Dielectric properties of cured epoxy resins containing the perfluorobutenyloxy group

1986 ◽  
Vol 24 (6) ◽  
pp. 249-252 ◽  
Author(s):  
S. Sasaki
Author(s):  
Istebreq A. Saeedi ◽  
Sunny Chaudhary ◽  
Thomas Andritsch ◽  
Alun S. Vaughan

AbstractReactive molecular additives have often been employed to tailor the mechanical properties of epoxy resins. In addition, several studies have reported improved electrical properties in such systems, where the network architecture and included function groups have been modified through the use of so-called functional network modifier (FNM) molecules. The study reported here set out to investigate the effect of a glycidyl polyhedral oligomeric silsesquioxane (GPOSS) FNM on the cross-linking reactions, glass transition, breakdown strength and dielectric properties of an amine-cured epoxy resin system. Since many previous studies have considered POSS to act as an inorganic filler, a key aim was to consider the impact of GPOSS addition on the stoichiometry of curing. Fourier transform infrared spectroscopy revealed significant changes in the cross-linking reactions that occur if appropriate stoichiometric compensation is not made for the additional epoxide groups present on the GPOSS. These changes, in concert with the direct effect of the GPOSS itself, influence the glass transition temperature, dielectric breakdown behaviour and dielectric response of the system. Specifically, the work shows that the inclusion of GPOSS can result in beneficial changes in electrical properties, but that these gains are easily lost if consequential changes in the matrix polymer are not appropriately counteracted. Nevertheless, if the system is appropriately optimized, materials with pronounced improvements in technologically important characteristics can be designed.


1991 ◽  
Vol 27 (4-5) ◽  
pp. 371-376 ◽  
Author(s):  
Michel Delmotte ◽  
Henri Jullien ◽  
Michel Ollivon

2012 ◽  
Vol 476-478 ◽  
pp. 665-669 ◽  
Author(s):  
Li Yang ◽  
Miao Yin ◽  
Xiu Yun Li ◽  
Han Bing Ma

In this paper, a type of nanoporous polyhedral oligomeric silisesquioxanes (POSS) containing eight functional groups have been synthesized and mixed with diglycidyl ether of bisphenol A (DGEBA) to form epoxy resin networks with nanostructures. The cured octa(aminophenyl) silsesquioxane (1c-POSS) and DGEBA system inherently possesses higher thermal stability and higher char yield than the control epoxy resins. Furthermore, the dielectric constant of the 1c-POSS/DGEBA material (4.36) is substantially lower than that of the neat epoxy resins (4.64) as a consequence the presence of nanoporous POSS cubes in the epoxy matrix.


2021 ◽  
Vol 899 ◽  
pp. 688-693
Author(s):  
Viktor A. Lomovskoy ◽  
Anna S. Shorshina ◽  
Igor D. Simonov-Emelyanov ◽  
Anastasia A. Razzhivina

It is known that epoxy resins (ES) and materials based on them are widely used in various areas of natural economy due to their valuable properties: low shrinkage during curing, high adhesion to various materials, chemical resistance, good physical and mechanical properties, and excellent dielectric properties [1].


1989 ◽  
Vol 27 (4) ◽  
pp. 753-762 ◽  
Author(s):  
Norman F. Sheppard ◽  
Stephen D. Senturia

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