Tunable micro-structure of dissolving pulp-based cellulose nanofibrils with facile prehydrolysis process

Cellulose ◽  
2021 ◽  
Vol 28 (6) ◽  
pp. 3759-3773
Author(s):  
Yachong Zhu ◽  
Chaojun Wu ◽  
Dongmei Yu ◽  
Qijun Ding ◽  
Ronggang Li
Author(s):  
J. Silcox ◽  
R. H. Wade

Recent work has drawn attention to the possibilities that small angle electron scattering offers as a source of information about the micro-structure of vacuum condensed films. In particular, this serves as a good detector of discontinuities within the films. A review of a kinematical theory describing the small angle scattering from a thin film composed of discrete particles packed close together will be presented. Such a model could be represented by a set of cylinders packed side by side in a two dimensional fluid-like array, the axis of the cylinders being normal to the film and the length of the cylinders becoming the thickness of the film. The Fourier transform of such an array can be regarded as a ring structure around the central beam in the plane of the film with the usual thickness transform in a direction normal to the film. The intensity profile across the ring structure is related to the radial distribution function of the spacing between cylinders.


TAPPI Journal ◽  
2013 ◽  
Vol 12 (11) ◽  
pp. 21-26 ◽  
Author(s):  
CHAO TIAN ◽  
LINQIANG ZHENG ◽  
QINGXIAN MIAO ◽  
CHRIS NASH ◽  
CHUNYU CAO ◽  
...  

The Fock test is widely used for assessing the reactivity of dissolving pulp. The objective of this study was to modify the method to improve the repeatability of the test. Various parameters that affect the repeatability of the Fock test were investigated. The results showed that Fock reactivity is dependent on testing conditions affecting the xanthation between cellulose and carbon disulfide, such as the moisture content of the pulp sample, sodium hydroxide (NaOH) concentration, xanthation temperature, carbon disulfide dosage, and xanthation time. The repeatability of the test was significantly improved using the following modified testing procedure: air dried sample in the constant temperature/humidity room, xanthation temperature of 66°F (19°C) in a water bath, xanthation time of 3 h, NaOH concentration of 9% (w/w), and 1.3 mL carbon disulfide.


TAPPI Journal ◽  
2015 ◽  
Vol 14 (3) ◽  
pp. 167-174 ◽  
Author(s):  
QIANQIAN WANG ◽  
J.Y. ZHU

Mixed office paper (MOP) pulp without deinking with an ash content of 18.1 ± 1.5% was used as raw material to produce nanofiller-paper. The MOP pulp with filler was mechanically fibrillated using a laboratory stone grinder. Scanning electron microscope imaging revealed that the ground filler particles were wrapped by cellulose nanofibrils (CNFs), which substantially improved the incorporation of filler into the CNF matrix. Sheets made of this CNF matrix were densified due to improved bonding. Specific tensile strength and modulus of the nanofiller-paper with 60-min grinding reached 48.4 kN·m/kg and 8.1 MN·m/kg, respectively, approximately 250% and 200% of the respective values of the paper made of unground MOP pulp. Mechanical grinding duration did not affect the thermal stability of the nanofiller-paper.


TAPPI Journal ◽  
2018 ◽  
Vol 17 (03) ◽  
pp. 157-164 ◽  
Author(s):  
Shengdan Wang ◽  
Wenhua Gao ◽  
Kefu Chen ◽  
Jinsong Zeng ◽  
Jun Xu ◽  
...  

Cellulose nanofibrils (CNF) were prepared by cellulase in conjunction with mechanical disintegration from the bleached softwood kraft pulp and labelled by Congo red dye. The labelled CNF were used to investigate the retention and distribution of CNF in paper handsheets. The retention of the labelled CNF was obtained by measuring the absorbance of white water using an ultraviolet-visible spectrophotometer. The results showed that this method for measuring the retention was rapid, feasible, and sensitive, owing to the high correlation coefficient R2 (0.9993) of the standard curve. The labelled CNF showed even distribution in paper handsheets. The colorimetric values of paper handsheets were explored with a residual ink analyzer.


