Rare Earth Luminescent Centers in Organic and Biochemical Compounds

2005 ◽  
pp. 462-499 ◽  
Author(s):  
J.-C. G. Bünzli
Keyword(s):  
Rare Earth ◽  
Biochemical Compounds ◽  
Luminescent Centers

Rare Earth Ion Implantation for Silicon Based Light Emission

2005 ◽  
Vol 108-109 ◽  
pp. 755-760 ◽  
Author(s):  
Wolfgang Skorupa ◽  
J.M. Sun ◽  
S. Prucnal ◽  
L. Rebohle ◽  
T. Gebel ◽  
...  
Keyword(s):  
Rare Earth ◽  
Ion Implantation ◽  
Indium Tin Oxide ◽  
Light Emission ◽  
Charge Trapping ◽  
Electrical Performance ◽  
Rare Earth Ion ◽  
Light Emitting ◽  
Silicon Based ◽  
Luminescent Centers

Using ion implantation different rare earth luminescent centers (Gd3+, Tb3+, Eu3+, Ce3+, Tm3+, Er3+) were formed in the silicon dioxide layer of a purpose-designed Metal Oxide Silicon (MOS) capacitor with advanced electrical performance, further called a MOS-light emitting device (MOSLED). Efficient electroluminescence was obtained for the wavelength range from UV to infrared with a transparent top electrode made of indium-tin oxide. Top values of the efficiency of 0.3 % corresponding to external quantum efficiencies distinctly above the percent range were reached. The electrical properties of these devices such as current-voltage and charge trapping characteristics, were also evaluated. Finally, application aspects to the field of biosensing will be shown.

Investigation on the site occupation of rare-earth ions in CaIn2O4 with the fluorescence probe of Eu3+

2017 ◽  
Vol 19 (19) ◽  
pp. 12473-12479 ◽  
Author(s):  
Fengfeng Chi ◽  
Xiantao Wei ◽  
Yanguang Qin ◽  
Fei Li ◽  
Yonghu Chen ◽  
...  
Keyword(s):  
Rare Earth ◽  
Fluorescence Probe ◽  
Rare Earth Ions ◽  
Site Occupation ◽  
Luminescent Centers

Five different luminescent centers were disclosed in Eu3+ doped CaIn2O4 phosphors.

None‐rare‐earth activated Ca 14 Al 10 Zn 6 O 35 :Bi 3+ ,Mn 4+ phosphor involving dual luminescent centers for temperature sensing

2019 ◽  
Vol 102 (12) ◽  
pp. 7436-7447 ◽  
Author(s):  
Yu Ding ◽  
Ning Guo ◽  
Xiang Lü ◽  
Huitao Zhou ◽  
Lu Wang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Temperature Sensing ◽  
Luminescent Centers

Electrically Pumped Rare Earth Doped Semiconductor Lasers

1993 ◽  
Vol 301 ◽  
Author(s):  
Jacques I. Pankove ◽  
Robert J. Feuerstein
Keyword(s):  
Rare Earth ◽  
Semiconductor Lasers ◽  
Energy Exchange ◽  
Impact Excitation ◽  
Recombination Energy ◽  
Electrically Pumped ◽  
Luminescent Centers ◽  
Re Elements ◽  
Rare Earth Doped ◽  
Rare Earth Impurities

ABSTRACTThe interest in rare earth (RE) elements as luminescent centers is due to the narrowness and stability of the luminescent transitions. In this paper we review the mechanisms that can be used to electrically excite rare earth impurities in semiconductors: pair recombination energy exchange and impact excitation. The different means of providing energetic electrons for impact excitation are also discussed. We also propose a possible explanation for the temperature dependence of photoluminescence in silicon.

