Thermal kinetics of montmorillonite nanoclay/maleic anhydride-modified polypropylene nanocomposites

2011 ◽  
Vol 109 (1) ◽  
pp. 17-25 ◽  
Author(s):  
Henry Kuo Feng Cheng ◽  
Nanda Gopal Sahoo ◽  
Xuehong Lu ◽  
Lin Li

Studies of the catalytic oxidation of benzene to maleic anhydride and carbon dioxide over vanadia/molybdena catalysts show that the major part of the reaction involves interacting gas and gas-solid processes. The results are consistent with a mechanism in which a benzeneoxygen adduct is formed catalytically, desorbs and then reacts to give maleic anhydride entirely in the gas phase. On the basis of this proposed mechanism, the kinetics of individual reactions have been investigated in some depth. The over-oxidation of maleic anhydride has been found to be not significant under the conditions of reaction. The kinetic relationships governing the homogeneous decomposition of the adduct and the oxidation of the adduct to maleic anhydride and to carbon dioxide have been established. The results show that essentially all of the anhydride originates from mixed gas-solid/gas reaction while substantial amounts of carbon dioxide are produced entirely catalytically.


2004 ◽  
Vol 39 (3) ◽  
pp. 311-317 ◽  
Author(s):  
Luis Rejano ◽  
Antonio de Castro ◽  
Antonio H. Sanchez ◽  
Francisco J. Casado ◽  
Alfredo Montano
Keyword(s):  

2003 ◽  
Vol 107 (43) ◽  
pp. 9249-9249 ◽  
Author(s):  
Evgeni M. Glebov ◽  
Larisa G. Krishtopa ◽  
Victor Stepanov ◽  
Lev N. Krasnoperov

Author(s):  
A. La Magna ◽  
G. Fisicaro ◽  
G. Mannino ◽  
V. Privitera ◽  
G. Piccitto ◽  
...  
Keyword(s):  

2021 ◽  
Author(s):  
Akshay Joshi ◽  
Shyam Sundar Pareek ◽  
R. Mangal ◽  
Narendra Bhojak

2019 ◽  
Vol 42 (3) ◽  
pp. e12991 ◽  
Author(s):  
Zhi Huang ◽  
Quan Zhou ◽  
Wei‐Liang Wu ◽  
Jun Wan ◽  
Ai‐Min Jiang

2014 ◽  
Vol 2014 ◽  
pp. 1-9
Author(s):  
R. K. Koul ◽  
Shivani Suri ◽  
Vishal Singh ◽  
K. K. Bamzai

Synthesis of mixed gadolinium calcium heptamolybdate (GdCaHM) system in silica gel medium using single gel single tube technique has been successfully achieved. The grown crystal exhibits various morphologies, which includes spherulites, multifaceted, and square platelets. The nature of the grown material was established by X-ray diffraction (XRD) studies. Fourier transform infrared spectroscopy (FTIR) study signifies the presence of heptamolybdate (Mo7O24) and water symmetry structure, whereas energy dispersive X-ray analysis (EDAX) establishes the stoichiometric of the grown crystal as GdCaMo7O24·8H2O. The thermal behaviour was studied using the thermoanalytical techniques, which include thermogravimetry (TG), differential thermal analysis (DTA), and differential scanning calorimetry (DSC). Results obtained on the application of TG based models, namely, Horowitz-Metzger, Coats-Redfern, and Piloyan-Novikova, suggest the contracting cylindrical model as the relevant model for the thermal decomposition of the material. The kinetic parameters, namely, the order of reaction (n), activation energy (Ea), frequency factor (Z), and entropy (ΔS*), were also calculated using these three models.


2011 ◽  
Vol 50 (4) ◽  
pp. 665-678 ◽  
Author(s):  
Abdolhosein Fereidoon ◽  
Mahmood Hemmati ◽  
Naser Kordani ◽  
Mohammad Kameli ◽  
Morteza Ghorbanzadeh Ahangari ◽  
...  

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