scholarly journals Cluster Property and Pure Phases

2021 ◽  
pp. 105-109
Author(s):  
Franco Strocchi
Keyword(s):  
Cluster Property ◽  
Pure Phases

Synthesis and study the Structural and electrical and mechanical properties of High Temperature Superconductor Tl0.5Pb0.5Ba2Can-1Cun-xNixO2n+3-δ Substituted with nickel oxide for n=3

2018 ◽  
Vol 31 (3) ◽  
pp. 26 ◽  
Author(s):  
Laheeb. A. Mohammed ◽  
Kareem. A. Jasim
Keyword(s):  
Nickel Oxide ◽  
High Temperature Superconductor ◽  
Sintering Temperature ◽  
Concentration Effects ◽  
High Tc ◽  
Xrd Diffraction ◽  
Ni Content ◽  
High Tc Phase ◽  
Pure Phases ◽  
Critical Temperature Tc

   on this research is to study the effect of nickel oxide substitution on the pure phases superconductor Tl0.5Pb0.5Ba2Can-1Cun-xNixO2n+3-δ (n=3) where x=(0,0.2,0.4,0.6,0.8.and 1.0). The specimens in this work were prepared with used  procedure of solid state reaction with sintering temperature 8500C for 24 h .we used technical (4-prob)to calculated and the critical temperature Tc . The results of the XRD diffraction analysis showed that the structure for pure and doped phases was tetragonal with phases high-Tc phase (1223),(1212) and low-Tc phase (1202)  and add to the presence of some impure phase. It was noted the value a=b,c  the parameter of  the lattice increment  with the increment of Ni content. The increment of (NiO) concentration effects electrical resistivity, dielectric constant and the hardness.

scholarly journals Controlled Synthesis of CuS and Cu9S5 and Their Application in the Photocatalytic Mineralization of Tetracycline

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 899
Author(s):  
Murendeni P. Ravele ◽  
Opeyemi A. Oyewo ◽  
Damian C. Onwudiwe
Keyword(s):  
Electron Microscopy ◽  
Visible Light ◽  
Blue Shift ◽  
X Ray Diffraction ◽  
X Ray ◽  
Copper Sulfides ◽  
Transmission Electron ◽  
Single Source Precursor ◽  
Pure Phase ◽  
Pure Phases

Pure-phase Cu2−xS (x = 1, 0.2) nanoparticles have been synthesized by the thermal decomposition of copper(II) dithiocarbamate as a single-source precursor in oleylamine as a capping agent. The compositions of the Cu2−xS nanocrystals varied from CuS (covellite) through the mixture of phases (CuS and Cu7.2S4) to Cu9S5 (digenite) by simply varying the temperature of synthesis. The crystallinity and morphology of the copper sulfides were studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), which showed pure phases at low (120 °C) and high (220 °C) temperatures and a mixture of phases at intermediate temperatures (150 and 180 °C). Covellite was of a spherical morphology, while digenite was rod shaped. The optical properties of these nanocrystals were characterized by UV−vis–NIR and photoluminescence spectroscopies. Both samples had very similar absorption spectra but distinguishable fluorescence properties and exhibited a blue shift in their band gap energies compared to bulk Cu2−xS. The pure phases were used as catalysts for the photocatalytic degradation of tetracycline (TC) under visible-light irradiation. The results demonstrated that the photocatalytic activity of the digenite phase exhibited higher catalytic degradation of 98.5% compared to the covellite phase, which showed 88% degradation within the 120 min reaction time using 80 mg of the catalysts. The higher degradation efficiency achieved with the digenite phase was attributed to its higher absorption of the visible light compared to covellite.

