Dendrimeric Epoxy Resins Based on Hexachlorocyclotriphosphazene as a Reactive Flame Retardant Polymeric Materials: A Review

Author(s):  
O. Dagdag ◽  
A. El Bachiri ◽  
O. Hamed ◽  
Rajesh Haldhar ◽  
Chandrabhan Verma ◽  
...  
Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1730
Author(s):  
Shaolin Lu ◽  
Yechang Feng ◽  
Peikun Zhang ◽  
Wei Hong ◽  
Yi Chen ◽  
...  

As a novel polymer, polyurethane (PU) has been widely applied in leather, synthetic leather, and textiles due to its excellent overall performance. Nevertheless, conventional PU is flammable and its combustion is accompanied by severe melting and dripping, which then generates hazardous fumes and gases. This defect limits PU applications in various fields, including the leather industry. Hence, the development of environmentally friendly, flame-retardant PU is of great significance both theoretically and practically. Currently, phosphorus-nitrogen (P-N) reactive flame-retardant is a hot topic in the field of flame-retardant PU. Based on this, the preparation and flame-retardant mechanism of flame-retardant PU, as well as the current status of flame-retardant PU in the leather industry were reviewed.


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 540
Author(s):  
Yukyung Kim ◽  
Sanghyuck Lee ◽  
Hyeonseok Yoon

Currently, polymers are competing with metals and ceramics to realize various material characteristics, including mechanical and electrical properties. However, most polymers consist of organic matter, making them vulnerable to flames and high-temperature conditions. In addition, the combustion of polymers consisting of different types of organic matter results in various gaseous hazards. Therefore, to minimize the fire damage, there has been a significant demand for developing polymers that are fire resistant or flame retardant. From this viewpoint, it is crucial to design and synthesize thermally stable polymers that are less likely to decompose into combustible gaseous species under high-temperature conditions. Flame retardants can also be introduced to further reinforce the fire performance of polymers. In this review, the combustion process of organic matter, types of flame retardants, and common flammability testing methods are reviewed. Furthermore, the latest research trends in the use of versatile nanofillers to enhance the fire performance of polymeric materials are discussed with an emphasis on their underlying action, advantages, and disadvantages.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2205
Author(s):  
Qian Li ◽  
Yujie Li ◽  
Yifan Chen ◽  
Qiang Wu ◽  
Siqun Wang

A novel liquid phosphorous-containing flame retardant anhydride (LPFA) with low viscosity was synthesized from 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and methyl tetrahydrophthalic anhydride (MeTHPA) and further cured with bisphenol-A epoxy resin E-51 for the preparation of the flame retardant epoxy resins. Both Fourier transform infrared spectroscopy (FT-IR), mass spectrometry (MS) and nuclear magnetic resonance (NMR) measurements revealed the successful incorporation of DOPO on the molecular chains of MeTHPA through chemical reaction. The oxygen index analysis showed that the LPFA-cured epoxy resin exhibited excellent flame retardant performance, and the corresponding limiting oxygen index (LOI) value could reach 31.2%. The UL-94V-0 rating was achieved for the flame retardant epoxy resin with the phosphorus content of 2.7%. With the addition of LPFA, the impact strength of the cured epoxy resins remained almost unchanged, but the flexural strength gradually increased. Meanwhile, all the epoxy resins showed good thermal stability. The glass transition temperature (Tg) and thermal decomposition temperature (Td) of epoxy resin cured by LPFA decreased slightly compared with that of MeTHPA-cured epoxy resin. Based on such excellent flame retardancy, low viscosity at room temperature and ease of use, LPFA showed potential as an appropriate curing agent in the field of electrical insulation materials.


RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 2756-2766
Author(s):  
Yi Zhang ◽  
Weiwei Yang

In this study, a highly effective flame retardant agent, called polybicyclopentaerythritol phosphate-O-4-imino-p-phenylmethane-4-imino-2-chloro-1,3,5-s-triazine (PEDMCD), has been prepared through a direct polycondensation reaction.


2014 ◽  
Vol 1053 ◽  
pp. 263-267 ◽  
Author(s):  
Xiu Juan Tian

Thermal stability and thermal degradation kinetics of epoxy resins with 2-(Diphenylphosphinyl)-1, 4-benzenediol were investegated by thermogravimetric analysis (TGA) at different heating rates of 5 K/min, 10 K/min, 20 K/min and 40 K/min. The thermal degradation kinetic mechanism and models of the modified epoxy resins were determined by Coast Redfern method.The results showed that epoxy resins modified with the flame retardant had more thermal stability than pure epoxy resin. The solid-state decomposition mechanism of epoxy resin and the modified epoxy resin corresponded to the controlled decelerating ځ˽̈́˰̵̳͂͆ͅ˼˰̴̱̾˰̸̵̈́˰̵̸̳̱̹̽̾̓̽˰̶̳̹̾̈́̿̾̓ͅ˰̶˸ځ˹˰̵̵͇͂˰̃˸́˽ځ˹2/3. The introduction of phosphorus-containing flame retardant reduced thermal degradation rate of epoxy resins in the primary stage, and promote the formation of carbon layer.


2011 ◽  
Vol 197-198 ◽  
pp. 1346-1349 ◽  
Author(s):  
Fa Chao Wu

Bis(2,6,7-trioxa-l-phosphabicyclo[2.2.2]octane-4-methanol) melaminium salt (Melabis) and microcapsules of Melabis with melamine resin shell as flame retardants (FR), respectively, were synthesized. Their structures were characterized by NMR, IR, SEM, TG and element analysis. 20% weight of microcapsules was doped into epoxy resins (EP) to get 28.5 % of LOI and UL 94 V-0. The heat and smoke release of EP containing microcapsules was valued by cone calorimeter.


2021 ◽  
Vol 22 ◽  
pp. 100562
Author(s):  
X. Lu ◽  
M. Yu ◽  
D. Wang ◽  
P. Xiu ◽  
C. Xu ◽  
...  
Keyword(s):  

2021 ◽  
pp. 101018
Author(s):  
Zhongwei Chen ◽  
Yifan Suo ◽  
Yuan Yu ◽  
Tingting Chen ◽  
Changxin Li ◽  
...  

2022 ◽  
Vol 10 (5) ◽  
pp. 1349-1364
Author(s):  
Li Wang ◽  
Rongbai Tong ◽  
Juanli Wang ◽  
Jintao Wan ◽  
Yuhu Li ◽  
...  

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