scholarly journals Lattice Boltzmann Modeling of Drying of Porous Media Considering Contact Angle Hysteresis

2021 ◽  
Author(s):  
Feifei Qin ◽  
Jianlin Zhao ◽  
Qinjun Kang ◽  
Dominique Derome ◽  
Jan Carmeliet
Keyword(s):  
Contact Angle ◽  
Porous Media ◽  
Lattice Boltzmann ◽  
Phase Distribution ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Contact Radius ◽  
Curved Surfaces ◽  
Hysteresis Model ◽  
Droplet Drying

AbstractDrying of porous media is governed by a combination of evaporation and movement of the liquid phase within the porous structure. Contact angle hysteresis induced by surface roughness is shown to influence multi-phase flows, such as contact line motion of droplet, phase distribution during drainage and coffee ring formed after droplet drying in constant contact radius mode. However, the influence of contact angle hysteresis on liquid drying in porous media is still an unanswered question. Lattice Boltzmann model (LBM) is an advanced numerical approach increasingly used to study phase change problems including drying. In this paper, based on a geometric formulation scheme to prescribe contact angle, we implement a contact angle hysteresis model within the framework of a two-phase pseudopotential LBM. The capability and accuracy of prescribing and automatically measuring contact angles over a large range are tested and validated by simulating droplets sitting on flat and curved surfaces. Afterward, the proposed contact angle hysteresis model is validated by modeling droplet drying on flat and curved surfaces. Then, drying of two connected capillary tubes is studied, considering the influence of different contact angle hysteresis ranges on drying dynamics. Finally, the model is applied to study drying of a dual-porosity porous medium, where phase distribution and drying rate are compared with and without contact angle hysteresis. The proposed model is shown to be capable of dealing with different contact angle hysteresis ranges accurately and of capturing the physical mechanisms during drying in different porous media including flat and curved geometries.

scholarly journals Dependency of Contact Angles on Three-Phase Contact Line: A Review

2021 ◽  
Vol 5 (1) ◽  
pp. 8
Author(s):  
H. Yildirim Erbil
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Contact Radius ◽  
Phase Contact ◽  
Sessile Droplet ◽  
Line Energy ◽  
Three Phase ◽  
Tension Term

The wetted area of a sessile droplet on a practical substrate is limited by the three-phase contact line and characterized by contact angle, contact radius and drop height. Although, contact angles of droplets have been studied for more than two hundred years, there are still some unanswered questions. In the last two decades, it was experimentally proven that the advancing and receding contact angles, and the contact angle hysteresis of rough and chemically heterogeneous surfaces, are determined by interactions of the liquid and the solid at the three-phase contact line alone, and the interfacial area within the contact perimeter is irrelevant. However, confusion and misunderstanding still exist in this field regarding the relationship between contact angle and surface roughness and chemical heterogeneity. An extensive review was published on the debate for the dependence of apparent contact angles on drop contact area or the three-phase contact line in 2014. Following this old review, several new articles were published on the same subject. This article presents a review of the novel articles (mostly published after 2014 to present) on the dependency of contact angles on the three-phase contact line, after a short summary is given for this long-lasting debate. Recently, some improvements have been made; for example, a relationship of the apparent contact angle with the properties of the three-phase line was obtained by replacing the solid–vapor interfacial tension term, γSV, with a string tension term containing the edge energy, γSLV, and curvature of the triple contact line, km, terms. In addition, a novel Gibbsian thermodynamics composite system was developed for a liquid drop resting on a heterogeneous multiphase and also on a homogeneous rough solid substrate at equilibrium conditions, and this approach led to the same conclusions given above. Moreover, some publications on the line energy concept along the three-phase contact line, and on the “modified” Cassie equations were also examined in this review.

LATTICE BOLTZMANN SIMULATIONS OF CONTACT LINE PINNING

2007 ◽  
Vol 18 (04) ◽  
pp. 595-601 ◽  
Author(s):  
XINLI JIA ◽  
J. B. MCLAUGHLIN ◽  
G. AHMADI ◽  
K. KONTOMARIS
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Lattice Boltzmann ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Contact Lines ◽  
Lattice Boltzmann Simulations ◽  
Spatially Periodic ◽  
Contact Line Pinning ◽  
Geometrical Defects

Contact angle hysteresis is caused by contact line pinning by geometrical and/or chemical non-uniformities on a solid surface. For small contact angles, theories have been developed for the pinning of contact angles, and an analogy between geometrical and chemical defects has been established. This paper presents LBM results for the interaction of a contact line with a spatially periodic array of chemical defects. The results are for finite contact angles. Qualitative comparisons with existing theories for chemical defects and experimental results for geometrical defects are made for pinned contact lines.

