Mechanical and UV absorption behavior of zinc oxide nanoparticles: reinforced poly(vinyl alcohol-g-acrylonitrile) nanocomposite films

2017 ◽  
Vol 74 (10) ◽  
pp. 4119-4141 ◽  
Author(s):  
Shikha Chouhan ◽  
A. K. Bajpai ◽  
J. Bajpai ◽  
R. Katare ◽  
S. J. Dhoble
Materials ◽  
2019 ◽  
Vol 12 (8) ◽  
pp. 1195 ◽  
Author(s):  
Loan T. T. Nguyen ◽  
Lan T. H. Nguyen ◽  
Anh T. T. Duong ◽  
Bui Duc Nguyen ◽  
Nguyen Quang Hai ◽  
...  

Lanthanum (La)-doped zinc oxide nanoparticles were synthesized with different La concentrations by employing a gel combustion method using poly(vinyl alcohol) (PVA). The as-synthesized photocatalysts were characterized using various techniques, including X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDX), photoluminescence (PL) spectroscopy, and UV–visible absorption spectroscopy. The average size of ZnO nanoparticles decreased from 34.3 to 10.3 nm with increasing concentrations of La, and the band gap, as evaluated by linear fitting, decreased from 3.10 to 2.78 eV. Additionally, it was found that the photocatalytic activity of doped samples, as investigated by using methyl orange dye under visible lights, improved in response to the increase in La concentration. The decomposition of methyl orange reached 85.86% after 150 min in visible light using La0.1Zn0.9O as the photocatalyst.


Author(s):  
Jayashree Bagawade ◽  

A series of novel zinc oxide / Poly (methyl methacrylate) nanocomposite films with different ZnO contents were prepared through inclusion of pre-synthesized zinc oxide nanoparticles. The physical composition and morphology of the as-prepared nanocomposites were studied by XRD and TEM. The TEM analyses revealed that the zinc oxide nanoparticles have a particle size of ~3–5 nm. X-ray diffraction proved the presence of the amorphous PMMA in the nanocomposites. The intermolecular interactions within the polymer nanocomposites were explored by FTIR and XRD. FTIR spectra confirmed the dispersion of the zinc oxide nanoparticles in the Poly (methyl methacrylate) i.e. PMMA matrices. The UV-Vis absorption measurements of the ZnO/PMMA nanocomposites proved their potential optical properties.


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