Dynamics of a SIVD in Mixtures of Sulfur Hexafluoride with Hydrocarbons

Author(s):  
V. V. Apollonov
Keyword(s):  
Author(s):  
V.B. Moskalenko ◽  
◽  
I.G. Chizhov ◽  
O.V. Varakin ◽  
Y.A. Pavlenko ◽  
...  

Author(s):  
Afonso Ferreira Miguel Junior ◽  
Luiz Fernando Santos de Vasconcelos ◽  
Celina Kakitani ◽  
césar yutaka ofuchi ◽  
Moisés Marcelino Neto ◽  
...  

Plants ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1137
Author(s):  
Katja Bizaj ◽  
Mojca Škerget ◽  
Iztok Jože Košir ◽  
Željko Knez

This work investigates the efficiency of supercritical fluid extraction of hops with a variety of solvents including carbon dioxide (CO2), propane, sulfur hexafluoride (SF6), and dimethyl ether (DME) at various densities (low-density and high-density). Operating parameters were 50 bar, 100 bar and 150 bar and 20 °C, 40 °C, 60 °C and 80 °C for all solvents, respectively. The influence of process parameters on the total yield of extraction and content of bitter acids in the extracts has been investigated. The mathematical model based on Fick’s second law well described the experimental extraction results. Furthermore, HPLC analysis has been used to determine α- and β-acids in extracts. The yield of bitter compounds in hop extracts was largely influenced by the type of solvent, the temperature and pressure applied during extraction. The results show that CO2 and propane were roughly equivalent to DME in solvating power, while SF6 was a poor solvent at the same conditions. The highest yield as well as the highest concentration of bitter acids in extracts were obtained by using DME, where the optimal operating conditions were 40 °C and 100 bar for the extraction of α-acids (max. concentration 9.6%), 60 °C and 50 bar for the extraction of β-acids (4.5%) and 60 °C and 150 bar for the maximum extraction yield (25.6%).


2021 ◽  
Vol 11 (5) ◽  
pp. 2391
Author(s):  
Jose I. Huertas ◽  
Javier E. Aguirre ◽  
Omar D. Lopez Mejia ◽  
Cristian H. Lopez

The effects of using solid barriers on the dispersion of air pollutants emitted from the traffic of vehicles on roads located over flat areas were quantified, aiming to identify the geometry that maximizes the mitigation effect of air pollution near the road at the lowest barrier cost. Toward that end, a near road Computational Fluid Dynamics (NR-CFD) model that simulates the dispersion phenomena occurring in the near-surface atmosphere (<250 m high) in a small computational domain (<1 km long), via Computational Fluid Dynamics (CFD) was used. Results from the NR-CFD model were highly correlated (R2 > 0.96) with the sulfur hexafluoride (SF6) concentrations measured by the US-National Oceanic and Atmospheric Administration (US-NOAA) in 2008 downwind a line source emission, for the case of a 6m near road solid straight barrier and for the case without any barrier. Then, the effects of different geometries, sizes, and locations were considered. Results showed that, under all barrier configurations, the normalized pollutant concentrations downwind the barrier are highly correlated (R2 > 0.86) to the concentrations observed without barrier. The best cost-effective configuration was observed with a quarter-ellipse barrier geometry with a height equivalent to 15% of the road width and located at the road edge, where the pollutant concentrations were 76% lower than the ones observed without any barrier.


Thorax ◽  
2021 ◽  
pp. thoraxjnl-2020-214717
Author(s):  
Frederik Trinkmann ◽  
Máté Maros ◽  
Katharina Roth ◽  
Arne Hermanns ◽  
Julia Schäfer ◽  
...  

BackgroundMultiple breath washout (MBW) using sulfur hexafluoride (SF6) has the potential to reveal ventilation heterogeneity which is frequent in patients with obstructive lung disease and associated small airway dysfunction. However, reference data are scarce for this technique and mostly restricted to younger cohorts. We therefore set out to evaluate the influence of anthropometric parameters on SF6-MBW reference values in pulmonary healthy adults.MethodsWe evaluated cross-sectional data from 100 pulmonary healthy never-smokers and smokers (mean 51 (SD 20), range 20–88 years). Lung clearance index (LCI), acinar (Sacin) and conductive (Scond) ventilation heterogeneity were derived from triplicate SF6-MBW measurements. Global ventilation heterogeneity was calculated for the 2.5% (LCI2.5) and 5% (LCI5) stopping points. Upper limit of normal (ULN) was defined as the 95th percentile.ResultsAge was the only meaningful parameter influencing SF6-MBW parameters, explaining 47% (CI 33% to 59%) of the variance in LCI, 32% (CI 18% to 47%) in Sacin and 10% (CI 2% to 22%) in Scond. Mean LCI increases from 6.3 (ULN 7.4) to 8.8 (ULN 9.9) in subjects between 20 and 90 years. Smoking accounted for 2% (CI 0% to 8%) of the variability in LCI, 4% (CI 0% to 13%) in Sacin and 3% (CI 0% to 13%) in Scond.ConclusionSF6-MBW outcome parameters showed an age-dependent increase from early adulthood to old age. The effect was most pronounced for global and acinar ventilation heterogeneity and smaller for conductive ventilation heterogeneity. No influence of height, weight and sex was seen. Reference values can now be provided for all important SF6-MBW outcome parameters over the whole age range.Trial registration numberNCT04099225.


Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1708
Author(s):  
Ruochen Peng ◽  
Qu Zhou ◽  
Wen Zeng

As an insulating medium, sulfur hexafluoride (SF6) is extensively applied to electrical insulation equipment to ensure its normal operation. However, both partial discharge and overheating may cause SF6 to decompose, and then the insulation strength of electrical equipment will be reduced. The adsorption properties and sensing mechanisms of four SF6 decomposed components (HF, SO2, SOF2 and SO2F2) upon an Au-modified InN (Au-InN) monolayer were studied in this work based on first-principles theory. Meanwhile, the adsorption energy (Ead), charge transfer (QT), deformation charge density (DCD), density of states (DOS), frontier molecular orbital and recovery property were calculated. It can be observed that the structures of the SO2, SOF2 and SO2F2 molecules changed significantly after being adsorbed. Meanwhile, the Ead and QT of these three adsorption systems are relatively large, while that of the HF adsorption system is the opposite. These phenomena indicate that Au-InN monolayer has strong adsorption capacity for SO2, SOF2 and SO2F2, and the adsorption can be identified as chemisorption. In addition, through the analysis of frontier molecular orbital, it is found that the conductivity of Au-InN changed significantly after adsorbing SO2, SOF2 and SO2F2. Combined with the analysis of the recovery properties, since the recovery time of SO2 and SO2F2 removal from Au-InN monolayer is still very long at 418 K, Au-InN is more suitable as a scavenger for these two gases rather than as a gas sensor. Since the recovery time of the SOF2 adsorption system is short at 418 K, and the conductivity of the system before and after adsorption changes significantly, Au-InN is an ideal SOF2 gas-sensing material. These results show that Au-InN has broad application prospects as an SO2, SOF2 and SO2F2 scavenger and as a resistive SOF2 sensor, which is of extraordinary meaning to ensure the safe operation of power systems. Our calculations can offer a theoretical basis for further exploration of gas adsorbent and resistive sensors prepared by Au-InN.


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