scholarly journals Biomimetic Approach for the Elaboration of Highly Hydrophobic Surfaces: Study of the Links between Morphology and Wettability

Biomimetics ◽  
2021 ◽  
Vol 6 (2) ◽  
pp. 38
Author(s):  
Quentin Legrand ◽  
Stephane Benayoun ◽  
Stephane Valette
Keyword(s):  
Contact Angle ◽  
Ginkgo Biloba ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Textured Surfaces ◽  
Replication Process ◽  
Wetting Behavior ◽  
Static Contact ◽  
Biomimetic Approach ◽  
Highly Hydrophobic

This investigation of morphology-wetting links was performed using a biomimetic approach. Three natural leaves’ surfaces were studied: two bamboo varieties and Ginkgo Biloba. Multiscale surface topographies were analyzed by SEM observations, FFT, and Gaussian filtering. A PDMS replicating protocol of natural surfaces was proposed in order to study the purely morphological contribution to wetting. High static contact angles, close to 135∘, were measured on PDMS replicated surfaces. Compared to flat PDMS, the increase in static contact angle due to purely morphological contribution was around 20∘. Such an increase in contact angle was obtained despite loss of the nanometric scale during the replication process. Moreover, a significant decrease of the hysteresis contact angle was measured on PDMS replicas. The value of the contact angle hysteresis moved from 40∘ for flat PDMS to less than 10∘ for textured replicated surfaces. The wetting behavior of multiscale textured surfaces was then studied in the frame of the Wenzel and Cassie–Baxter models. Whereas the classical laws made it possible to describe the wetting behavior of the ginkgo biloba replications, a hierarchical model was developed to depict the wetting behavior of both bamboo species.

The Surface Modification with Fluorocarbon Thin Films for the Prevention of Stiction in Mems

1998 ◽  
Vol 518 ◽  
Author(s):  
Sang-Ho Lee ◽  
Myong-Jong Kwon ◽  
Jin-Goo Park ◽  
Yong-Kweon Kim ◽  
Hyung-Jae Shin
Keyword(s):  
Contact Angle ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Fluorocarbon Films ◽  
Perfluorodecanoic Acid ◽  
Large Hysteresis ◽  
Static Contact ◽  
Receding Contact ◽  
Highly Hydrophobic ◽  
Receding Contact Angle

AbstractHighly hydrophobic fluorocarbon films were prepared by the vapor phase (VP) deposition method in a vacuum chamber using both liquid (3M's FC40, FC722) and solid sources (perfluorodecanoic acid (CF3(CF2)8COOH), perfluorododecane (C12F26)) on Al, Si and oxide coated wafers. The highest static contact angles of water were measured on films deposited on aluminum substrate. But relatively lower contact angles were obtained on the films on Si and oxide wafers. The advancing and receding contact angle analysis using a captive drop method showed a large contact angle hysteresis (ΔH) on the VP deposited fluorocarbon films. AFM study showed poor film coverage on the surface with large hysteresis. FTIR-ATR analysis positively revealed the stretching band of CF2 groups on the VP deposited substrates. The thermal stability of films was measured at 150°C in air and nitrogen atmospheres as a function of time. The rapid decrease of contact angles was observed on VP deposited FC and PFDA films in air. However, no decrease of contact angle on them was observed in N2.

Evaporative Particle Deposition on Superhydrophobic Surfaces

2013 ◽  
Author(s):  
Mercy Dicuangco ◽  
Susmita Dash ◽  
Justin A. Weibel ◽  
Suresh V. Garimella
Keyword(s):  
Contact Angle ◽  
Particle Deposition ◽  
Contact Angle Hysteresis ◽  
Droplet Evaporation ◽  
Superhydrophobic Surfaces ◽  
Contact Radius ◽  
Droplet Shape ◽  
Substrate Heating ◽  
Solid Liquid ◽  
Constant Contact Angle

