scholarly journals Insights into shallow magmatic processes in large silicic magma bodies: the trace element record in the Fish Canyon magma body, Colorado

2005 ◽  
Vol 149 (3) ◽  
pp. 338-349 ◽  
Author(s):  
O. Bachmann ◽  
M. A. Dungan ◽  
F. Bussy
2021 ◽  
Author(s):  
◽  
Simon James Barker

<p>This thesis research presents geochemical perspectives on the magmatic recovery of Taupo volcano (New Zealand) in the aftermath of the 25.4 ka Oruanui supereruption. Following the Oruanui, and after only ~5 kyr of quiescence, Taupo erupted three small volume (~0.1 km3) dacitic units, followed by another ~5 kyr break, and then the modern sequence from ~12 ka onwards of 25 rhyolitic units organised into 3 geochemically distinct subgroups (SG1-SG3). The eruptive units are stratigraphically constrained over exceptionally short time intervals, providing fine-scale temporal snapshots of the magma system. In this thesis I compare and contrast whole-rock, mineral and glass compositions of Oruanui and post-Oruanui magmas through time to investigate the post-supereruption reconstruction and evolution of Taupo through to the latest eruption.  Despite overlapping vent sites and crustal source domains between the Oruanui and post-Oruanui eruptions, U/Th disequilibrium model-ages in zircons from Taupo SG1 rhyolites (erupted 12 ka-10 ka) and SG2 rhyolites (erupted 7 ka-2.6 ka) imply the presence of only minor inheritance of crystals from the Oruanui magma source. Post-Oruanui model-age spectra are instead typically centred close to eruption ages with subordinate older pre-300 ka equiline grains. U-Pb dating of these equiline grains shows that both 300-450 ka plutonic-derived and pre-100 Ma greywacke basement-derived zircons are present. The former largely coincide in age with zircons from the 350 ka Whakamaru eruption products, and are dominant over greywacke in young units which were vented within the published Whakamaru caldera outline. Despite multiple ages and vent sites, trace element compositions are broadly similar in zircons, regardless of their ages. However, a small subset of zircons analysed from SG1 rhyolites have notably high concentrations of U, Th, P, Y+ (REE)3+ and Nb but with only minor changes in Hf and Ti. SG2 zircons typically have higher Sc, reflecting large-scale changes in melt chemistry and crystallising mineral phases with time. The age spectra indicate that most Oruanui zircons were removed by thermally induced dissolution immediately following the supereruption. U-Th ages from individual post-Oruanui eruptions show consistent inheritance of post-Oruanui grains with model ages that centre between the temporally separated but geographically overlapping eruption groups, generating model-age modes. Within the statistical limitations of the isotopic measurements, we interpret these repeated modes to be significant, resulting from incorporation of crystal populations from cyclic post-Oruanui periods of magmatic cooling and crystallisation, acting within a crustal protolith chemically independent of that which built the Oruanui. Cooling periods alternate with times of rejuvenation and eruption, in some cases demonstrably accompanying syn-eruptive regional rifting and mafic injection. Not only were the processes that developed the supersized Oruanui magma body unusually rapid, but this huge magma system was effectively reset and rebuilt on a comparably short timescale.  Major and trace element whole rock, glass and mineral chemistry of post-Oruanui eruptive products indicate how the host magma system re-established and evolved. The dacite units show wide variations in melt inclusion compositions and strongly zoned minerals consistent with interaction of less-evolved mafic magmas at a depths of >8 km, overlapping with the inferred base of the old Oruanui mush system. The dacites reflect the first products of the rebuilding silicic magma system, as most of the Oruanui mush was reconfigured or significantly modified in composition following thermal fluxing accompanying post-caldera collapse readjustment. The first (SG1) rhyolites erupted from 12 ka formed through shallow fractionation (4-5 km depth) and cooling of a parental melt similar in composition to the earlier dacite melts, with overlapping melt inclusion and crystal core compositions between the two magma types. For the younger rhyolite units, fine-scale temporal changes in melt chemistry and mineral phase stability occur over time, which are closely linked to the development, stabilisation and maturation of a new and likely unitary rhyolite mush system at Taupo. The new mush system is closely linked to and sometimes physically interacts with the underlying mafic melts, which are similar in composition to those involved in the Oruanui eruption and provide the long-term thermal and chemical driving force for magmatism. We consider that the new mush body has expanded to >250 km3 (and possibly up to 1000 km3) but has not yet been located by geophysical investigations.  For the most recent SG3 eruptions, the system once again underwent widespread destabilisation, resulting in increased levels of melt extraction from the silicic mush. Trends in whole-rock chemistry and close links between melt inclusions and mineral zoning with earlier units indicates that the 35 km3 Unit Y (Taupo eruption) melt dominant body formed in response to mafic disruption of the silicic mush pile. Associated Fe-Mg diffusion timescales in orthopyroxene suggest that Taupo is capable of changing behaviour and generating large eruptible melt bodies on timescales as short as decades to centuries. The 232 AD Unit Y eruption culminated from a critical combination of high differential tectonic stress build up, and increased potency in the silicic magma system resulting from elevated levels of mafic magma input, resulting in one of the largest and most violent worldwide Holocene eruptions. The post-Y magma system then responded to further disruption with the eruption of sub-lacustrine dome(s). Taupo is considered to be capable of rapidly recovering in its modern form to continue its hyperactive eruptive behaviour on timescales that are of human interest and concern.</p>


