Formation and corrosion resistance of a novel Co–Ti–Mo composite chromium‐free chemical conversion coating on LY12 aluminum alloy

Author(s):  
Xuzheng Qian ◽  
Waner Zhao ◽  
Wen Zhan ◽  
Tianyue Zhang ◽  
Jingjing Pan ◽  
...  
2010 ◽  
Vol 129-131 ◽  
pp. 819-823
Author(s):  
Yan Bo Wu ◽  
Si Si Zeng ◽  
Peng Sun

Ti-W composite coating was made by chemical conversion method on aluminum alloy. By orthogonal experiment, the optimal coating-forming conditions were the concentration ratio of TiOSO4 and Na2WO4 was 0.3 g/L:0.3 g/L、KMnO4 1.0 g/L、NaF 1.0 g/L、reaction temperature 40°C、reaction time 2min. The morphology of the coating was observed by scanning electron microscopy (SEM). Coating composition and the microcosmic phase structure were characterized using energy dispersive X-ray (EDX) analysis and X-ray diffraction (XRD) respectively. Electrochemical test was used to study the coatings corrosion resistance. The results indicated that the composite chemical conversion coating is a crystal structure material that composites with Al、Mn、W、Ti et al., its surface appears as a accumulation of fibroid spherical particles, the crystallinity of conversion coating is better than uncoated sample obviously. The corrosion potential of the coating is improved to -0.440V, they were both prove the corrosion resistance has improved.


2010 ◽  
Vol 146-147 ◽  
pp. 208-211
Author(s):  
Yan Bo Wu ◽  
Si Si Zeng ◽  
Peng Sun

In this paper, we made two different chemical conversion coatings on aluminum alloy by TiOSO4 and Na2WO4. The morphology of the chemical conversion surface layers were observed by scanning electron microscopy (SEM). The microcosmic phase structures were characterized using X-ray diffraction (XRD). Electrochemical method was used to study the coatings corrosion resistance. The results indicated that the two conversion coatings were crystal structure material, the surface of coating were both show pothole structure. TiOSO4 coating have better corrosion resistance than Na2WO4 coating.


Coatings ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 397 ◽  
Author(s):  
Hehong Zhang ◽  
Xiaofeng Zhang ◽  
Xuhui Zhao ◽  
Yuming Tang ◽  
Yu Zuo

A chemical conversion coating on 5052 aluminum alloy was prepared by using K2ZrF6 and K2TiF6 as the main salts, KMnO4 as the oxidant and NaF as the accelerant. The surface morphology, structure and composition were analyzed by SEM, EDS, FT–IR and XPS. The corrosion resistance of the conversion coating was studied by salt water immersion and polarization curve analysis. The influence of fluorosilane (FAS-17) surface modification on its antifouling property was also discussed. The results showed that the prepared conversion coating mainly consisted of AlF3·3H2O, Al2O3, MnO2 and TiO2, and exhibited good corrosion resistance. Its corrosion potential in 3.5 wt % NaCl solution was positively shifted about 590 mV and the corrosion current density was dropped from 1.10 to 0.48 μA cm−2. By sealing treatment in NiF2 solution, its corrosion resistance was further improved yielding a corrosion current density drop of 0.04 μA cm−2. By fluorosilane (FAS-17) surface modification, the conversion coating became hydrophobic due to low-surface-energy groups such as CF2 and CF3, and the contact angle reached 136.8°. Moreover, by FAS-17 modification, the corrosion resistance was enhanced significantly and its corrosion rate decreased by about 25 times.


2019 ◽  
Vol 19 (6) ◽  
pp. 3487-3494 ◽  
Author(s):  
Bin Liu ◽  
Yi Zhao ◽  
Liang Li ◽  
Yafei Feng ◽  
Zhigang Fang ◽  
...  

An environment-friendly non-chromium chemical conversion coating was obtained from fluozirconate/fluotitanate acidic solution for the corrosion protection of AA 5083. The surface morphology, composition, electrochemical behavior and corrosion resistance of this coating were investigated. The coating was found to be a homogeneous and dense layer consisting of nano-size particles, of which the major component was compound oxides consisted by Al, Mg, Zr, Ti, F and O. The results of electrochemical measurements, immersion and natural salt spray (NSS) tests demonstrated that the corrosion resistance of the AA 5083 H-116 was improved by the nano-sized non-chromium chemical conversion coating considerably, which was most attributed to the great inhibitive action on the anodic dissolution by acting as a protective barrier layer.


2016 ◽  
Vol 40 (2) ◽  
pp. 1347-1353 ◽  
Author(s):  
Cong-cong Jiang ◽  
Gui-yong Xiao ◽  
Xian Zhang ◽  
Rui-fu Zhu ◽  
Yu-peng Lu

A uniform fine-crystalline structure is obtained upon PCC coating on 35CrMnSi with Fe2+ curing (b).


2010 ◽  
Vol 129-131 ◽  
pp. 467-471
Author(s):  
Yan Bo Wu ◽  
Si Si Zeng ◽  
Peng Sun

A chrome-free chemical conversion coating was prepared using stannous sulfate as the main salt. The morphology of the chemical conversion surface layer was observed by scanning electron microscopy (SEM). Coating composition and the microcosmic phase structure were characterized using energy dispersive X-ray (EDX) analysis and X-ray diffraction (XRD) respectively. Electrochemical method and dropping test were used to study the coatings corrosion resistance. The results indicated that the tin salts conversion coating is a crystal structure material that composites with Sn-F-O-Al et al., the surface appears as a accumulation of spherical particles, the crystallinity of conversion coating is better than uncoated sample obviously, the corrosion resistance has improved too.


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