Calibration of reaction parameters for the improvement of thermal stability and crystalline quality of multi-walled carbon nanotubes

2010 ◽  
Vol 45 (3) ◽  
pp. 783-792 ◽  
Author(s):  
Saveria Santangelo ◽  
Giacomo Messina ◽  
Giuliana Faggio ◽  
Maurizio Lanza ◽  
Alessandro Pistone ◽  
...  
Author(s):  
Dhiraj Kumar ◽  
Kalyan Kumar Singh

Laser machining of carbon fibre reinforced polymer composites is a challenging task due to a significant difference between physical and thermal properties of the constituent materials, i.e. polymer matrix and carbon fibres. This results in extended heat-affected zone (HAZ), taper kerf and poor surface finishing. This paper focuses on an investigation, attempting to minimise the divergence in the decomposition temperature of carbon fibres and epoxy resin by adding multi-walled carbon nanotubes in polymer matrix as a secondary reinforcement. High thermal conductivity of multi-walled carbon nanotubes increases the thermal diffusivity of polymer matrix, which in turn reduces the matrix recession. In addition, laser power and scan speed was also considered as an input parameter and their influence on output responses such as HAZ, taper angle and surface roughness has been studied. To analyse the effect of multi-walled carbon nanotubes on the resultant thermal damage, an innovative technique, i.e. scanning acoustic microscopy was used. This technique provides a ply-by-ply damage analysis. C-scans of the top and bottom surface of the machined holes in the composite were also carried out. Further, micrographs of the holes were taken to analyse the quality of the holes using field-emission scanning electron microscope. The obtained results indicated that HAZ, taper angle and surface roughness of holes decreased by ∼30%, ∼47% and ∼43%, respectively, with 1.5 wt% multi-walled carbon nanotubes doped carbon fibre reinforced polymer laminates, when compared with the results obtained from experiments with neat carbon fibre reinforced polymer composite laminates.


2017 ◽  
Vol 54 (1) ◽  
pp. 41-44 ◽  
Author(s):  
Maria Adina Vulcan ◽  
Celina Damian ◽  
Paul Octavian Stanescu ◽  
Eugeniu Vasile ◽  
Razvan Petre ◽  
...  

This paper deals with the synthesis of polyurea and its use as polymer matrix for nanocomposites reinforced with multi-walled carbon nanotubes (MWCNT). Two types of materials were obtained during this research, the first cathegory uses the polyurea as matrix and the second one uses a mixture between epoxy resin and polyurea. The nanocomposites were characterized by Thermogravimetric Analysis (TGA), Dynamic Mechanical Analysis (DMA), Scanning Electron Microscopy (SEM) and Tensile Tests .The elastomeric features of nanocomposites were highlighted by the results which showed low value of Tg. Also higher thermal stability with ~40oC compared with commercial products (M20) were observed, but lower mechanical properties compared to neat polyurea.


2012 ◽  
Vol 97 (8) ◽  
pp. 1405-1414 ◽  
Author(s):  
Zuzana Morávková ◽  
Miroslava Trchová ◽  
Elena Tomšík ◽  
Juraj Čechvala ◽  
Jaroslav Stejskal

2013 ◽  
Vol 28 (1) ◽  
pp. 1-7 ◽  
Author(s):  
Mária Filkusová ◽  
Andrea Fedorková ◽  
Renáta Oriňáková ◽  
Andrej Oriňák ◽  
Zuzana Nováková ◽  
...  

2015 ◽  
Vol 1107 ◽  
pp. 314-319
Author(s):  
Mai Woon Lee ◽  
Muhammad Aniq Shazni Mohammad Haniff ◽  
Au Shih Teh ◽  
Daniel C.S. Bien ◽  
Soo Kien Chen ◽  
...  

In this paper, the effect of nickel (Ni) catalyst on the growth of carbon nanotubes (CNTs) was studied where the CNTs were vertically grown by plasma enhanced chemical vapor deposition (PECVD) method. The growth conditions were fixed at a temperature of 700°C with a pressure of 1000mTorr for 40 minutes with various thicknesses of sputtered Ni catalyst. Experimental results show that high density of CNTs was observed especially towards thicker catalyst layers where larger and taller nanotubes were formed. The growth rate increases by ~0.7 times with increasing catalyst thickness from 4nm to 10nm. The nucleation of the catalyst with various thicknesses was also studied as the absorption of the carbon feedstock is dependent on the initial size of the catalyst island. From the Raman results, we found that only slight variation in the intensity ratio of G-band over D-band as increasing catalyst thicknesses. The minor difference in G/D ratio indicates that the catalyst thickness does not significantly influence the quality of CNTs grown.


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