′ precipitates from the matrix, and the short distance among γ′ precipitates close to each other. Meanwhile, the slower cooling rates tend to result in the serrated grain boundaries, and the wavelength between successive peaks (λ) and the maximum amplitude (A) are larger with the decreasing of the cooling rates. The content of the low ΣCSL boundaries increases with the decreasing of the cooling rates, which is of great benefit in improving the creep property of the Waspaloy.


2004 ◽  
Vol 3 (1) ◽  
pp. 312-315 ◽  
Author(s):  
H. H. Liu ◽  
G. S. Bodvarsson ◽  
G. Zhang

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