Structural relaxation characteristics of glass-forming polymeric liquids subject to transisent cross-links

2007 ◽  
pp. 46-50 ◽  
Author(s):  
L. M. Torell ◽  
P. Jacobsson ◽  
D. Sidebottom ◽  
L. Börjesson
Keyword(s):  
Structural Relaxation ◽  
Polymeric Liquids ◽  
Glass Forming ◽  
Cross Links ◽  
Relaxation Characteristics

Dynamics in a Nonfragile Glass-Forming Liquid

1996 ◽  
Vol 455 ◽  
Author(s):  
B. Rufflé ◽  
S. Beaufils ◽  
J. Etrillard ◽  
J. Gallier ◽  
B. Toudic ◽  
...  
Keyword(s):  
Structural Relaxation ◽  
Mode Coupling ◽  
Low Frequency ◽  
Large Temperature ◽  
Coupling Theory ◽  
Mode Coupling Theory ◽  
Glass Forming ◽  
Real Change ◽  
Wide Energy ◽  
Fragile Glass

ABSTRACTThe dynamics of Na0.5Li0.5PO3 (Tg = 515 K, Tm = 749 K) a non fragile glass forming liquid has been investigated over a large temperature range (300 − 1000 K.) and in a wide energy window using various experimental techniques. The susceptibility spectra obtained by coherent neutron scattering and depolarized light scattering between 1 and 104 GHz show mainly two contributions: a low frequency vibrational peak, the so-called Boson peak and a quasielastic component, referred to the βfast process in the mode coupling theory (MCT).The data are discussed in relation to the mode coupling theory for the liquid glass transition. In particular, the temperature evolution of the susceptibility height in the βfast region is compatible with a crossover temperature Tc ∼ 620 K which is also deduced from a power law temperature dependence of the structural relaxation timescale. As a secondary βslow process, observed by 31P NMR, decouples from the structural relaxation timescale also below 600 K, a real change in the dynamics seems to occur around Tc ∼ 620 K = 1.2 Tg in this non fragile glass Conning liquid.

scholarly journals Long-time structural relaxation of glass-forming liquids: Simple or stretched exponential?

2020 ◽  
Vol 152 (4) ◽  
pp. 041103
Author(s):  
Kristine Niss ◽  
Jeppe C. Dyre ◽  
Tina Hecksher
Keyword(s):  
Structural Relaxation ◽  
Stretched Exponential ◽  
Glass Forming ◽  
Long Time

Measurement and Calculation of Residual Stress in Axi-Symmetric Glass Sample Using Structural Relaxation Theory

2008 ◽  
Vol 39-40 ◽  
pp. 529-534
Author(s):  
Norbert Krečmer ◽  
Marek Liška ◽  
Josef Chocholoušek ◽  
Peter Vrábel
Keyword(s):  
Temperature Dependence ◽  
Structural Relaxation ◽  
Coefficient Of Thermal Expansion ◽  
High Stress ◽  
Polarized Light ◽  
Temperature History ◽  
Fictive Temperature ◽  
Stress Calculation ◽  
Applied Model ◽  
Glass Forming

Consistent model including structural relaxation is necessary for correct glass stress calculation in numerical computations of glass forming processes. Calculation of glass relaxation phenomena is often done by combining independent empirical formula on stress relaxation (for a simple temperature regime) and independent model of time-temperature dependence on Tool fictive temperature, Tf. Another approach was developed and verified here. Tool-Narayanaswamy and Moynihan/Mazurin relaxation model was adopted. Relaxation was obtained not from empirical model, but from calculated time-temperature dependence of Tool fictive temperature (Tf), dynamic viscosity, heat capacity and coefficient of thermal expansion. Heat conduction in a glass probe of known temperature history, structural relaxation and stress calculation were used in one computation scheme using Matlab. The stress of glass probe was measured using polarized light (Senarmont method). Rather high stress computation accuracy was obtained in comparison to stress experimental results. The applied model approach is being to be extended for application in commercial finite element codes for modeling of glass forming processes.

Static lengths in glass-forming monodisperse hard-sphere fluids from periodic array pinning

Soft Matter ◽  
2016 ◽  
Vol 12 (2) ◽  
pp. 402-407 ◽  
Author(s):  
Yuxing Zhou ◽  
Scott T. Milner
Keyword(s):  
Structural Relaxation ◽  
Hard Sphere ◽  
Volume Fraction ◽  
Particle Volume Fraction ◽  
Relaxation Times ◽  
Periodic Array ◽  
Length Scale ◽  
Master Curves ◽  
Particle Volume ◽  
Glass Forming

In glassy hard-sphere fluids, with varying particle volume fraction and distance between pinned particles, particle diffusivities and structural relaxation times both collapse to master curves, revealing a growing static length scale.

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