scholarly journals The basal dunite of the Precambrian mafic-ultramafic Näränkävaara intrusion: Petrogenetic considerations and implications to exploration

Author(s):  
Ville Järvinen ◽  
Tapio Halkoaho ◽  
Jukka Konnunaho ◽  
Jussi S. Heinonen ◽  
O. Tapani Rämö

Abstract Several mafic-ultramafic layered intrusions were emplaced in the Fennoscandian Shield during wide-spread mantle-sourced magmatism at 2.5–2.4 Ga. The Näränkävaara intrusion (surface area 5 × 30 km2), northeastern Finland, contains a 1.5–2 km thick basal dunite (not dated), and a 1.5 km thick layered series (2436 ± 5 Ma). A newly discovered marginal series between the basal dunite and the layered series indicates that the basal dunite is older, and highlights the need for further study on their relationship. Along its southern basement contact, the basal dunite contains a 200–300 m thick zone of olivine ortho- and mesocumulates, but the bulk of it is composed of olivine adcumulates and lesser olivine-orthopyroxene heteradcumulates. Based on whole-rock geochemistry, the basal dunite is divided into a low-Fe zone (average FeOt 10.2 wt% and Ni 2250 ppm) and a high-Fe zone (average FeOt 12.5 wt% and Ni 1700 ppm). Both zones have high MgO (32–47 wt%) and varying Cr (830–5160 ppm) and Al2O3/TiO2 (16–26). Textural and geochemical layering is similar along the 30 km strike of the basal dunite. A LREE-enriched high-MgO basaltic parental magma composition (13–18 wt% MgO) is inferred for the basal dunite from olivine–melt mixing trends in orthocumulates. The dunite exhibits at least two geochemical reversals as well as abundant low-porosity adcumulates, poikilitic chromite, and bimodal olivine, suggesting formation in a high-volume open magmatic system. Significant similarity in major and trace element compositions with the Näränkävaara layered series and the Burakovsky intrusion and Vetreny belt extrusives in Russian Karelia suggests that the basal dunite belongs to the Fennoscandian 2.5–2.4 Ga mafic layered intrusions. An Archean komatiitic origin for the dunite body cannot be completely ruled out, however. Distinct Ni-depletion in olivine is found in the basal dunite from the low-Fe zone to the high-Fe zone (3200 versus 2200 ppm). This depletion does not correlate with Fo contents, which suggests that it is not related to olivine fractionation. The basal dunite may thus have potential for Ni-(Cu-Co-PGE) sulfide mineralization.

2019 ◽  
Vol 55 (8) ◽  
pp. 1535-1560 ◽  
Author(s):  
Ville Järvinen ◽  
Tapio Halkoaho ◽  
Jukka Konnunaho ◽  
Jussi S. Heinonen ◽  
O. Tapani Rämö

AbstractAbout 20 mafic-ultramafic layered intrusions in the northern Fennoscandian shield were emplaced during a widespread magmatic event at 2.5–2.4 Ga. The intrusions host orthomagmatic Ni-Cu-PGE and Cr-V-Ti-Fe deposits. We update the magmatic stratigraphy of the 2.44-Ga Näränkävaara mafic-ultramafic body, northeastern Finland, on the basis of new drill core and outcrop observations. The Näränkävaara body consists of an extensive basal dunite (1700 m thick), and a layered series comprising a peridotitic–pyroxenitic ultramafic zone (600 m thick) and a gabbronoritic–dioritic mafic zone (700 m thick). Two reversals are found in the layered series. The composition of the layered series parental magma was approximated using a previously unidentified marginal series gabbronorite. The parental magma was siliceous high-Mg basalt with high MgO, Ni, and Cr, but also high SiO2 and Zr, which suggests primary magma contamination by felsic crust. Cu/Pd ratio below that of primitive mantle implies PGE-fertility. The structural position of the marginal series indicates that the thick basal dunite represents an older wallrock for the layered intrusion. A subeconomic reef-type PGE-enriched zone is found in the border zone between the ultramafic and mafic zones and has an average thickness of 25 m with 150–250 ppb of Pt + Pd + Au. Offset-type metal distribution and high sulfide tenor (50–300 ppm Pd) and R-factor (105) suggest reef formation by sulfide saturation induced by fractional crystallization. The reef-forming process was probably interrupted by influx of magma related to the first reversal. Metal ratios suggest that this replenishing magma was PGE-depleted before emplacement.