A Method for Quantitative Phase Analysis of Silicon Nitride by X-Ray Diffraction

1990 ◽  
Vol 5 (3) ◽  
pp. 121-124 ◽  
Author(s):  
David J. Devlin ◽  
Kamal E. Amin
Keyword(s):  
Silicon Nitride ◽  
Iterative Method ◽  
Calibration Curve ◽  
Quantitative Measurement ◽  
Quantitative Phase Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Pure Phases ◽  
Yttrium Disilicate

AbstractThe relative intensities ratios for the determination of the relative amounts of alpha and beta phases in silicon nitride and the relative amounts of delta yttrium disilicate (Y2Si2O7) and nitrogen apatite [Y5(SiO4)3N] are reported. These constants were determined using an iterative method applicable when the pure phases are not easily prepared. In addition, a calibration curve was obtained for the quantitative measurement of free silicon in silicon nitride over the range 0 to 0.3% by weight of Si.

Effective rheology of a two-phase subduction shear zone: insights from numerical simple shear experiments and implications for subduction zone interfaces

2021 ◽  
Author(s):  
Paraskevi Io Ioannidi ◽  
Laetitia Le Pourhiet ◽  
Philippe Agard ◽  
Samuel Angiboust ◽  
Onno Oncken
Keyword(s):  
Simple Shear ◽  
Large Scale ◽  
Confining Pressure ◽  
Shear Zones ◽  
Dislocation Creep ◽  
Small Scale ◽  
Two Phase ◽  
Weak Phase ◽  
Pure Phases ◽  
Geodynamic Models

<p>Exhumed subduction shear zones often exhibit block-in-matrix structures comprising strong clasts within a weak matrix (mélanges). Inspired by such observations, we create synthetic models with different proportions of strong clasts and compare them to natural mélange outcrops. We use 2D Finite Element visco-plastic numerical simulations in simple shear kinematic conditions and we determine the effective rheology of a mélange with basaltic blocks embedded within a wet quartzitic matrix. Our models and their structures are scale-independent; this allows for upscaling published field geometries to km-scale models, compatible with large-scale far-field observations. By varying confining pressure, temperature and strain rate we evaluate effective rheological estimates for a natural subduction interface. Deformation and strain localization are affected by the block-in-matrix ratio. In models where both materials deform viscously, the effective dislocation creep parameters (A, n, and Q) vary between the values of the strong and the weak phase. Approaching the frictional-viscous transition, the mélange bulk rheology is effectively viscous creep but in the small scale parts of the blocks are frictional, leading to higher stresses. This results in an effective value of the stress exponent, n, greater than that of both pure phases, as well as an effective viscosity lower than the weak phase. Our effective rheology parameters may be used in large scale geodynamic models, as a proxy for a heterogeneous subduction interface, if an appropriate evolution law for the block concentration of a mélange is given.</p>

scholarly journals Bicritical Central Point of Ising Model Phase Diagram

2010 ◽  
Vol 2010 ◽  
pp. 1-5 ◽  
Author(s):  
Yahia Boughaleb ◽  
Mohammed Nouredine ◽  
Mohamed Snina ◽  
Rachid Nassif ◽  
Mohamed Bennai
Keyword(s):  
Phase Diagram ◽  
Order Parameter ◽  
Present Model ◽  
Central Point ◽  
Square Lattice ◽  
Ordered Structures ◽  
Ordered Phases ◽  
Algebraic Order ◽  
Pure Phases ◽  
Model Phase

We deal with a 2D half occupied square lattice with repulsive interactions between first and second neighboring particles. Despite the intensive studies of the present model the central point of the phase diagram for which the ratio of the two interaction strengths is still open. In the present paper we show, using standard Monte Carlo calculations, that the situation corresponds to a phase of mixed ordered structures quantified by an “algebraic” order parameter defined as the sum of densities of the existing ordered clusters. The introduced grandeur also characterizes the transitions towards the known pure ordered phases for the other values of as mentioned by the agreement of our results with those of the literature. The computation of the Cowley short range order parameter against suggests that the central point is bicritical and is a state to cross when passing between the two pure phases.

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