An overview of neonicotinoids: biotransformation and biodegradation by microbiological processes

Author(s):  
Charlene S. Anjos ◽  
Rafaely N. Lima ◽  
André L. M. Porto
2019 ◽  
Vol 97 ◽  
pp. 02022
Author(s):  
Viktor Sopov ◽  
Julia Danchenko ◽  
Ekaterina Latorez

Specification of corrosion processes in sewerage networks, the predominant role of microbiological processes in them requires the protection of concrete with materials resistant to specific biogenic sulfuric acid aggression. The effective protective materials, in this case, are those that, in addition to acid-proofing materials, have bactericidal properties. Polymer composite materials (PCM) of cold curing based on modified epoxy-resin, resins with dispersed oxides as fillers are widely used in construction. Unique properties and simple technologies make it possible to use them as injection formulations for repair, restoration and restoration of building structures and structures, waterproofing and facing materials, for impregnating, gluing and coating metal, wooden, brick and concrete building structures and parts. In the reconstruction and restoration of sewerage collectors operating under conditions of exposure to liquid biochemically aggressive media with mineral acids and organic substances, particular attention is paid to the permeability of repair materials. Based on the results of the study, PCM compositions were chosen whose estimated lifetime is about 20 years, ensuring reliable protection of the sewage collectors from corrosion.


2020 ◽  
Vol 18 (Suppl.1) ◽  
pp. 614-618
Author(s):  
N. Penev ◽  
Y. Andreev

The concept of bioeconomics covers all sectors of the economy, including agriculture, which supplies renewable resources: plants, animals, microorganisms and their processed products. The goal is a transition to an economy that is independent of fossil fuels and non-renewable resources. Agriculture and forestry, fisheries and aquaculture, as well as the conversion of biotechnological biomass and biological waste, are central to the multilateral new value chain. The processing industry uses renewable resources in various products, in particular, due to the industrial application of biotechnological and microbiological processes, especially in the chemical industry. This also applies to the food, woodworking, paper, construction, leather, and textile industries, as well as parts of the pharmaceutical and energy industries. Thus, the cyclic system and the storage of reusable waste are also included in the bioeconomic system. The aim of our study is to study the degree of development of sustainable value chains in bioeconomics.


Author(s):  
N. K. Fisher

According to the thermodynamic ladder, microorganisms in groundwater use electron acceptors consistently – for transformation of pollution from the pollution plume edge to its core. However, some researchers come to the conclusion that only methanogenic biotransformation of pollution or reduction of Fe(III) and Mn(IV) from the solid phase can occur in the plume, and due to the kinetic factor microorganisms use electron acceptors from the aqueous phase (O2, NO3- и SO42-) only on the edge of the pollution plume. The purpose of the research was to determine whether microorganisms use Fe(III) and Mn(IV) as acceptors of electrons for hydrocarbons transformation in groundwater in the northern part of the Middle Heilongjiang-Amur River basin aquifer. In the study area, both lenses of petroleum-hydrocarbons (non-aqueous phase liquids) on the surface of groundwater (up to 2.5 m) and high concentrations of dissolved hydrocarbons (up to 1000 mg/l) are noted. Microbiological processes were assessed in situ by the method of geochemical indicators. The most active biogeochemical processes occurred during the spring-summer rise of groundwater level. The seasonal increasing of level led to the entry of Fe(III) and Mn(IV) into the pollution plume and activation of the microbiological processes of its reduction. Microorganisms mostly use electron acceptors from the solid phase – Fe(III) and Mn(IV), but not NO3, SO42 from the aqueous phase. This is confirmed by the close correlation of HCO3- formation and that of Fe(II) and Mn(II) in groundwater (r2 up to 0.93). This says that for the groundwater self-purification the kinetic factor rather than thermodynamic one is decisive; and microorganisms use electron acceptors that are currently available. As a result of microbiological pollution destruction, the content of Fe(II) in groundwater increased up to 100 mg/l, Mn (II) – up to 16 mg/l, which exceeds the natural background 4 and 8 times, respectively. This was also because the regional geochemical background of the study area (Amur River basin) forms Fe and Mn.