2021 ◽  
Author(s):  
◽  
Simon James Barker

<p>This thesis research presents geochemical perspectives on the magmatic recovery of Taupo volcano (New Zealand) in the aftermath of the 25.4 ka Oruanui supereruption. Following the Oruanui, and after only ~5 kyr of quiescence, Taupo erupted three small volume (~0.1 km3) dacitic units, followed by another ~5 kyr break, and then the modern sequence from ~12 ka onwards of 25 rhyolitic units organised into 3 geochemically distinct subgroups (SG1-SG3). The eruptive units are stratigraphically constrained over exceptionally short time intervals, providing fine-scale temporal snapshots of the magma system. In this thesis I compare and contrast whole-rock, mineral and glass compositions of Oruanui and post-Oruanui magmas through time to investigate the post-supereruption reconstruction and evolution of Taupo through to the latest eruption.  Despite overlapping vent sites and crustal source domains between the Oruanui and post-Oruanui eruptions, U/Th disequilibrium model-ages in zircons from Taupo SG1 rhyolites (erupted 12 ka-10 ka) and SG2 rhyolites (erupted 7 ka-2.6 ka) imply the presence of only minor inheritance of crystals from the Oruanui magma source. Post-Oruanui model-age spectra are instead typically centred close to eruption ages with subordinate older pre-300 ka equiline grains. U-Pb dating of these equiline grains shows that both 300-450 ka plutonic-derived and pre-100 Ma greywacke basement-derived zircons are present. The former largely coincide in age with zircons from the 350 ka Whakamaru eruption products, and are dominant over greywacke in young units which were vented within the published Whakamaru caldera outline. Despite multiple ages and vent sites, trace element compositions are broadly similar in zircons, regardless of their ages. However, a small subset of zircons analysed from SG1 rhyolites have notably high concentrations of U, Th, P, Y+ (REE)3+ and Nb but with only minor changes in Hf and Ti. SG2 zircons typically have higher Sc, reflecting large-scale changes in melt chemistry and crystallising mineral phases with time. The age spectra indicate that most Oruanui zircons were removed by thermally induced dissolution immediately following the supereruption. U-Th ages from individual post-Oruanui eruptions show consistent inheritance of post-Oruanui grains with model ages that centre between the temporally separated but geographically overlapping eruption groups, generating model-age modes. Within the statistical limitations of the isotopic measurements, we interpret these repeated modes to be significant, resulting from incorporation of crystal populations from cyclic post-Oruanui periods of magmatic cooling and crystallisation, acting within a crustal protolith chemically independent of that which built the Oruanui. Cooling periods alternate with times of rejuvenation and eruption, in some cases demonstrably accompanying syn-eruptive regional rifting and mafic injection. Not only were the processes that developed the supersized Oruanui magma body unusually rapid, but this huge magma system was effectively reset and rebuilt on a comparably short timescale.  Major and trace element whole rock, glass and mineral chemistry of post-Oruanui eruptive products indicate how the host magma system re-established and evolved. The dacite units show wide variations in melt inclusion compositions and strongly zoned minerals consistent with interaction of less-evolved mafic magmas at a depths of >8 km, overlapping with the inferred base of the old Oruanui mush system. The dacites reflect the first products of the rebuilding silicic magma system, as most of the Oruanui mush was reconfigured or significantly modified in composition following thermal fluxing accompanying post-caldera collapse readjustment. The first (SG1) rhyolites erupted from 12 ka formed through shallow fractionation (4-5 km depth) and cooling of a parental melt similar in composition to the earlier dacite melts, with overlapping melt inclusion and crystal core compositions between the two magma types. For the younger rhyolite units, fine-scale temporal changes in melt chemistry and mineral phase stability occur over time, which are closely linked to the development, stabilisation and maturation of a new and likely unitary rhyolite mush system at Taupo. The new mush system is closely linked to and sometimes physically interacts with the underlying mafic melts, which are similar in composition to those involved in the Oruanui eruption and provide the long-term thermal and chemical driving force for magmatism. We consider that the new mush body has expanded to >250 km3 (and possibly up to 1000 km3) but has not yet been located by geophysical investigations.  For the most recent SG3 eruptions, the system once again underwent widespread destabilisation, resulting in increased levels of melt extraction from the silicic mush. Trends in whole-rock chemistry and close links between melt inclusions and mineral zoning with earlier units indicates that the 35 km3 Unit Y (Taupo eruption) melt dominant body formed in response to mafic disruption of the silicic mush pile. Associated Fe-Mg diffusion timescales in orthopyroxene suggest that Taupo is capable of changing behaviour and generating large eruptible melt bodies on timescales as short as decades to centuries. The 232 AD Unit Y eruption culminated from a critical combination of high differential tectonic stress build up, and increased potency in the silicic magma system resulting from elevated levels of mafic magma input, resulting in one of the largest and most violent worldwide Holocene eruptions. The post-Y magma system then responded to further disruption with the eruption of sub-lacustrine dome(s). Taupo is considered to be capable of rapidly recovering in its modern form to continue its hyperactive eruptive behaviour on timescales that are of human interest and concern.</p>


