Determination of organic acids and ketones in contaminated soils

1994 ◽  
Vol 17 (5) ◽  
pp. 293-298 ◽  
Author(s):  
Arno Langbehn ◽  
Hans Steinhart
Author(s):  
N. N. Loy ◽  
S. N. Gulina

The effect of presowing seed treatment on various concentrations of dicarboxylic (organic) acids on the sowing characteristics of spring barley has been studied. Seeds were treated with organic acids obtained by exposing cuttings to the radiation with a dose of 100 kGy and consequent hydrolysis, in concentrations: 1•10-7 %; 1•10-9; 1•10-11; 1•10-13 and 1•10-15 % on a laboratory rotary machine RVO-64 for one day before laying for germination. Distilled water was used for the control case. The rate of application of the working solution calculated as 10 liters / ton of seeds. Seeds were germinated in filter paper rolls in accordance with GOST 12038-84 requirements. The temperature was maintained at +24 ° C in the thermostat where the glasses with rolls were placed. For determination of germinative power and laboratory germination the sprouted seeds were evaluated after three and seven days, respectively. In laboratory experiments it was established that the treatment of barley seeds of varieties Zazersky 85, Nur and Vladimir with organic acids (OK) in different concentrations had both a stimulating and a negative effect. On the Zazersky 85 variety, in variants with acid concentrations of 1•10-9 and 1•10-11, an increase in germination energy (EP) by 2-4% and a significant decrease (by 3-4%) of laboratory germination (LV) of barley seeds were noted. On the Nur variety, the increase in EP was observed at 4% (concentration 1•10-11), LV and seed growth force (CPC) by 2-7% at a concentration of 1•10-7 and in the dose range 1•10-11 - 1•10-14 compared to the control values. On the grade of Vladimir, an increase in EP, LV, and CPC was found to increase by 1-6% at concentrations OK 1•10-7 and 1•10-13. It was shown that the treatment of seeds with acids led to an increase in the length of the germ in all studied varieties (by 3-9%) and dry biomass of 7-day-old seedlings - by 3-6%. Consequently, the treatment of seeds with a mixture of dicarboxylic acids has a stimulating effect on the sowing quality of spring barley.


Author(s):  
Nafea A. ◽  
Zidan W. ◽  
Asmaa Fawzy ◽  
Sehata A.
Keyword(s):  

2021 ◽  
Vol 11 (4) ◽  
pp. 1799
Author(s):  
Claudio Cameselle ◽  
Susana Gouveia ◽  
Adrian Cabo

The electrokinetic remediation of an agricultural soil contaminated with heavy metals was studied using organic acids as facilitating agents. The unenhanced electrokinetic treatment using deionized water as processing fluid did not show any significant mobilization and removal of heavy metals due to the low solubilization of metals and precipitation at high pH conditions close to the cathode. EDTA and citric acid 0.1 M were used as facilitating agents to favor the dissolution and transportation of metals. The organic acids were added to the catholyte and penetrated into the soil specimen by electromigration. EDTA formed negatively charged complexes. Citric acid formed neutral metal complexes in the soil pH conditions (pH = 2–4). Citric acid was much more effective in the dissolution and transportation out of the soil specimen of complexed metals. In order to enhance the removal of metals, the concentration of citric acid was increased up to 0.5 M, resulting in the removal of 78.7% of Cd, 78.6% of Co, 72.5% of Cu, 73.3% of Zn, 11.8% of Cr and 9.8% of Pb.


1998 ◽  
Vol 61 (4) ◽  
pp. 449-453 ◽  
Author(s):  
Valérie Magne ◽  
Mohamed Mathlouthi ◽  
Bertrand Robilland

2014 ◽  
Vol 97 (2) ◽  
pp. 498-505 ◽  
Author(s):  
Steve Kupina ◽  
Mark Roman ◽  
D Anderson ◽  
S Bhandari ◽  
M S Cardozo ◽  
...  

Abstract An international collaborative study was conducted of an HPLC-refractive index (RI) detector method for the determination of the combined amounts of sugars, glycerol, organic acids, and phenolic compounds in wines and wine-like beverages. Nine collaboratinglaboratories representing major winery, contract laboratories, and government laboratories tested eight different materials as blind duplicates using the proposed method. Sample materials included red and white wines, port, wine cooler, and nonalcoholic wine. One material was a negative control, and one material was a reference material. Samples were either treated with an ion-exchange resin to remove interferingorganic acids prior to analysis or left untreated toinclude organic acids and phenolics. Red wine samples were treated with polyvinylpolypyrrolidone to remove potential interferences from phenolics prior to analysis. The HPLC analyses were performed on a Bio-Rad Fast Acid Analysis Column using RI detection. Reproducibility (RSDR) for untreated samples(sugars + phenolics + organic acids) ranged from 6.6% for Titrivin AA4 reference material to 11.0% for dry red wine. RSDR for treated samples (sugars only) ranged from 6.8% for white zinfandel to 18.9% for dry white wine. RSDR for treatedsamples (sugars only) + glycerol ranged from 6.4% for white zinfandel to 19.8% for dry red wine. Based on these results, the method was adopted as Official First Action status for determination of total carbohydrates in wine and wine-like beverages.


1991 ◽  
Vol 24 (1-2) ◽  
pp. 87-94 ◽  
Author(s):  
G. Doyon ◽  
G. Gaudreau ◽  
D. St-Gelais ◽  
Y. Beaulieu ◽  
C.J. Randall

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