1998 ◽  
Vol 35 (7) ◽  
pp. 854-870 ◽  
Author(s):  
D C Vogel ◽  
R S James ◽  
R R Keays

The Palaeoproterozoic Southern Province comprises a thick, continental rift related volcanic-sedimentary sequence along the southern margin of the Archaean Superior Province. The Agnew Intrusion (50 km2), which is a member of the East Bull Lake suite of layered intrusions, occurs adjacent to the Superior Province - Southern Province boundary in central Ontario, Canada, and provides an opportunity to examine the early tectono-magmatic evolution of a Palaeoproterozoic rifting event. The Agnew Intrusion is a well-exposed, 2100 m thick, layered gabbronoritic to leucogabbronoritic pluton. It was the product of at least four recognizable, but chemically similar, high-Al2O3 and low-TiO2 magma pulses. Structural data, coupled with excellent stratigraphic correlations between the Agnew Intrusion and other East Bull Lake suite layered intrusions, suggest that these plutons are erosional remnants of one or more sill-like bodies that may originally have formed an extensive, subhorizontal mafic sheet. We argue on the basis of field evidence that the early evolution of the Southern Province was characterized by a large, mantle plume induced magmatic event that gave rise to a Palaeoproterozoic continental flood basalt province. However, the incompatible trace element characteristics of the Agnew Intrusion parental magma (i.e., large ion lithophile and light rare earth element enrichment and high field strength element depletion) are more typical of modern subduction-modified subcontinental lithospheric mantle. Given that this is a prevailing geochemical signature of mafic rocks in the Archaean-Palaeoproterozoic, we suggest that there was a fundamental difference in both the composition and structure between the ancient and more modern mantle. "Subduction-like" geochemical signatures may have been imparted to the entire developing mantle during early Earth differentiation.


