Densities, Viscosities and Derived Properties of n-Pentane or n-Hexane with n-Undecane and n-Dodecane from 288.15 K to 343.15 K

2022 ◽  
Vol 43 (2) ◽  
Author(s):  
Gerhaldy Campos-Gómez ◽  
Gustavo A. Iglesias-Silva
Keyword(s):  
Author(s):  
Michael Withnall ◽  
Edvard Lindelöf ◽  
Ola Engkvist ◽  
Hongming Chen

We introduce Attention and Edge Memory schemes to the existing Message Passing Neural Network framework for graph convolution, and benchmark our approaches against eight different physical-chemical and bioactivity datasets from the literature. We remove the need to introduce <i>a priori</i> knowledge of the task and chemical descriptor calculation by using only fundamental graph-derived properties. Our results consistently perform on-par with other state-of-the-art machine learning approaches, and set a new standard on sparse multi-task virtual screening targets. We also investigate model performance as a function of dataset preprocessing, and make some suggestions regarding hyperparameter selection.


Author(s):  
Paul Cowpertwait ◽  
Valerie Isham ◽  
Christian Onof

A conceptual stochastic model of rainfall is proposed in which storm origins occur in a Poisson process, where each storm has a random lifetime during which rain cell origins occur in a secondary Poisson process. In addition, each cell has a random lifetime during which instantaneous random depths (or ‘pulses’) of rain occur in a further Poisson process. A key motivation behind the model formulation is to account for the variability in rainfall data over small (e.g. 5 min) and larger time intervals. Time-series properties are derived to enable the model to be fitted to aggregated rain gauge data. These properties include moments up to third order, the probability that an interval is dry, and the autocovariance function. To allow for distinct storm types (e.g. convective and stratiform), several processes may be superposed. Using the derived properties, a model consisting of two storm types is fitted to 60 years of 5 min rainfall data taken from a site near Wellington, New Zealand, using sample estimates taken at 5 min, 1 hour, 6 hours and daily levels of aggregation. The model is found to fit moments of the depth distribution up to third order very well at these time scales. Using the fitted model, 5 min series are simulated, and annual maxima are extracted and compared with equivalent values taken from the historical record. A good fit in the extremes is found at both 1 and 24 hour levels of aggregation, although at the 5 min level there is some underestimation of the historical values. Proportions of time intervals with depths below various low thresholds are extracted from the simulated and historical series and compared. A tendency for underestimation of the historical values is evident at some time scales, with a close fit being obtained as the threshold is increased.


2018 ◽  
Vol 15 (16) ◽  
pp. 5221-5236 ◽  
Author(s):  
Thibaut Wagener ◽  
Nicolas Metzl ◽  
Mathieu Caffin ◽  
Jonathan Fin ◽  
Sandra Helias Nunige ◽  
...  

Abstract. The western tropical South Pacific was sampled along a longitudinal 4000 km transect (OUTPACE cruise, 18 February, 3 April 2015) for the measurement of carbonate parameters (total alkalinity and total inorganic carbon) between the Melanesian Archipelago (MA) and the western part of the South Pacific gyre (WGY). This paper reports this new dataset and derived properties: pH on the total scale (pHT) and the CaCO3 saturation state with respect to aragonite (Ωara). We also estimate anthropogenic carbon (CANT) distribution in the water column using the TrOCA method (Tracer combining Oxygen, inorganic Carbon and total Alkalinity). Along the OUTPACE transect a deeper penetration of CANT in the intermediate waters was observed in the MA, whereas highest CANT concentrations were detected in the subsurface waters of the WGY. By combining our OUTPACE dataset with data available in GLODAPv2 (1974–2009), temporal changes in oceanic inorganic carbon were evaluated. An increase of 1.3 to 1.6 µmol kg−1 a−1 for total inorganic carbon in the upper thermocline waters is estimated, whereas CANT increases by 1.1 to 1.2 µmol kg−1 a−1. In the MA intermediate waters (27 kg m−3 <σθ<27.2 kg m−3) an increase of 0.4 µmol kg−1 a−1 CANT is detected. Our results suggest a clear progression of ocean acidification in the western tropical South Pacific with a decrease in the oceanic pHT of up to −0.0027 a−1 and a shoaling of the saturation depth for aragonite of up to 200 m since the pre-industrial period.


