scholarly journals 17 O‐excess and d‐excess of atmospheric water vapor measured by cavity ring‐down spectrometry: Evidence of a matrix effect and implication for the calibration procedure

Author(s):  
Claudia Voigt ◽  
Christine Vallet‐Coulomb ◽  
Clément Piel ◽  
Anne Alexandre
2002 ◽  
Vol 40 (6) ◽  
pp. 1211-1219 ◽  
Author(s):  
J.R. Wang ◽  
P. Racette ◽  
M.E. Triesky ◽  
E.V. Browell ◽  
S. Ismail ◽  
...  

2021 ◽  
Vol 13 (12) ◽  
pp. 2402
Author(s):  
Weifu Sun ◽  
Jin Wang ◽  
Yuheng Li ◽  
Junmin Meng ◽  
Yujia Zhao ◽  
...  

Based on the optimal interpolation (OI) algorithm, a daily fusion product of high-resolution global ocean columnar atmospheric water vapor with a resolution of 0.25° was generated in this study from multisource remote sensing observations. The product covers the period from 2003 to 2018, and the data represent a fusion of microwave radiometer observations, including those from the Special Sensor Microwave Imager Sounder (SSMIS), WindSat, Advanced Microwave Scanning Radiometer for Earth Observing System sensor (AMSR-E), Advanced Microwave Scanning Radiometer 2 (AMSR2), and HY-2A microwave radiometer (MR). The accuracy of this water vapor fusion product was validated using radiosonde water vapor observations. The comparative results show that the overall mean deviation (Bias) is smaller than 0.6 mm; the root mean square error (RMSE) and standard deviation (SD) are better than 3 mm, and the mean absolute deviation (MAD) and correlation coefficient (R) are better than 2 mm and 0.98, respectively.


2011 ◽  
Vol 4 (9) ◽  
pp. 1979-1994 ◽  
Author(s):  
C. Straub ◽  
A. Murk ◽  
N. Kämpfer ◽  
S. H. W. Golchert ◽  
G. Hochschild ◽  
...  

Abstract. This paper presents the Alpine Radiometer Intercomparison at the Schneefernerhaus (ARIS), which took place in winter 2009 at the high altitude station at the Zugspitze, Germany (47.42° N, 10.98° E, 2650 m). This campaign was the first direct intercomparison between three new ground based 22 GHz water vapor radiometers for middle atmospheric profiling with the following instruments participating: MIRA 5 (Karlsruhe Institute of Technology), cWASPAM3 (Max Planck Institute for Solar System Research, Katlenburg-Lindau) and MIAWARA-C (Institute of Applied Physics, University of Bern). Even though the three radiometers all measure middle atmospheric water vapor using the same rotational transition line and similar fundamental set-ups, there are major differences between the front ends, the back ends, the calibration concepts and the profile retrieval. The spectrum comparison shows that all three radiometers measure spectra without severe baseline artifacts and that the measurements are in good general agreement. The measurement noise shows good agreement to the values theoretically expected from the radiometer noise formula. At the same time the comparison of the noise levels shows that there is room for instrumental and calibration improvement, emphasizing the importance of low elevation angles for the observation, a low receiver noise temperature and an efficient calibration scheme. The comparisons of the retrieved profiles show that the agreement between the profiles of MIAWARA-C and cWASPAM3 with the ones of MLS is better than 0.3 ppmv (6%) at all altitudes. MIRA 5 has a dry bias of approximately 0.5 ppm (8%) below 0.1 hPa with respect to all other instruments. The profiles of cWASPAM3 and MIAWARA-C could not be directly compared because the vertical region of overlap was too small. The comparison of the time series at different altitude levels show a similar evolution of the H2O volume mixing ratio (VMR) for the ground based instruments as well as the space borne sensor MLS.


2013 ◽  
Vol 13 (14) ◽  
pp. 6877-6886 ◽  
Author(s):  
D. Scheiben ◽  
A. Schanz ◽  
B. Tschanz ◽  
N. Kämpfer

Abstract. In this paper, we compare the diurnal variations in middle-atmospheric water vapor as measured by two ground-based microwave radiometers in the Alpine region near Bern, Switzerland. The observational data set is also compared to data from the chemistry–climate model WACCM. Due to the small diurnal variations of usually less than 1%, averages over extended time periods are required. Therefore, two time periods of five months each, December to April and June to October, were taken for the comparison. The diurnal variations from the observational data agree well with each other in amplitude and phase. The linear correlation coefficients range from 0.8 in the upper stratosphere to 0.5 in the upper mesosphere. The observed diurnal variability is significant at all pressure levels within the sensitivity of the instruments. Comparing our observations with WACCM, we find that the agreement of the phase of the diurnal cycle between observations and model is better from December to April than from June to October. The amplitudes of the diurnal variations for both time periods increase with altitude in WACCM, but remain approximately constant at 0.05 ppm in the observations. The WACCM data are used to separate the processes that lead to diurnal variations in middle-atmospheric water vapor above Bern. The dominating processes were found to be meridional advection below 0.1 hPa, vertical advection between 0.1 and 0.02 hPa and (photo-)chemistry above 0.02 hPa. The contribution of zonal advection is small. The highest diurnal variations in water vapor as seen in the WACCM data are found in the mesopause region during the time period from June to October with diurnal amplitudes of 0.2 ppm (approximately 5% in relative units).


2001 ◽  
Author(s):  
Dasheng Feng ◽  
Stig Syndergaard ◽  
Benjamin M. Herman ◽  
E. R. Kursinski ◽  
T. P. Yunck ◽  
...  

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