Investigation of alumina nanoparticles role on the critical flux and performance of polyvinyl chloride membrane in a submerged membrane system for the removal of humic acid

Author(s):  
Habib Etemadi ◽  
Hamidreza Qazvini
2013 ◽  
Vol 96 (1) ◽  
pp. 204-211 ◽  
Author(s):  
Somayeh Tajik ◽  
Mohammad Ali Taher ◽  
Iran Sheikhshoaie

Abstract This paper describes the construction and performance characteristics of novel polyvinyl chloride membrane (PME) and coated platinum (CPtE) aluminium (Al) ion selective electrodes based on E-N′-(2-hydroxy-3-methoxybenzylidene) benzohydrazide. The electrodes exhibited linear responses with near Nernstian slopes of 19.9 ± 0.3 (PME) and 20.1 ± 0.4 (CPtE) mV/decade of activity within the Al3+ ion concentration range of 3.0 × 10–7 to 1.0 × 10–2 M for the PME and 1.0 × 10–7 –1.0 × 10–2 M for the CPtE. These sensors were applicable in a pH range of 3.0 to 7.0. The LODs of the PME and CPtE were 1.7 × 10–7 and 5.6 × 10–8 M, respectively. They had a response time of less than 10 s and could be used practically for a period of at least 2 months without measurable divergence in results. The isothermal temperature coefficient of the PME was 1.12 × 10–3 V/°C, and it can tolerate partially nonaqueous media up to 25%. The electrodes showed excellent selectivity towards Al3+ ions in the presence of a wide range of alkali, alkaline earth, and transition metals ions. They were successfully applied for the direct determination of Al3+ ions in tap water, aqueduct water, mineral water, and Al–Mg syrup and as indicator electrodes in potentiometric titration of Al ions with EDTA.


2021 ◽  
Vol 13 (2) ◽  
pp. 168781402098840
Author(s):  
Mohammed S Gad ◽  
Sayed M Abdel Razek ◽  
PV Manu ◽  
Simon Jayaraj

Experimental work was done to examine the impact of diesel fuel with alumina nanoparticles on combustion characteristics, emissions and performance of diesel engine. Alumina nanoparticles were mixed with crude diesel in various weight fractions of 20, 30, and 40 mg/L. The engine tests showed that nano alumina addition of 40 ppm to pure diesel led to thermal efficiency enhancement up to 5.5% related to the pure diesel fuel. The average specific fuel consumption decrease about neat diesel fuel was found to be 3.5%, 4.5%, and 5.5% at dosing levels of 20, 30, and 40 ppm, respectively at full load. Emissions of smoke, HC, CO, and NOX were found to get diminished by about 17%, 25%, 30%, and 33%, respectively with 40 ppm nano-additive about diesel operation. The smaller size of nanoparticles produce fuel stability enhancement and prevents the fuel atomization problems and the clogging in fuel injectors. The increase of alumina nanoparticle percentage in diesel fuel produced the increases in cylinder pressure, cylinder temperature, heat release rate but the decreases in ignition delay and combustion duration were shown. The concentration of 40 ppm alumina nanoparticle is recommended for achieving the optimum improvements in the engine’s combustion, performance and emission characteristics.


2000 ◽  
Vol 35 (13) ◽  
pp. 1979-1990 ◽  
Author(s):  
YUKIO SAKAI ◽  
ROBERT W. CATTRALL ◽  
IAN D. POTTER ◽  
SPAS D. KOLEV ◽  
ROHANI PAIMIN

2020 ◽  
Vol 119 ◽  
pp. 108100
Author(s):  
Marco Consumi ◽  
Gemma Leone ◽  
Claudia Bonechi ◽  
Gabriella Tamasi ◽  
Stefania Lamponi ◽  
...  

1991 ◽  
Vol 40 (1) ◽  
pp. 1-6 ◽  
Author(s):  
Takashi MASADOME ◽  
Toshihiko IMATO ◽  
Nobuhiko ISHIBASHI

2006 ◽  
Vol 326-328 ◽  
pp. 1317-1320 ◽  
Author(s):  
Jong Oh Kim ◽  
Jong Tae Jung ◽  
Won Youl Choi

This study was conducted to evaluate the applicability of photocatalytic metal membrane system for the treatment of humic acid and heavy metals in aqueous solution. The catalysts, TiO2 powder P25 Degussa and metal membrane with 0.5 μm nominal pore size were used for experiments. Removal efficiency of humic acid and heavy metals increased with the increase of TiO2 dosage, however decreased over 0.3 g/L of TiO2 dosage. The addition of H2O2 as an oxidation reagent had a positive effect for the removal rate of humic acid and heavy metals. Metal membrane with stainless steel seemed to be quite stable to UV light with oxidation reagent in long-term operational periods over 6 months. Moreover, TiO2 particles can be effectively separated from the treated water by membrane rejection and the permeation flux was also enhanced by the combination of photocatalytic reaction.


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