2013 ◽  
Author(s):  
Jirko Kuhnisch ◽  
Jong Seto ◽  
Claudia Lange ◽  
Susanne Schrof ◽  
Sabine Stumpp ◽  
...  

GIS Business ◽  
2020 ◽  
Vol 15 (1) ◽  
pp. 158-165 ◽  
Author(s):  
Dr. Sarvesh PS Rajput

This study reported that the addition of nano-silica enhances the mechanical characteristics of concrete as its compressive, flexural and tensile split strengths are increased. As a comparison mixture to equate it along with nano-modified concrete, ordinary samples of Portland cement (OPC) have been utilized. Herein, upto 6.0 percent of OPC has been substituted by nanosilica. In fact, the introduction of nanosilica improves mechanical and microstructural characteristics of concrete by significantly (28 to 35%). The finding therefore, indicated that partly replacing OPC with up to 5 percent nanosilica increases the mechanical and microstructural properties cured up to ninety days as opposed to the standard OPC mix.


2019 ◽  
Vol 16 (2) ◽  
Author(s):  
Amin Suhadi ◽  
Seodihono

Production technology of metal casting industry in Indonesia needs to be improved, especially in the manufacturing of spare parts and box engine made of gray cast iron which has various wall thick such as dove tale construction. Microstructure of gray cast iron is influenced by cooling rate during casting, chemical composition and melting treatment process (inoculation). The part which has the thinnest thickness has the fastest cooling therefore, the grain boundary is smaller compared to other section. As a result this part has highest hardness and difficult to be machined. This research is conducted to solve this problem by modifying melting and solidification treatment process. The research starting from micro structure analysis, composition and mechanical properties tests on the product, and then conducting modification treatment through Taguchi method approach. Experimental results obtained show that the best level settings to control factors which affect to the uniformity of the microstructure and mechanical properties in gray cast iron is the addition of seed inoculation super ® 75, as much as 0.25% with the method of inoculation material entering into the Transfer Ladle.Teknologi produksi pada industri pengecoran di Indonesia masih membutuhkan perbaikan terutama dalam pembuatan komponen mesin perkakas dan peralatan pabrik yang terbuat dari besi tuang kelabu yang mempunyai variasi ketebalan yang besar seperti konstruksi ekor burung (dove tale). Pada pengecoran, struktur mikro dari besi tuang kelabu sangat dipengaruhi oleh kecepatan pendinginan, komposisi kimia dan proses perlakuan pada logam cair (inokulasi). Bagian yang mempunyai ukuran paling tipis mempunyai kecepatan pendinigan paling tinggi karena itu ukuran butirnya jauh lebih kecil dari bagian lain, akibatnya bagian ini mempunyai kekerasan lebih tinggi dan sulit dilakukan pengerjaan mesin. Penelitian ini bertujuan untuk memperbaiki hal ini yang terjadi pada dove taledengan cara memodifikasi proses perlakuan pada cairan besi dan proses pendinginan. Penelitian dimulai dari analisa struktur mikro, pengujian komposisi kimia, pengujian sifat mekanis pada produk kemudian dilakukan modifikasi menggunakan pendekatan metode statistik Taguchi. Hasil penelitian menunjukkan bahwa pengaturan terbaik yang dapat diperoleh untuk mendapatkan keseragaman struktur mikro dan sifat mekanis pada pengecoran besi tuang kelabu adalah penambahan seed inoculation super ® 75, sebesar 0.25% dengan metode pemasukan inokulasi kedalam Ladle pengangkut logam cair.Keywords: carbon, micro structure, hardness, inoculation


2020 ◽  
Vol 2020 (12) ◽  
pp. 13-17
Author(s):  
Nikolay Proskuryakov ◽  
Uliana Putilova ◽  
Rasul Mamadaliev ◽  
Oleg Teploukhov

The comparative investigation results of AD33 aluminum alloy welded joint quality dependence upon changes in a laser beam motion rate for conditions of hand and automatic laser welding are shown. A micro-structure of a welded joint at the hand and automatic laser welding of the AD33 alloy is investigated.


Tellus ◽  
1956 ◽  
Vol 8 (4) ◽  
pp. 443-444 ◽  
Author(s):  
P. Squires
Keyword(s):  

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