Organic–Inorganic Composite Material Polyaniline Ce(IV) molybdate: Thermal and Room Temperature Electrical Conductivity Measurement Studies

2011 ◽  
Vol 22 (2) ◽  
pp. 379-385 ◽  
Author(s):  
Zafar Alam ◽  
Zeid A. AL-Othman ◽  
Mu. Naushad ◽  
Syed Ashfaq Nabi
2020 ◽  
Vol 11 (1) ◽  
pp. 7614-7620

For the fabrication of the electrode, the Polyvinyl alcohol/polyaniline composite was prepared by the sol-gel method. The electrical conductivity of the composite was determined on compressed pellets by using a 4-in-line-probe dc electrical conductivity-measuring instrument. The electrical conductivity measurement studies revealed that the composite possessed the electrical conductivity in the range of 10-4 to 10-2 S cm-1, i.e., in the semiconductor region and followed the Arrhenius equation. The thermal stability of the composite material (HCl treated) in terms of dc electrical conductivity retention was studied under isothermal conditions (at 50, 70, 90, 110, 130, and 150 °C) at 15 min intervals. The stability of the material (HCl treated) in terms of electrical conductivity retention was also monitored for five cycles at increasing temperatures with 1 h intervals. The composite material was found thermally and environmentally stable in terms of dc electrical conductivity retention.


2011 ◽  
Vol 10 (04n05) ◽  
pp. 1091-1094 ◽  
Author(s):  
RAM MANOHAR YADAV ◽  
RAJESH KUMAR ◽  
KALPANA AWASTHI ◽  
O. N. SRIVASTAVA

The present work describes the preparation characterization and electrical conductivity measurement of carbon–nitrogen (C–N) nanotubes–PEO composites films. CNNTs–PEO composite films have been prepared by using the solution cast technique and characterized by scanning electron microscope (SEM PHILIPS XL-20). The DC electrical conductivity measurements of the composite films revealed that for PEO film conductivity has been found to be ~ 7.5 × 10-8 Scm-1, and for C–N nanotubes (~ 20 wt.%)–PEO film it was found to be ~6.2 Scm-1 at room temperature. Thus, compared to the PEO film, the conductivity of the C–N nanotubes (~ 20 wt.%)–PEO composite film is eight orders of magnitude higher. The same conductivity of ~ 6.2 Scm-1 for the carbon nanotubes (CNT)–PEO composites comes out at 50 wt.% of CNT in PEO as reported earlier by our group. The conductivity increases with the increase of temperature, confirming the semiconducting nature of the C–N nanotubes–PEO composites.


Author(s):  
Yunfeng Dong ◽  
Morten Stendahl Jellesen ◽  
Rune Juul Christiansen ◽  
Jesper Hovelskov ◽  
Jorgen Sundgren ◽  
...  

2016 ◽  
Vol 697 ◽  
pp. 327-330 ◽  
Author(s):  
Ke Shan ◽  
Xing Min Guo ◽  
Feng Rui Zhai ◽  
Zhong Zhou Yi

Y0.06Sr0.94Ti0.6Fe0.4O3-δ-YSZ composites were prepared by mixing Y, Fe co-doped SrTiO3 (Y0.06Sr0.94Ti0.6Fe0.4O3-δ known as YSTF) and 8 mol% Y2O3 stabilized ZrO2 (YSZ) in different weight fractions. The phase stability, phase compatibility, microstructure and mixed ionic-electronic conductivity of composites were investigated. Phase analysis by XRD showed no clearly detectable secondary phases. The electrical conductivity measurement on the YSTF-YSZ composites showed a drastic decrease in total electrical and ionic conductivities when more than 10 wt% of YSZ was used in the composites. The total electrical conductivity was 0.102 S/cm for Y0.06Sr0.94Ti0.6Fe0.4O3-δ and 0.043 S/cm for YSTF-20YSZ at 700 oC, respectively. The value at 700 oC is approximately 2.4 times higher than that of YSTF-20YSZ. The ionic conductivity of Y0.06Sr0.94Ti0.8Fe0.2O3-δ varies from 0.015S/cm at 700 oC to 0.02 S/cm at 800 oC, respectively. The value at 800°C is approximately 12.5 times higher than YSTF-20YSZ. The ion transference numbers of YSTF-YSZ composites vary from 0.14 to 0.28 at 800 °C.


2017 ◽  
Vol 28 (1) ◽  
pp. 348-355 ◽  
Author(s):  
Khin Khin Tha ◽  
Ulrich Katscher ◽  
Shigeru Yamaguchi ◽  
Christian Stehning ◽  
Shunsuke Terasaka ◽  
...  

2012 ◽  
Vol 109 (1) ◽  
pp. 159-162 ◽  
Author(s):  
Baoan Liu ◽  
Xin Yin ◽  
Minglei Zhao ◽  
Qinghua Zhang ◽  
Mingxia Xu ◽  
...  

1987 ◽  
Vol 22 (6) ◽  
pp. 761-764 ◽  
Author(s):  
S. S. Nabatov ◽  
A. N. Dremin ◽  
S. O. Shubitidze ◽  
V. V. Yakushev

1980 ◽  
Vol 85 (B4) ◽  
pp. 1876 ◽  
Author(s):  
Tsutomu Mashimo ◽  
Ken-Ichi Kondo ◽  
Akira Sawaoka ◽  
Yasuhiko Syono ◽  
Humihiko Takei ◽  
...  

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