Synthesis of Complex Oxides From Metal Alkoxides

2006 ◽  
pp. 127-148
1994 ◽  
Vol 346 ◽  
Author(s):  
M.I. Yanovskaya ◽  
N.M. Kotova ◽  
I.E. Obvintseva ◽  
E.P. Turevskaya ◽  
N.Ya. Turova ◽  
...  

ABSTRACTPreparation of complex oxides in the form of powders and thin films from metal alkoxides is discussed. Most attention is paid to ferroelectric and related materials ‐ complex titanates and zirconates. Techniques for preparation of high‐purity morphologically homogeneous powders Ti2, ZrO2 barium titanate and BaTiO3‐based solid solutions, MgTiO3, Bi2WO6, Bi2MoO6 are proposed and discussed wilh respect to their application in ceramics technology. The solutions prepared electrochemically in methoxyethanol were widely used for formation of thin films, e.g. Y2O3‐stabilized ZrO2 and ρζγ solid solutions on Pt‐coated silicon substrates.


Metals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1148 ◽  
Author(s):  
Roman Husák ◽  
Hynek Hadraba ◽  
Zdeněk Chlup ◽  
Milan Heczko ◽  
Tomáš Kruml ◽  
...  

Oxide dispersion-strengthened (ODS) materials contain homogeneous dispersions of temperature-stable nano-oxides serving as obstacles for dislocations and further pinning of grain boundaries. The strategy for dispersion strengthening based on complex oxides (Y-Hf, -Zr, -Ce, -La) was developed in order to refine oxide dispersion to enhance the dispersion strengthening effect. In this work, the strengthening of EUROFER steel by complex oxides based on Y and elements of the IIIB group (lanthanum, scandium) and IVB group (cerium, hafnium, zirconium) was explored. Interparticle spacing as a dispersoid characteristic appeared to be an important factor in controlling the dispersion strengthening contribution to the yield strength of ODS EUROFER steels. The dispersoid size and average grain size of ODS EUROFER steel were altered in the ranges of 5–13 nm and 0.6–1.7 µm, respectively. Using this strategy, the yield strength of the prepared alloys varied between 550 MPa and 950 MPa depending on the doping element.


Author(s):  
Yalong Zou ◽  
Jiabo Le ◽  
Yufeng Cao ◽  
Na An ◽  
Yang Zhou ◽  
...  

The attractive photoelectrochemical (PEC) water splitting for hydrogen fuels always desires new semiconductors which provide stronger visible light absorption with suitable band positions. Sn(II) complex oxides are expected to offer...


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