1960 ◽  
Vol 27 ◽  
pp. 1-145
Author(s):  
B.G.J Upton

An intrusive complex of saturated syenites and gabbros near Ivigtut in S.W. Greenland forms the mountain of Kûngnât Fjeld. The rocks were intruded into the basement gneisses towards the close of the Gardar period, thought to be of Pre-Cambrian age. The complex consists of three steep-sided syenite bodies. These were intruded successively with progressive easterly shift of centre and were succeeded by an alkali gabbro intrusion which, occurring as a ring-dyke, almost entirely surrounds the syenites. Emplacement of each of these intrusions is thought to have been by ring-faulting and cauldron subsidence. The S.W. marginal syenite, regarded as the earliest of the three syenite intrusions, is a small, poorly exposed body. It consists of quartz syenite containing fayalite and aegirine-augite. The second syenite intrusion formed the western layered syenite stock. This is a larger mass thought to have been originally ca. 2.6 X 3.5 kms. It possesses the characteristics of a layered intrusion of Skærgaard type with inwardly directed rhythmic banding, cryptic layering, feldspar lamination and an overall increase in mafic index from top to bottom. The base of the layered rocks is not exposed. The intrusion is divided horizontally, by a raft-like mass of gneiss blocks, into an upper and a lower layered series. This raft, the "grey-zone", is believed to represent a subsided mass of roofing material which sank only a relatively short distance before coming to rest, suspended in the magma chamber. Differentiation by bottom accumulation of fayalite, clinopyroxene, high-temperature alkali feldspars etc. continued independently above and below this raft. In each case it resulted in pronounced fractionation of the magma. In both series the rocks grade up from quartz-free to quartz-bearing types. The ultimate differentiates of the upper layered series have been lost by erosion, but those of the lower series are represented by transgressive soda-granite dykes and sheets. These latter, which remained unconsolidated until very late in the cooling history of the complex, include riebeckite-astrophyllite granites of close affinity to some of the Nigerian examples. The differentiated sequence of the lower layered series is analogous to the larvikite-nordmarkite-ekerite sequence of the Oslo region. The eastern syenite intrusion is also layered in its central part with somewhat higher average dips than in the western intrusion. For the most part it consists of more basic syenites with more magnesian pyroxenes and olivines and more calcic feldspars. However, fractionation in situ again produced quartz syenites of less basic type. The eastern stock possesses a marginal border group on its eastern flanks. An irregular zone of pegmatite surrounds the eastern intrusion and is thought to have been caused by outward diffusion of volatiles and alkali silicates. In the syenites partial analyses indicate a range in feldspar composition from Ab59 Or29 An10·5 Cn1·5 to ca. Ab59 Or37·5 An3·5, (mol. comp.). Optical data show a pyroxene range from augites of ca. Ca42 Mg20 Fe38 through ferroaugites to hedenbergitic types, and with progressive Na enrichment through to aegirine-augites. The olivines range from ca. Fa80-Fa100. Convection, occurring within the main western and eastern syenite magma chambers, is believed to have been responsible for the steep inclination of the layering by promoting marginal deposition of primary precipitate crystals. Evidence for strong magmatic currents is mainly provided by the trough-banding. Consideration of the feldspars suggests that in the two layered intrusions the magma chambers became filled with accumulated crystal mush over. a temperature range between 800-700°C. The behaviour of the trace-elements is broadly similar to that found in the Skærgaard series, except that at Kûngnât Ba and Sr were progressively removed from the magma. Li and Zr are strongly concentrated in the latest fractionates of the western lower layered series. The syenite melts were continuously depleted in F by the bottom accumulation of fluorapatite. The ring-dyke consists of a suite of gabbroic and syeno-gabbroic rocks thought to have been derived by the fractionation of alkali-basalt magma at depth. Some contamination by syenitic material is suspected. In places the ring-dyke rocks suffered strong metasomatism from residual syenitic and granitic liquids. Apart from water, this alteration involved the addition of Li and Rb. Spectrographic analyses of the feldspars from the whole complex showed that there are all gradations from those with severe Rb depletion to those with moderate Rb enrichment. A surprising Ag-Cu content in some of the feldspars is attributed to the presence of submicroscopic sulphide inclusions. The four Kûngnât intrusions were apparently intruded in order of increasing basicity. A possible explanation is that the four magma portions were tapped off from successively deeper levels of an already differentiated parental magma. The Kûngnât complex is probably coeval and comagmatic with the alkaline intrusions at Nunarssuit, Ilímaussaq and Tugtutôq. The development of nepheline syenites in this region of south Greenland is considered to be closely linked to that of the saturated syenites such as those at Kûngnât.


2018 ◽  
Vol 2018 (1) ◽  
pp. 000652-000654
Author(s):  
Saskia Schröder ◽  
Vanessa Stenchly ◽  
Hans-Joachim Quenzer ◽  
Wolfgang Reinert

Abstract New devices for a digital lifestyle like augmented reality (AR) glasses may find their wide spread use only if consumer relevant pricing can be achieved. Low cost RGB-light sources are a key element for AR. assembly productivity for these micro opto-electrical RGB-light sources and a further reduction in their package dimensions. We present our new approach to build miniature RGB-light sources on structured silicon wafers and elaborate the required skill set and our future process infrastructure based on our existing high volume capable optical packaging platform. The platform provides an optical bench with integrated heat spreader and emission windows enabling miniature hermetic housing for laser diodes assemblies on 8″ wafers.


