Synergistic effect of polyurethane‐coated carbon fiber and electron beam irradiation on the thermal/mechanical properties and long‐term durability of polyamide‐based thermoplastic composites

2022 ◽  
Author(s):  
Soo‐Yeon Kim ◽  
Ha‐Eun Gang ◽  
Gyu‐Tae Park ◽  
Ha‐Bin Jeon ◽  
Hyun Bin Kim ◽  
...  
Author(s):  
Claudia Giovedi ◽  
Luci Diva Brocardo Machado ◽  
Marcos Augusto ◽  
Eddy Segura Pino ◽  
Patrícia Radino

2016 ◽  
Vol 15 (01n02) ◽  
pp. 1650004 ◽  
Author(s):  
Muhammad A. Imam ◽  
Shaik Jeelani ◽  
Vijaya K. Rangari ◽  
Michelle G. Gome ◽  
Esperidiana. A. B. Moura

Nylon-6 is an engineering plastic with excellent properties and processability, which are essential in several industrial applications. The addition of filler such as diamond (DN) and diamond coated carbon nanotubes (CNTs) to form molded composites may increase the range of Nylon-6 applications due to the resulting increase in strength. The effects of electron-beam irradiation on these thermoplastic nanocomposites are either increase in the cross-linking or causes chain scission. In this study, DN-coated CNTs were synthesized using the sonochemical technique in the presence of cationic surfactant cetyltrimethyl ammonium bromide (CTAB). The DN-coated CNTs nanoparticles and diamond nanoparticles were then introduced into Nylon-6 polymer through a melt extrusion process to form nanocomposite fibers. They were further tested for their mechanical (Tensile) and thermal properties (thermogravimetric analysis (TGA), differential scanning calorimetry (DSC)). These composites were further exposed to the electron-beam (160[Formula: see text]kGy, 132[Formula: see text]kGy and 99[Formula: see text]kGy) irradiation using a 1.5[Formula: see text]MeV electron-beam accelerator, at room temperature, in the presence of air and tested for their thermal and mechanical properties. The best ultimate tensile strength was found to be 690[Formula: see text]MPa and 864[Formula: see text]MPa irradiated at 132 for DN/CNTs/Nylon-6 and Diamond/Nylon-6 nanocomposite fiber as compared to 346[Formula: see text]MPa and 321[Formula: see text]MPa for DN/CNTs/Nylon-6 and Diamond/Nylon-6 nanocomposite fiber without irradiation. The neat Nylon-6 tensile strength was 240[Formula: see text]MPa. These results are consistent with the activation energy calculated from TGA graphs. DSC analysis result shows that the slight increase in glass transition temperature ([Formula: see text]) and decrease in melting temperature ([Formula: see text]) which was expected from high electron-beam radiation dose.


2021 ◽  
Vol 294 ◽  
pp. 126300
Author(s):  
Imane Belyamani ◽  
Joachim Maris ◽  
Sylvie Bourdon ◽  
Jean-Michel Brossard ◽  
Laurent Cauret ◽  
...  

2021 ◽  
Vol 7 (8) ◽  
pp. 79528-79537
Author(s):  
Pedro Marcio Munhoz ◽  
Fernando Codelo Nascimento ◽  
Leonardo Gondim de Andrade e Silva ◽  
Julio Harada ◽  
Wilson Aparecido Parejo Calvo

The aim of this research was to evaluate the changes in the mechanical properties of poly(butylene adipate co-terephthalate)/poly(lactic acid) (PBAT/PLA) polymeric blend after the radiation process at different radiation doses. The irradiation was performed in an electron beam accelerator, with 1.5 MeV of energy and 25 mA electric current. The samples were irradiated with doses of 5, 10, 15, 25, 50, 65 and 80 kGy. Both irradiated and non-irradiated samples were characterized by Izod pendulum impact resistance and tensile strength at rupture. The results showed an increase of 44% in relation to Izod impact resistance at a dose of 65 kGy. However, the module of elasticity decreased 56% and tensile strength at rupture decreased 55% at the same radiation dose. In relation to elongation, significant alterations caused by electron beam irradiation was not observed. Therefore, it can be concluded that irradiated blends could be used to make environmentally friendly products, which could absorb impact energy. 


Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2431
Author(s):  
Elena Manaila ◽  
Anton Airinei ◽  
Maria Daniela Stelescu ◽  
Maria Sonmez ◽  
Laurentia Alexandrescu ◽  
...  

Composites based on ethylene–propylene–diene terpolymer (EPDM), butyl/halobutyl rubber and nanosilica were prepared by melt mixing and subjected to different doses of electron beam irradiation. The effect of irradiation dose on the mechanical properties, morphology, glass transition temperature, thermal stability and water uptake was investigated. The efficiency of the crosslinking by electron beam irradiation was analyzed by Charlesby–Pinner parameter evaluation and crosslink density measurements. The scanning electron microscopy data showed a good dispersion of nanosilica in the rubber matrix. An improvement in hardness and 100% modulus was revealed by increasing irradiation dose up to 150 kGy. The interaction between polymer matrix and nanosilica was analyzed using the Kraus equation. Additionally, these results indicated that the mechanical properties, surface characteristics, and water uptake were dependent on crosslink characteristics.


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