The ability to control the size, shape, and location of particulate deposits is important in patterning, nanowire growth, sorting biological samples, and many other industrial and scientific applications. It is therefore of interest to understand the fundamentals of particle deposition via droplet evaporation. In the present study, we experimentally probe the assembly of particles on superhydrophobic surfaces by the evaporation of sessile water droplets containing suspended latex particles. Superhydrophobic surfaces are known to result in a significant decrease in the solid-liquid contact area of a droplet placed on such a substrate, thereby increasing the droplet contact angle and reducing the contact angle hysteresis. We conduct experiments on superhydrophobic surfaces of different geometric parameters that are maintained at different surface temperatures. The transient droplet shape and wetting behavior during evaporation are analyzed as a function of substrate temperature as well as surface morphology. During the evaporation process, the droplet exhibits a constant contact radius mode, a constant contact angle mode, or a mixed mode in which the contact angle and contact radius change simultaneously. The evaporation time of a droplet can be significantly reduced with substrate heating as compared to room-temperature evaporation. To describe the spatial distribution of the particle residues left on the surfaces, qualitative and quantitative evaluations of the deposits are presented. The results show that droplet evaporation on superhydrophobic surfaces, driven by mass diffusion under isothermal conditions or by substrate heating, suppresses particle deposition at the contact line. This preempts the so-called coffee-ring and allows active control of the location of particle deposition.

Simulation of Spreading Dynamics of a EWOD Droplet With Dynamic Contact Angle and Contact Angle Hysteresis

2009 ◽  
Author(s):  
Fangjun Hong ◽  
Ping Cheng ◽  
Zhen Sun ◽  
Huiying Wu
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Low Voltage ◽  
Contact Angle Hysteresis ◽  
Dynamic Contact Angle ◽  
Dynamic Contact ◽  
Dielectric Surface ◽  
Contact Radius ◽  
Droplet Spreading ◽  
Spreading Dynamics

In this paper, the electrowetting dynamics of a droplet on a dielectric surface was investigated numerically by a mathematical model including dynamic contact angle and contact angle hysteresis. The fluid flow is described by laminar N-S equation, the free surface of the droplet is modeled by the Volume of Fluid (VOF) method, and the electrowetting force is incorporated by exerting an electrical force on the cells at the contact line. The Kilster’s model that can deal with both receding and advancing contact angle is adopted. Numerical results indicate that there is overshooting and oscillation of contact radius in droplet spreading process before it ceases the movement when the excitation voltage is high; while the overshooting is not observed for low voltage. The explanation for the contact line overshooting and some special characteristics of variation of contact radius with time were also conducted.

scholarly journals Amphiphobic Nanostructured Coatings for Industrial Applications

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 787 ◽  
Author(s):  
Federico Veronesi ◽  
Giulio Boveri ◽  
Mariarosa Raimondo
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Photoelectron Spectroscopy ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Friction Reduction ◽  
Hybrid Coatings ◽  
Wetting Behavior ◽  
Wide Range ◽  
Solid Liquid

The search for surfaces with non-wetting behavior towards water and low-surface tension liquids affects a wide range of industries. Surface wetting is regulated by morphological and chemical features interacting with liquid phases under different ambient conditions. Most of the approaches to the fabrication of liquid-repellent surfaces are inspired by living organisms and require the fabrication of hierarchically organized structures, coupled with low surface energy chemical composition. This paper deals with the design of amphiphobic metals (AM) and alloys by deposition of nano-oxides suspensions in alcoholic or aqueous media, coupled with perfluorinated compounds and optional infused lubricant liquids resulting in, respectively, solid–liquid–air and solid–liquid–liquid working interfaces. Nanostructured organic/inorganic hybrid coatings with contact angles against water above 170°, contact angle with n-hexadecane (surface tension γ = 27 mN/m at 20 °C) in the 140–150° range and contact angle hysteresis lower than 5° have been produced. A full characterization of surface chemistry has been undertaken by X-ray photoelectron spectroscopy (XPS) analyses, while field-emission scanning electron microscope (FE-SEM) observations allowed the estimation of coatings thicknesses (300–400 nm) and their morphological features. The durability of fabricated amphiphobic surfaces was also assessed with a wide range of tests that showed their remarkable resistance to chemically aggressive environments, mechanical stresses and ultraviolet (UV) radiation. Moreover, this work analyzes the behavior of amphiphobic surfaces in terms of anti-soiling, snow-repellent and friction-reduction properties—all originated from their non-wetting behavior. The achieved results make AM materials viable solutions to be applied in different sectors answering several and pressing technical needs.

Dynamic contact angles and contact angle hysteresis

1977 ◽  
Vol 62 (2) ◽  
pp. 205-212 ◽  
Author(s):  
Rulon E Johnson ◽  
Robert H Dettre ◽  
Dale A Brandreth
Keyword(s):  
Contact Angle ◽  
Contact Angle Hysteresis ◽  
Dynamic Contact ◽  
Contact Angles
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