2019 ◽  
Vol 114 (7) ◽  
pp. 1365-1388 ◽  
Author(s):  
Hervé Rezeau ◽  
Robert Moritz ◽  
Jörn-Frederik Wotzlaw ◽  
Samvel Hovakimyan ◽  
Rodrik Tayan

Abstract The trace element composition of zircon, especially in tandem with U-Pb geochronology, has become a powerful tool for tracing magmatic processes associated with the formation of porphyry copper deposits. However, the use of the redox-sensitive Eu and Ce anomalies as a potential mineral exploration proxy is controversial. This study presents a comprehensive, temporally constrained data set of zircon trace element compositions (n = 645) for three compositionally distinct magmatic series identified in the Meghri-Ordubad pluton, southernmost Lesser Caucasus. The 30 million years of Cenozoic magmatism in the Meghri-Ordubad pluton are associated with several ore-forming pulses leading to the formation of porphyry copper deposits and epithermal-style mineralization. Our zircon geochemical data constrain the thermal and chemical evolution of this complex intrusive suite and allow an evaluation of the usefulness of zircon as a mineral exploration proxy for porphyry copper deposits. Our results combined with Rayleigh fractionation modeling indicate that the trace element composition of zircon (Th/U, Hf, Ti, YbN/DyN, Eu anomalies) is influenced by the composition and the water concentration of the parental magma, as well as by co-crystallizing titanite and apatite. In contrast, the variations of Ce anomalies remain difficult to explain by magmatic processes and could rather be ascribed to relative fluctuations of the redox conditions. In the Meghri-Ordubad pluton, we do not observe any systematic patterns between the trace element composition in zircons and the different ore-forming pulses. This questions the reliability of using the trace element composition in zircon as an exploration mineral proxy, and it rather emphasizes that a good knowledge of the entire magmatic evolution of a metallogenic province is required.


Elements ◽  
2019 ◽  
Vol 15 (3) ◽  
pp. 191-196 ◽  
Author(s):  
Olivier Bachmann ◽  
Sharon R. Allen ◽  
Caroline Bouvet de Maisonneuve

The Kos–Nisyros–Yali volcanic field has produced a range of volcanic products over the last 3 million years. Volumetrically, silicic magma dominates, and activity includes one of the largest known explosive eruptions of the Aegean arc, the >60 km3 (dense-rock equivalent), 161 ka rhyolitic Kos Plateau Tuff. The Kos–Nisyros–Yali volcanic field is situated within an area of active crustal extension, which has greatly influenced magmatic processes and landscape development in the region. Recent seismic unrest, surface deformation and intense geothermal activity indicate that the system remains active, particularly around the Nisyros and Yali edifices. These signs of magmatic activity, together with the fact that the most recent eruptions have become increasingly silicic, would justify detailed monitoring of the area.


