Magnetization Reversal of Nano-particles

Author(s):  
Bernard Barbara
1998 ◽  
Vol 29 ◽  
pp. S123-S124
Author(s):  
B. Schleicher ◽  
U. Tapper ◽  
E.I. Kauppinen ◽  
M. Martin ◽  
L. Roschier ◽  
...  

Author(s):  
A. K. Datye ◽  
D. S. Kalakkad ◽  
L. F. Allard ◽  
E. Völkl

The active phase in heterogeneous catalysts consists of nanometer-sized metal or oxide particles dispersed within the tortuous pore structure of a high surface area matrix. Such catalysts are extensively used for controlling emissions from automobile exhausts or in industrial processes such as the refining of crude oil to produce gasoline. The morphology of these nano-particles is of great interest to catalytic chemists since it affects the activity and selectivity for a class of reactions known as structure-sensitive reactions. In this paper, we describe some of the challenges in the study of heterogeneous catalysts, and provide examples of how electron holography can help in extracting details of particle structure and morphology on an atomic scale.Conventional high-resolution TEM imaging methods permit the image intensity to be recorded, but the phase information in the complex image wave is lost. However, it is the phase information which is sensitive at the atomic scale to changes in specimen thickness and composition, and thus analysis of the phase image can yield important information on morphological details at the nanometer level.


Author(s):  
J. Liu ◽  
M. Pan ◽  
G. E. Spinnler

Small metal particles have peculiar chemical and physical properties as compared to bulk materials. They are especially important in catalysis since metal particles are common constituents of supported catalysts. The structural characterization of small particles is of primary importance for the understanding of structure-catalytic activity relationships. The shape and size of metal particles larger than approximately 5 nm in diameter can be determined by several imaging techniques. It is difficult, however, to deduce the shape of smaller metal particles. Coherent electron nanodiffraction (CEND) patterns from nano particles contain information about the particle size, shape, structure and defects etc. As part of an on-going program of STEM characterization of supported catalysts we report some preliminary results of CEND study of Ag nano particles, deposited in situ in a UHV STEM instrument, and compare the experimental results with full dynamical simulations in order to extract information about the shape of Ag nano particles.


2020 ◽  
pp. 54-58
Author(s):  
S. M. Plotnikov

The division of the total core losses in the electrical steel of the magnetic circuit into two components – losses dueto hysteresis and eddy currents – is a serious technical problem, the solution of which will effectively design and construct electrical machines with magnetic circuits having low magnetic losses. In this regard, an important parameter is the exponent α, with which the frequency of magnetization reversal is included in the total losses in steel. Theoretically, this indicator can take values from 1 to 2. Most authors take α equal to 1.3, which corresponds to the special case when the eddy current losses are three times higher than the hysteresis losses. In fact, for modern electrical steels, the opposite is true. To refine the index α, an attempt was made to separate the total core losses on the basis that the hysteresis component is proportional to the first degree of the magnetization reversal frequency, and the eddy current component is proportional to the second degree. In the article, the calculation formulas of these components are obtained, containing the values of the total losses measured in idling experiments at two different frequencies, and the ratio of these frequencies. It is shown that the rational frequency ratio is within 1.2. Presented the graphs and expressions to determine the exponent α depending on the measured no-load losses and the frequency of magnetization reversal.


1994 ◽  
Vol 18 (2) ◽  
pp. 193-196 ◽  
Author(s):  
H. Nishio ◽  
H. Taguchi ◽  
F. Hirata ◽  
T. Takeishi

1993 ◽  
Vol 17 (S_1_MORIS_92) ◽  
pp. S1_255-257 ◽  
Author(s):  
Roscoe C. Giles ◽  
Masud Mansuripur

MRS Advances ◽  
2020 ◽  
Vol 5 (61) ◽  
pp. 3153-3161
Author(s):  
Marco Antonio Juárez Sánchez ◽  
Miguel Ángel Meléndez Lira ◽  
Celestino Odín Rodríguez Nava

AbstractDrug contamination in water is one of the current fields of study. Since 1990, the presence of drugs in drinking water has been a concern to scientists and public. In Mexico, these organic compounds are not efficiently removed in wastewater treatment plants; therefore, alternative methodologies have been studied that allow these compounds to have a high percentage of degradation or be completely degraded. One example of these techniques is heterogeneous photocatalysis which has obtained positive results in the degradation of drugs using ZnO nanoparticles. These are commonly selected for their electrical characteristics, even though they disperse in water and an additional unit operation is required to separate them from the liquid medium. To eliminate drugs with nano particles in a single stage, polycaprolactone-based membranes with adhered ZnO nanoparticles, by means of electrospinning, were prepared to degrade drugs such as diclofenac. The technique used has shown to efficiently break down diclofenac in 4 hours according to the capillary electrophoresis readings.


2003 ◽  
Vol 777 ◽  
Author(s):  
T. Devolder ◽  
M. Belmeguenai ◽  
C. Chappert ◽  
H. Bernas ◽  
Y. Suzuki

AbstractGlobal Helium ion irradiation can tune the magnetic properties of thin films, notably their magneto-crystalline anisotropy. Helium ion irradiation through nanofabricated masks can been used to produce sub-micron planar magnetic nanostructures of various types. Among these, perpendicularly magnetized dots in a matrix of weaker magnetic anisotropy are of special interest because their quasi-static magnetization reversal is nucleation-free and proceeds by a very specific domain wall injection from the magnetically “soft” matrix, which acts as a domain wall reservoir for the “hard” dot. This guarantees a remarkably weak coercivity dispersion. This new type of irradiation-fabricated magnetic device can also be designed to achieve high magnetic switching speeds, typically below 100 ps at a moderate applied field cost. The speed is obtained through the use of a very high effective magnetic field, and high resulting precession frequencies. During magnetization reversal, the effective field incorporates a significant exchange field, storing energy in the form of a domain wall surrounding a high magnetic anisotropy nanostructure's region of interest. The exchange field accelerates the reversal and lowers the cost in reversal field. Promising applications to magnetic storage are anticipated.


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