Characterization of Rare-Earth Fluoride Anti-Stokes Phosphors by Scanning arid Transmission Electron Microscopy

1971 ◽  
Vol 29 ◽  
pp. 142-143
Author(s):  
N. M. P. Low ◽  
L. E. Brosselard
Keyword(s):  
Electron Microscopy ◽  
Rare Earth ◽  
Elevated Temperatures ◽  
Stoichiometric Composition ◽  
Rare Earth Ions ◽  
Crystalline Solid ◽  
Precipitation Process ◽  
Rare Earth Fluoride ◽  
Earth Fluoride ◽  
Rare Earth Fluorides

There has been considerable interest over the past several years in materials capable of converting infrared radiation to visible light by means of sequential excitation in two or more steps. Several rare-earth trifluorides (LaF3, YF3, GdF3, and LuF3) containing a small amount of other trivalent rare-earth ions (Yb3+ and Er3+, or Ho3+, or Tm3+) have been found to exhibit such phenomenon. The methods of preparation of these rare-earth fluorides in the crystalline solid form generally involve a co-precipitation process and a subsequent solid state reaction at elevated temperatures. This investigation was undertaken to examine the morphological features of both the precipitated and the thermally treated fluoride powders by both transmission and scanning electron microscopy.Rare-earth oxides of stoichiometric composition were dissolved in nitric acid and the mixed rare-earth fluoride was then coprecipitated out as fine granules by the addition of excess hydrofluoric acid. The precipitated rare-earth fluorides were washed with water, separated from the aqueous solution, and oven-dried.

Study of segregation in La1.8Sr0.2CuO4 superconductor by STEM-EDS microanalysis

1987 ◽  
Vol 45 ◽  
pp. 54-55
Author(s):  
T. F. Kelly ◽  
P. J. Lee ◽  
E. E. Hellstrom ◽  
D. C. Larbalestier
Keyword(s):  
Rare Earth ◽  
High Field ◽  
Transport Current ◽  
Total Thickness ◽  
New Class ◽  
Ceramic Superconductors ◽  
Current Densities ◽  
Group Ii ◽  
Eds Microanalysis

Recently there has been much excitement over a new class of high Tc (>30 K) ceramic superconductors of the form A1-xBxCuO4-x, where A is a rare earth and B is from Group II. Unfortunately these materials have only been able to support small transport current densities 1-10 A/cm2. It is very desirable to increase these values by 2 to 3 orders of magnitude for useful high field applications. The reason for these small transport currents is as yet unknown. Evidence has, however, been presented for superconducting clusters on a 50-100 nm scale and on a 1-3 μm scale. We therefore planned a detailed TEM and STEM microanalysis study in order to see whether any evidence for the clusters could be seen.A La1.8Sr0.2Cu04 pellet was cut into 1 mm thick slices from which 3 mm discs were cut. The discs were subsequently mechanically ground to 100 μm total thickness and dimpled to 20 μm thickness at the center.

Microstructural characterization of a cast RENi5-based alloy

1993 ◽  
Vol 51 ◽  
pp. 1176-1177
Author(s):  
G. M. Micha ◽  
L. Zhang
Keyword(s):  
Electron Microscopy ◽  
Rare Earth ◽  
Microstructural Characterization ◽  
Binary Compound ◽  
Nickel Metal ◽  
Cast Material ◽  
Nickel Metal Hydride ◽  
Transmission Electron ◽  
Cast Condition

RENi5 (RE: rare earth) based alloys have been extensively evaluated for use as an electrode material for nickel-metal hydride batteries. A variety of alloys have been developed from the prototype intermetallic compound LaNi5. The use of mischmetal as a source of rare earth combined with transition metal and Al substitutions for Ni has caused the evolution of the alloy from a binary compound to one containing eight or more elements. This study evaluated the microstructural features of a complex commercial RENi5 based alloy using scanning and transmission electron microscopy.The alloy was evaluated in the as-cast condition. Its chemistry in at. pct. determined by bulk techniques was 12.1 La, 3.2 Ce, 1.5 Pr, 4.9 Nd, 50.2 Ni, 10.4 Co, 5.3 Mn and 2.0 Al. The as-cast material was of low strength, very brittle and contained a multitude of internal cracks. TEM foils could only be prepared by first embedding pieces of the alloy in epoxy.

Rare Earth Production

1952 ◽  
Vol 44 (3) ◽  
pp. 442-442
Author(s):  
Frank Spedding ◽  
Harley Wilhelm ◽  
Wayne Keller et al
Keyword(s):  
Rare Earth
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