PREPARATION OF CARBON–NITROGEN NANOTUBES (CNNTs)–POLY ETHYLENE OXIDE (PEO) COMPOSITES FILMS AND THEIR ELECTRICAL CONDUCTIVITY MEASUREMENT

2011 ◽  
Vol 10 (04n05) ◽  
pp. 1091-1094 ◽  
Author(s):  
RAM MANOHAR YADAV ◽  
RAJESH KUMAR ◽  
KALPANA AWASTHI ◽  
O. N. SRIVASTAVA

The present work describes the preparation characterization and electrical conductivity measurement of carbon–nitrogen (C–N) nanotubes–PEO composites films. CNNTs–PEO composite films have been prepared by using the solution cast technique and characterized by scanning electron microscope (SEM PHILIPS XL-20). The DC electrical conductivity measurements of the composite films revealed that for PEO film conductivity has been found to be ~ 7.5 × 10-8 Scm-1, and for C–N nanotubes (~ 20 wt.%)–PEO film it was found to be ~6.2 Scm-1 at room temperature. Thus, compared to the PEO film, the conductivity of the C–N nanotubes (~ 20 wt.%)–PEO composite film is eight orders of magnitude higher. The same conductivity of ~ 6.2 Scm-1 for the carbon nanotubes (CNT)–PEO composites comes out at 50 wt.% of CNT in PEO as reported earlier by our group. The conductivity increases with the increase of temperature, confirming the semiconducting nature of the C–N nanotubes–PEO composites.

2012 ◽  
Vol 488-489 ◽  
pp. 114-117 ◽  
Author(s):  
M.F. Shukur ◽  
M.F.Z. Kadir ◽  
Z. Ahmad ◽  
R. Ithnin

The polymer electrolytes were prepared using the solution cast technique. The polymer host consisted of chitosan and poly(ethylene oxide) (PEO). Ammonium nitrate (NH4NO3) was added to the blend solution to provide the charge carriers for ionic conduction. The sample containing 40 wt.% NH4NO3 exhibited a conductivity value of 5.83 × 10-4 S cm-1 at 373 K. Conductivity-temperature relationship for all samples obeyed Arrhenius rule and the activation energy of each samples were obtained. The sample containing 40 wt.% NH4NO3 showed the lowest activation energy at 0.29 eV. The conductivity variation for the prepared electrolyte system was explained using the Rice and Roth model. Sample with 40 wt. % NH4NO3 exhibited the highest number density and mobility of charge carriers with values of 1.39 × 1020 cm-3 and 4.60 × 10-6 cm2 V-1 s-1 respectively. The increase in conductivity was attributed to the increase in the number density and mobility of charge carriers.


Author(s):  
Yunfeng Dong ◽  
Morten Stendahl Jellesen ◽  
Rune Juul Christiansen ◽  
Jesper Hovelskov ◽  
Jorgen Sundgren ◽  
...  

2016 ◽  
Vol 697 ◽  
pp. 327-330 ◽  
Author(s):  
Ke Shan ◽  
Xing Min Guo ◽  
Feng Rui Zhai ◽  
Zhong Zhou Yi

Y0.06Sr0.94Ti0.6Fe0.4O3-δ-YSZ composites were prepared by mixing Y, Fe co-doped SrTiO3 (Y0.06Sr0.94Ti0.6Fe0.4O3-δ known as YSTF) and 8 mol% Y2O3 stabilized ZrO2 (YSZ) in different weight fractions. The phase stability, phase compatibility, microstructure and mixed ionic-electronic conductivity of composites were investigated. Phase analysis by XRD showed no clearly detectable secondary phases. The electrical conductivity measurement on the YSTF-YSZ composites showed a drastic decrease in total electrical and ionic conductivities when more than 10 wt% of YSZ was used in the composites. The total electrical conductivity was 0.102 S/cm for Y0.06Sr0.94Ti0.6Fe0.4O3-δ and 0.043 S/cm for YSTF-20YSZ at 700 oC, respectively. The value at 700 oC is approximately 2.4 times higher than that of YSTF-20YSZ. The ionic conductivity of Y0.06Sr0.94Ti0.8Fe0.2O3-δ varies from 0.015S/cm at 700 oC to 0.02 S/cm at 800 oC, respectively. The value at 800°C is approximately 12.5 times higher than YSTF-20YSZ. The ion transference numbers of YSTF-YSZ composites vary from 0.14 to 0.28 at 800 °C.


2017 ◽  
Vol 28 (1) ◽  
pp. 348-355 ◽  
Author(s):  
Khin Khin Tha ◽  
Ulrich Katscher ◽  
Shigeru Yamaguchi ◽  
Christian Stehning ◽  
Shunsuke Terasaka ◽  
...  

2012 ◽  
Vol 109 (1) ◽  
pp. 159-162 ◽  
Author(s):  
Baoan Liu ◽  
Xin Yin ◽  
Minglei Zhao ◽  
Qinghua Zhang ◽  
Mingxia Xu ◽  
...  

1987 ◽  
Vol 22 (6) ◽  
pp. 761-764 ◽  
Author(s):  
S. S. Nabatov ◽  
A. N. Dremin ◽  
S. O. Shubitidze ◽  
V. V. Yakushev

Sign in / Sign up

Export Citation Format

Share Document