2005 ◽  
Vol 5 (5) ◽  
pp. 8507-8646 ◽  
Author(s):  
G. McFiggans ◽  
P. Artaxo ◽  
U. Baltensperger ◽  
H. Coe ◽  
M. C. Facchini ◽  
...  

Abstract. The effects of atmospheric aerosol on climate forcing may be very substantial but are quantified poorly at present; in particular, the effects of aerosols on cloud radiative properties, or the "indirect effects" are credited with the greatest range of uncertainty amongst the known causes of radiative forcing. This manuscript explores the effects that the composition and properties of atmospheric aerosol can have on the activation of droplets in warm clouds, so potentially influencing the magnitude of the indirect effect. The effects of size, composition, mixing state and various derived properties are assessed and a range of these properties provided by atmospheric measurements in a variety of locations is briefly reviewed. The suitability of a range of process-level descriptions to capture these aerosol effects is investigated by assessment of their sensitivities to uncertainties in aerosol properties and by their performance in closure studies. The treatment of these effects within global models is reviewed and suggestions for future investigations are made.


1964 ◽  
Vol 54 (1) ◽  
pp. 19-39
Author(s):  
W. L. Pilant ◽  
L. Knopoff

abstract Two or more dispersed wave trains each with constant amplitude will interfere giving a resultant wave train which is amplitude modulated, if the individual waves have their principal energies in a common frequency band and if the trains arrive with time separations small compared to their total length. The dispersive characteristics of the trains need not be the same. If the component trains are of comparable magnitude, the modulation due to interference becomes significant and a “beat” phenomenon occurs. Multiple trains of dispersed seismic surface waves may occur because of a temporal and/or spatial distribution at the source or because of multipath propagation. Each of these causal mechanisms influences the amplitude and phase spectra of the resultant wave train; derived properties such as phase velocities and amplitude ratios are also influenced. In the case of multipath propagation, wavelength dependent time delays may occur. Two cases of twin earthquakes are analyzed, and the significant features of interference are demonstrated. In one case, estimates are obtained for the amplitude ratio and time delay of the second shock with respect to the first. The interpretation of seismograms and spectra influenced by multiple events is discussed.


2011 ◽  
Vol 270 (1) ◽  
pp. 56-62 ◽  
Author(s):  
Krishna Kumar Kandaswamy ◽  
Kuo-Chen Chou ◽  
Thomas Martinetz ◽  
Steffen Möller ◽  
P.N. Suganthan ◽  
...  

2019 ◽  
Vol 64 (8) ◽  
pp. 3632-3640 ◽  
Author(s):  
Taotao Zhan ◽  
Ying Zhang ◽  
Qi Zhou ◽  
Junshuai Chen ◽  
Xiaopo Wang ◽  
...  

2008 ◽  
Vol 15 (6) ◽  
pp. 987-997 ◽  
Author(s):  
E. I. Nikolopoulos ◽  
A. Kruger ◽  
W. F. Krajewski ◽  
C. R. Williams ◽  
K. S. Gage

Abstract. The authors present results of a comparative analysis of rainfall data from several ground-based instruments. The instruments include two vertically pointing Doppler radars, S-band and X-band, an optical disdrometer, and a tipping-bucket rain gauge. All instruments were collocated at the Iowa City Municipal Airport in Iowa City, Iowa, for a period of several months. The authors used the rainfall data derived from the four instruments to first study the temporal variability and scaling characteristics of rainfall and subsequently assess the instrumental effects on these derived properties. The results revealed obvious correspondence between the ground and remote sensors, which indicates the significance of the instrumental effect on the derived properties.


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