Quantitative Analyses of Trace Elements in Environmental Samples: Options and (Im)possibilities

2009 ◽  
pp. 113-138 ◽  
Author(s):  
Katarina Vogel-Mikuš ◽  
Peter Kump ◽  
Marijan Nečemer ◽  
Primož Pelicon ◽  
Iztok Arčon ◽  
...  
2018 ◽  
Vol 12 (20) ◽  
pp. 289-295
Author(s):  
B. E. Orimadegun ◽  
E. B. Bolajoko ◽  
A. A. Onyeaghala ◽  
O. O. Ademola-Aremu

2019 ◽  
Vol 91 (6) ◽  
pp. 1029-1063 ◽  
Author(s):  
Roberto Terzano ◽  
Melissa A. Denecke ◽  
Gerald Falkenberg ◽  
Bradley Miller ◽  
David Paterson ◽  
...  

Abstract Trace elements analysis is a fundamental challenge in environmental sciences. Scientists measure trace elements in environmental media in order to assess the quality and safety of ecosystems and to quantify the burden of anthropogenic pollution. Among the available analytical techniques, X-ray based methods are particularly powerful, as they can quantify trace elements in situ. Chemical extraction is not required, as is the case for many other analytical techniques. In the last few years, the potential for X-ray techniques to be applied in the environmental sciences has dramatically increased due to developments in laboratory instruments and synchrotron radiation facilities with improved sensitivity and spatial resolution. In this report, we summarize the principles of the X-ray based analytical techniques most frequently employed to study trace elements in environmental samples. We report on the most recent developments in laboratory and synchrotron techniques, as well as advances in instrumentation, with a special attention on X-ray sources, detectors, and optics. Lastly, we inform readers on recent applications of X-ray based analysis to different environmental matrices, such as soil, sediments, waters, wastes, living organisms, geological samples, and atmospheric particulate, and we report examples of sample preparation.


2003 ◽  
Vol 56 (3) ◽  
pp. 103 ◽  
Author(s):  
William Maher ◽  
Frank Krikowa ◽  
Jason Kirby ◽  
Ashley T. Townsend ◽  
Peter Snitch

The strengths and weaknesses of using inductively coupled plasma mass spectrometer (ICPMS) measurements of samples in solution for marine environmental analyses using real world examples is discussed. ICPMS can detect nanogram per litre concentrations of trace elements but suffers from polyatomic interferences generated from the sample matrix. Most of the routine trace elements measured in marine biological tissue and sedimentdigests, with the notable exceptions of iron, chromium, vanadium, and selenium, are not subject to severe interferences. Low recoveries of trace elements from sediments are due to the inability of extraction acids to remove trace elements such as chromium and nickel from sediment matrices. The use of ICPMS offers the advantage that elements such as phosphorus, which previously required elaborate digestion procedures and a colorimetric determination, can be rapidly determined using nitric acid digestion alone. The use of flow injection coupled with ICPMS allows on-line preconcentration of trace metals and metalloids using chelation by ion-exchange resins or hydride generation and trapping as well as separation from matrix elements. Thus, the routine determination of trace elements and inorganic and methylated arsenic, antimony, mercury, and germanium species in open-ocean waters is possible. The coupling of HPLC and GC to ICPMS allows the measurement of metal and metalloid species in biological and sediment extracts. However, extraction of unaltered species from matrices presents a challenge. Many of the species found in the environmental samples are not known and analytical standards are not available. The concurrent use of HPLC-MS is needed to confirm these species.


2018 ◽  
Vol 1 (3) ◽  
pp. 31 ◽  
Author(s):  
Ahmed Elezz ◽  
Hassan Mustafa Hassan ◽  
Hamood Abdulla Alsaadi ◽  
Ahmed Easa ◽  
Saeed Al-Meer ◽  
...  

A method for the measurement of total mercury (T-Hg) in environmental samples using cold vapour atomic absorption spectrometry (CV AAS) has been validated yielding a dynamic range (0.04–10.00 μg/kg) and high certified reference material (CRM) recovery (>90%). The validation was carried out according to International Union of Pure and Applied Chemistry (IUPAC) validation and Eurachem Guides. A freeze-dried and homogenised sample was weighed and then digested using Suprapur acids (HNO3, H2SO4, and HF) with potassium dichromate solution in a hot block digestion system. A calibration curve was constructed (R2 > 0.999). Two CRMs (Marine Sediment Reference Material (PACS-3) and Trace Elements in Muscle Tissue (Trace Elements and Methylmercury in Mussel Tissue (NIST2976)) were utilised for quality assurance and control. The limit of quantification (LOQ) calculated as 0.04 µg/kg, and uncertainty (U) calculated as 2%. The obtained results showed the suitability of this method for direct mercury measurement in environmental samples. Additionally, the proficiency of this method was recognised by accreditation under the standard of International Organization for Standardization (ISO/IEC 17025:2017) for competence of testing and calibration laboratories.


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