Biogenic synthesis of ZnO nanoparticles from Parthenium histerophorus extract and its catalytic activity for building bioactive polyhydroquinolines

Author(s):  
Prasad Mane ◽  
Bipin Shinde ◽  
Pankaj Mundada ◽  
Bhausaheb Karale ◽  
Arvind Burungale
2018 ◽  
Vol 1 (4) ◽  
pp. 1467-1475 ◽  
Author(s):  
Lu Xiong ◽  
Xing Zhang ◽  
Yu-Xi Huang ◽  
Wu-Jun Liu ◽  
Ya-Li Chen ◽  
...  

2019 ◽  
Vol 11 (2) ◽  
pp. 119 ◽  
Author(s):  
Aisha Shamim ◽  
Tariq Mahmood ◽  
Monis Bin Abid

Nanoparticles are ultrafine structures with dimensions less than 100 nm. Nanoparticles have diverse applications. There are three important methods of fabrication of nanoparticles namely physical, chemical and biological methods. Physical method is a top down strategy for the fabrication of nanoparticles. It is energy intensive and time consuming. A chemical method is simple, but is expensive and requires expensive chemicals with high purity and also involves hazards of contaminations. Biological synthesis is very simple, cheap and environment friendly, requiring no expensive chemicals, temperature and is time saving. Plants and microorganisms are commonly used in this method. These are available everywhere. In the present work we synthesized Zinc Oxide (ZnO) nanoparticles by biological method using Aspargillus niger and zinc chloride (ZnCl2) as precursors. Biogenic synthesis of metallic nanoparticles by fungi is a safe and economical process because of formation of stable and small sized nanoparticles. Fungal biomass secretes proteins which act as reducing and stabilizing agents. The synthesized nanoparticles were characterized by XRD (X-Ray Diffraction), SEM (Scanning Electron Microscopy), UV-Vis (Ultraviolet, Visible) and EDX (Energy Dispersive X-Ray) techniques. Their size was in nm range and morphology of synthesized ZnO NPs was hexagonal. The ZnO nanoparticles are one of the most versatile materials and are used in cosmetics and in Bioenergy production, as a catalyst and as antibacterial material.


Author(s):  
Sekar Vijayakumar ◽  
Zaira I. González-Sánchez ◽  
Balasubramanian Malaikozhundan ◽  
Kandasamy Saravanakumar ◽  
Mani Divya ◽  
...  

Author(s):  
Thangavelu Krithiga ◽  
Sunitha Salla ◽  
Jayabalan Karthikeyan ◽  
Jagadeesan Aravind Kumar

Aim and Objectives: The focus of the present work is to synthesize ZnO/C composite using dextrose as carbon source by combustion method and study the comparative evaluation on one-pot synthesis of β-acetamido- β-(phenyl) propiophenone over ZnO nanoparticles and ZnO/C composite catalyst. Materials and Methods: The ZnO nanoparticles has been synthesized by sol-gel method using zinc nitrate and NaOH and ZnO/Carbon composites by combustion method using zinc nitrate and dextrose as carbon source. The resulting gel was placed in a preheated muffle furnace at 400o C. The solution boils and ignites with a flame. On cooling highly amorphous powder of ZnO/Carbon composite is obtained. Results: The XRD patterns reveal the hexagonal phase with Wurtzite structure and the nanocrystalline nature of the catalysts. The SEM image of ZnO/C composite showed that it contains spherical particles with an average size of 41 nm. The average particle size of the composite was around 60nm by DLS method. The catalytic activity of the ZnO/Carbon composites has been analyzed by one-pot four-component condensation of benzaldehyde, acetophenone, acetyl chloride and acetonitrile. The feed molar ratio of 1:1 (Bz:AP) and catalyst loading of 30 mol% is found to be the optimal condition for βacetamido ketone conversion over ZnO/carbon composite. Conclusion: The substantial catalytic activity of the synthesized ZnO/C composite materials was tested by one-pot fourcomponent condensation of benzaldehyde (Bz), acetophenone (AP), acetyl chloride (AC) and acetonitrile (AN) which showed a high β-acetamido ketone conversion under the optimized reaction conditions. It has also been found that the catalyst is very stable and reusable.


2013 ◽  
Vol 872 ◽  
pp. 263-270 ◽  
Author(s):  
Elena Yunda ◽  
Anna Yu. Godymchuk ◽  
Natalia I. Kosova ◽  
Denis V. Kuznetsov ◽  
Svetlana Senatova

Toxicant properties of nanoparticles are influenced by their dispersiveness, catalytic activity, aggregation and dissolution properties, which are determined by acid-base properties of the surface. This paper provides the experimental results of the research of surface acid-base characteristics for pH = 2.0...9.0, and takes into account their contribution to aggregative activity of Zn and ZnO nanoparticles in suspensions with pH = 4.0, 6.0, and 8.0. The maximum value of adsorption capacity can be expected in acid medium for Zn nanoparticles, and in base medium for ZnO nanoparticles. This study showed that when the value of pH is different from 6, suspension aggregative stability was strengthened or weakened for Zn and ZnO nanoparticles, respectively. The conclusion concerning the contribution of nanoparticles adsorption activity which is changed by surface acid-base characteristics to aggregative stability of particles of different compounds has been made.


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