2016 ◽  
Vol 101 (2) ◽  
pp. 328-342 ◽  
Author(s):  
Calvin G. Barnes ◽  
Valbone Memeti ◽  
Nolwenn Coint

2021 ◽  
Author(s):  
◽  
Jessica Anne Dallas

<p>Meteorites provide the only direct record of the chronology and nature of the processes that occurred in the early solar system. In this study, meteorites were examined in order to gain insight into the timing and nature of magmatism and silicate differentiation on asteroidal bodies in the first few million years of the solar system. These bodies are considered the precursors to terrestrial planets, and as such they provide information about conditions in the solar system at the time of planet formation. This study focuses on eucrites, which are basaltic meteorites that are believed to represent the crust of the Howardite-Eucrite-Diogenite (HED) parent body. The processes of silicate differentiation and the relationship between eucrites and the diogenitic mafic cumulate of the HED parent body are poorly understood. The major and trace element chemistry of the minerals in the eucrite suite was measured. There is little variability in mineral major element concentrations in eucrites, however considerable variability was observed in mineral trace element concentrations, particularly with respect to incompatible elements in the mineral phases. Magnesium was separated from digested eucrite samples, and the Mg isotope composition of the eucrites was measured to high precision in order to date the samples using the short-lived ²⁶Al–²⁶Mg chronometer and examine magmatic evolution on the HED parent body. Correlations between incompatible elements in pyroxene and ²⁶Mg anomalies, produced by the decay of ²⁶Al, indicate that the eucrite suite was formed from a single, evolving magma body. Large trace element and Mg isotopic differences between eucrites and diogenites indicate that the two meteorite groups did not, as previously suggested, originate from the same magma body. Instead they may have formed from two large magma bodies, which were spatially or temporally separated on the HED parent body. The application of the short-lived ²⁶Al–²⁶Mg chronometer to this suite of eucrites constrains the onset of eucrite formation to ~3 Myr after the formation of the solar system’s first solids, as a result of rapid accretion and melting of planetesimals due to heating from the decay of ²⁶Al.</p>


2022 ◽  
Vol 9 ◽  
Author(s):  
G. F. Cooper ◽  
E. C. Inglis

Lavas produced at subduction zones represent the integration of both source heterogeneity and an array of crustal processes, such as: differentiation; mixing; homogenisation; assimilation. Therefore, unravelling the relative contribution of the sub-arc mantle source versus these crustal processes is difficult when using the amalgamated end products in isolation. In contrast, plutonic xenoliths provide a complementary record of the deeper roots of the magmatic plumbing system and provide a unique record of the true chemical diversity of arc crust. Here, we present the δ56Fe record from well characterised plutonic xenoliths from two distinct volcanic centres in the Lesser Antilles volcanic arc–the islands of Martinique and Statia. The primary objective of this study is to test if the Fe isotope systematics of arc lavas are controlled by sub-arc mantle inputs or during subsequent differentiation processes during a magma’s journey through volcanic arc crust. The Fe isotopic record, coupled to petrology, trace element chemistry and radiogenic isotopes of plutonic xenoliths from the two islands reveal a hidden crustal reservoir of heavy Fe that previously hasn’t been considered. Iron isotopes are decoupled from radiogenic isotopes, suggesting that crustal and/or sediment assimilation does not control the Fe systematics of arc magmas. In contrast to arc lavas, the cumulates from both islands record MORB-like δ56Fe values. In Statia, δ56Fe decreases with major and trace element indicators of differentiation (SiO2, Na2O + K2O, Eu/Eu*, Dy/Yb), consistent with fractionating mineral assemblages along a line of liquid descent. In Martinique, δ56Fe shows no clear relationship with most indicators of differentiation (apart from Dy/Yb), suggesting that the δ56Fe signature of the plutonic xenoliths has been overprinted by later stage processes, such as percolating reactive melts. Together, these data suggest that magmatic processes within the sub-arc crust overprint any source variation of the sub-arc mantle and that a light Fe source is not a requirement to produce the light Fe isotopic compositions recorded in volcanic arc lavas. Therefore, whenever possible, the complimentary plutonic record should be considered in isotopic studies to understand the relative control of the mantle source versus magmatic processes in the crust.


2016 ◽  
Vol 437 ◽  
pp. 138-149 ◽  
Author(s):  
Marie Nicolle ◽  
David Jousselin ◽  
Laurie Reisberg ◽  
Delphine Bosch ◽  
Aurore Stephant

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