Electrochemical Reduction and Dissolution of Aluminium in a Thin-Layer Refinery Process

The cyclic voltammograms of some binuclear copper(II) compounds with binucleating ligands where two molecules of tridentate ligand, N, N -bis(benzimidazol-2-ylmethyl)amine are linked by several alkyl chains, were measured under both argon and dioxygen. The results demonstrate that the binuclear copper(I) species produced by electrochemical reduction exhibit high reactivity towards dioxygen, while the reaction of the corresponding mononuclear species with oxygen is very slow. Thin-layer coulometry ([binuclear copper(I)]/[O2] = 0.47 - 10.6) and thin-layer cyclic voltammetry ([binuclear copper(I)]/[O2] = 4.3 - 10.6 ) revealed that two molecules of the binuclear copper(I) species react with one molecule of dioxygen.

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Thickness- and Particle-Size-Dependent Electrochemical Reduction of Carbon Dioxide on Thin-Layer Porous Silver Electrodes

ChemSusChem ◽

10.1002/cssc.201501637 ◽

2016 ◽

Vol 9 (5) ◽

pp. 428-432 ◽

Cited By ~ 28

Author(s):

Lin Zhang ◽

Zhiyong Wang ◽

Nada Mehio ◽

Xianbo Jin ◽

Sheng Dai

Keyword(s):

Carbon Dioxide ◽

Particle Size ◽

Thin Layer ◽

Electrochemical Reduction ◽

Size Dependent ◽

Silver Electrodes ◽

Porous Silver

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An integrated calcium fluoride crystal ir thin-layer cell and its application to identification of electrochemical reduction product of bilirubin

Electrochimica Acta ◽

10.1016/0013-4686(94)00369-c ◽

1995 ◽

Vol 40 (7) ◽

pp. 823-828 ◽

Cited By ~ 6

Author(s):

Jianjun Niu ◽

Shaojun Dong

Keyword(s):

Thin Layer ◽

Electrochemical Reduction ◽

Calcium Fluoride ◽

Reduction Product ◽

Fluoride Crystal ◽

Layer Cell ◽

Thin Layer Cell

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Syntheses and photochemical properties of octasubstituted phthalocyaninato zinc complexes

Journal of Porphyrins and Phthalocyanines ◽

10.1002/jpp.388 ◽

2001 ◽

Vol 05 (11) ◽

pp. 782-792 ◽

Cited By ~ 114

Author(s):

SUZANNE E. MAREE ◽

TEBELLO NYOKONG

Keyword(s):

Thin Layer ◽

Singlet Oxygen ◽

Electrochemical Reduction ◽

Zinc Complexes ◽

Quantum Yields ◽

Photochemical Properties ◽

High Concentrations ◽

Electron Donating Groups ◽

Selection Of

In this work a selection of octasubstituted phthalocyaninato zinc complexes were synthesized and their photochemistry studied. The substituents included cholesterol (3a), estrone (3b), naphthol (3c) and phenoxy groups substituted with CH3 (3d), C ( CH 3)3 (at two positions, 3e), C ( CH 3)3 (3f), NO2 (3g), NH 2 (3h), COH (3i), COOH (3j), and H (3k). In general, complexes containing electron-donating groups attached to the phenoxy ring (e.g. 3e and 3f) were found to be photochemically unstable with photobleaching quantum yields of the order of 10-3. In the presence of electron-withdrawing groups (3g, 3i, and 3j) the photobleaching quantum yields were of the order of 10-6 to 10-5. Singlet oxygen quantum yields (ΦΔ) ranged from 0.01 to 0.73. The lowest ΦΔ was observed for the highly aggregated complex 3c. All the complexes showed aggregation at high concentrations. Electrochemical reduction using a thin-layer spectroelectrochemistry cell showed that the complexes become more monomeric following reduction.

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Highly active and selective Au thin layer on Cu polycrystalline surface prepared by galvanic displacement for the electrochemical reduction of CO2 to CO

Applied Catalysis B Environmental ◽

10.1016/j.apcatb.2017.05.001 ◽

2017 ◽

Vol 213 ◽

pp. 211-215 ◽

Cited By ~ 29

Author(s):

Jun-Hyuk Kim ◽

Hyunje Woo ◽

Su-Won Yun ◽

Hyun-Woo Jung ◽

Seoin Back ◽

...

Keyword(s):

Thin Layer ◽

Electrochemical Reduction ◽

Galvanic Displacement ◽

Highly Active ◽

Reduction Of Co2

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Highly Active and Selective Au Thin Layer on Cu Polycrystalline Surface Prepared By Galvanic Displacement for the Electrochemical Reduction of CO2 to CO

ECS Meeting Abstracts ◽

10.1149/ma2017-02/45/1989 ◽

2017 ◽

Keyword(s):

Thin Layer ◽

Electrochemical Reduction ◽

Galvanic Displacement ◽

Highly Active ◽

Reduction Of Co2

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Applications of Photoelectron Microscopy

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100092499 ◽

1976 ◽

Vol 34 ◽

pp. 506-507

Author(s):

William J. Baxter

Keyword(s):

Electron Microscopy ◽

Thermal Decomposition ◽

Chemical Composition ◽

Ultraviolet Radiation ◽

Thin Layer ◽

Edge Effects ◽

Electron Optics ◽

Surface Layers ◽

Crystalline Orientation ◽

Fluorescent Screen

In this form of electron microscopy, photoelectrons emitted from a metal by ultraviolet radiation are accelerated and imaged onto a fluorescent screen by conventional electron optics. image contrast is determined by spatial variations in the intensity of the photoemission. The dominant source of contrast is due to changes in the photoelectric work function, between surfaces of different crystalline orientation, or different chemical composition. Topographical variations produce a relatively weak contrast due to shadowing and edge effects.Since the photoelectrons originate from the surface layers (e.g. ∼5-10 nm for metals), photoelectron microscopy is surface sensitive. Thus to see the microstructure of a metal the thin layer (∼3 nm) of surface oxide must be removed, either by ion bombardment or by thermal decomposition in the vacuum of the microscope.

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