Author(s):  
D. E. Fornwalt ◽  
A. R. Geary ◽  
B. H. Kear

A systematic study has been made of the effects of various heat treatments on the microstructures of several experimental high volume fraction γ’ precipitation hardened nickel-base alloys, after doping with ∼2 w/o Hf so as to improve the stress rupture life and ductility. The most significant microstructural chan§e brought about by prolonged aging at temperatures in the range 1600°-1900°F was the decoration of grain boundaries with precipitate particles.Precipitation along the grain boundaries was first detected by optical microscopy, but it was necessary to use the scanning electron microscope to reveal the details of the precipitate morphology. Figure 1(a) shows the grain boundary precipitates in relief, after partial dissolution of the surrounding γ + γ’ matrix.


Author(s):  
J. Temple Black

Since its introduction by Fernandez-Moran, the diamond knife has gained wide spread usage as a common material for cutting of thin sections of biological and metallic materials into thin films for examination in the transmission electron microscope. With the development of high voltage E.M. and scanning transmission E.M., microtomy applications will become increasingly important in the preparation of specimens. For those who can afford it, the diamond knife will thus continue to be an important tool to accomplish this effort until a cheaper but equally strong and sharp tool is found to replace the diamond, glass not withstanding.In Figs. 1 thru 3, a first attempt was made to examine the edge of a used (β=45°) diamond knife by means of the scanning electron microscope. Because diamond is conductive, first examination was tried without any coating of the diamond. However, the contamination at the edge caused severe charging during imaging. Next, a thin layer of carbon was deposited but charging was still extensive at high magnification - high voltage settings. Finally, the knife was given a light coating of gold-palladium which eliminated the charging and allowed high magnification micrographs to be made with reasonable resolution.


Author(s):  
E. Knapek ◽  
H. Formanek ◽  
G. Lefranc ◽  
I. Dietrich

A few years ago results on cryoprotection of L-valine were reported, where the values of the critical fluence De i.e, the electron exposure which decreases the intensity of the diffraction reflections by a factor e, amounted to the order of 2000 + 1000 e/nm2. In the meantime a discrepancy arose, since several groups published De values between 100 e/nm2 and 1200 e/nm2 /1 - 4/. This disagreement and particularly the wide spread of the results induced us to investigate more thoroughly the behaviour of organic crystals at very low temperatures during electron irradiation.For this purpose large L-valine crystals with homogenuous thickness were deposited on holey carbon films, thin carbon films or Au-coated holey carbon films. These specimens were cooled down to nearly liquid helium temperature in an electron microscope with a superconducting lens system and irradiated with 200 keU-electrons. The progress of radiation damage under different preparation conditions has been observed with series of electron diffraction patterns and direct images of extinction contours.


Author(s):  
M.G. Burke ◽  
M.K. Miller

Interpretation of fine-scale microstructures containing high volume fractions of second phase is complex. In particular, microstructures developed through decomposition within low temperature miscibility gaps may be extremely fine. This paper compares the morphological interpretations of such complex microstructures by the high-resolution techniques of TEM and atom probe field-ion microscopy (APFIM).The Fe-25 at% Be alloy selected for this study was aged within the low temperature miscibility gap to form a <100> aligned two-phase microstructure. This triaxially modulated microstructure is composed of an Fe-rich ferrite phase and a B2-ordered Be-enriched phase. The microstructural characterization through conventional bright-field TEM is inadequate because of the many contributions to image contrast. The ordering reaction which accompanies spinodal decomposition in this alloy permits simplification of the image by the use of the centered dark field technique to image just one phase. A CDF image formed with a B2 superlattice reflection is shown in fig. 1. In this CDF micrograph, the the B2-ordered Be-enriched phase appears as bright regions in the darkly-imaging ferrite. By examining the specimen in a [001] orientation, the <100> nature of the modulations is evident.


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