Author(s):  
L. Symochko ◽  
О. Hafiiyak ◽  
O. Demyanyuk

The article presents the results of monitoring the area adjacent to the Carpathian Biosphere Reserve for the detection of unauthorized landfills and examines the ecological status of these soils. Four unauthorized landfills of solid waste in Pidhirna, Stanislav, Steryshora, and Feresok tracts with an area of 0.15 to 1.5 ha with a waste accumulation period of 12–22 years and different morphological composition which had a significant impact on the ecological status of the soil have been identified. Bioindication methods have shown changes in the soil microbial cenoses under the direct influence of unauthorized landfills of solid waste, namely increased the number of organotrophic bacteria and micromycetes and decreased number of nitrogen-fixing microorganisms. The highest number of bacteria using nitrogen of organic compounds (25.36–28.61 million CFU/g soil) and micromycetes (51.8–76.8 thousand CFU/g soil) was fixed in the soils in the tract PidhirnaandFeresok with advantage of 1.5–1.7 times and 2.5–3.8 times compared to the soil of the protected area. Increasing the number of pedotrophic and oligotrophic microorganisms and microorganisms that assimilate organic forms of nitrogen, on average, 2.70, 2.84 and 1.48 times has been affected the direction of the main soil-microbiological processes. The coefficient of oligotrophicity varied in the range of 0.21–0.30, mineralization-immobilization one — 1.22–1.38, pedotrophic one — 0.55–0.96 with a maximum in the soil of the landfill in the tracts of Feresok and Pidhirna, which indicates the strengthening of microbiological processes of mineralization and decomposition of soil organic matter, including humus compounds. A close relationship was established between the duration of solid waste storage in a certain area and the level of soil phytotoxicity (r = 0.92). In the soil of landfills in Pidhirna, Steryshora and Feresok tracts, the phytotoxicity index is significant (over 50%), which indicates a high level of soil ecosystem pollution and increased environmental risks in the area of unauthorized accumulation of solid waste.


2021 ◽  
Vol 1 (19) ◽  
pp. 282-284
Author(s):  
A.P. Pustovgar

This paper describes the use of biocatalytic technologies in construction and housing and communal services. Special attention is paid to the use of microbiological processes for the modification of soil bases, concretes and building mortars. The problems and directions of future research in this area are considered.


Limnology ◽  
2019 ◽  
Vol 21 (2) ◽  
pp. 197-205
Author(s):  
Ja Yeong Park ◽  
Shogo Sugahara ◽  
Michiko Egawa ◽  
Yasushi Seike

AbstractHighly concentrated dissolved silicate was detected in pore water from anoxic-reducing sediment in Lake Nakaumi, a brackish lake. Silicate concentration also simultaneously increased with total hydrogen sulfide concentration during the summer. Generally, dissolved silicate is readily adsorbed onto ferric hydroxide and precipitates in an oxidative environment. In this study, we focused on the behavior of ferric hydroxide adsorbing silicate in sediment and determined that hydrogen sulfide was the main cause of dissolved silicate elution from ferric hydroxide adsorbing silicate because the hydrogen sulfide produced via microbiological processes in the anoxic-reducing environment was reducible for other metal oxides. According to laboratory experiments, silicate was released from ferric hydroxide by reacting with sodium sulfide, causing increasing elution of dissolved silicate from anoxic-reducing sediments with increasing concentration of sodium sulfide in the solutions. This result shows that hydrogen sulfide is very crucial for silicate release under a reducing environment. Therefore, in Lake Nakaumi, silicate would be released from the bottom after ferric hydroxide adsorbing silicate reacted with hydrogen sulfide in a summer reductive environment.


1990 ◽  
Vol 171 ◽  
pp. 245-252 ◽  
Author(s):  
M.V. Rekharsky ◽  
O.A. Rodionova ◽  
S.V. Belyaev

1981 ◽  
Vol 8 (1) ◽  
pp. 5-18 ◽  
Author(s):  
Douglas Argyle Campbell

This survey has described the foreseeable environmental and economic impacts of enhanced oil-recovery (EOR) on U.S. oil production between 1980 and 2000. It has indicated that EOR production may be expected to rise from the approximately 4% of total U.S. oil production in 1980, to the projected approximations of 10.5% in 1985, 18.5% in 1990, 23% in 1995, and perhaps 30% in 2000. These percentages are substantial, particularly as this form of oil production has been, up until recently, quite limited. Many of the processes are still in the laboratory stage of development—particularly chemical and microbiological processes. With continued laboratory experimentation and field research, it is possible that the percentages could be even greater than the above suggestions as we reach into the 21st Century.The potential for EOR is very considerable and probably great, as it could involve some two-thirds of all the oil already identified in the United States and assumed to be unrecoverable by primary or secondary means. The U.S. Department of Energy (DOE) has given important incentives to the EOR industry to make such increased production worth while through raising prices to compensate for the cost of equipment, and deducting expenditure on such equipment from a new ‘Windfall Profit Tax’.Along with EOR's economic potential, there are two major ecological dangers: air pollution through thermal processes, and ground-water pollution through chemical processes. It is essential to the well-being of the United States that clean air standards be adhered to, and that the equipment necessary to purify the air (particularly in California) be available and operate to reduce emissions.A great deal more research needs to be undertaken towards developing safeguards to ensure that drinkingwater is not contaminated by dangerous chemicals which may be used in ‘chemical flooding’ of depleted oil-wells. Many of these chemicals have merely ‘come out of the laboratory’ and are sold by chemical companies without sufficient field-testing. How far these chemicals could travel underground must still be determined. It is also important to ensure that carbon dioxide, fed into a geological formation, can be recaptured and re-injected without escaping into the atmosphere, where there is the potential danger of a global ‘greenhouse effect’ upon the world's temperature. Finally, it is important to safeguard the Earth against microbes which could be injected into its geological strata without sufficient knowledge of their impact on the ecology of the Earth. Thus, much environmental research will be called for with these new methods of producing oil for Man's use.This study has reviewed the four major methods of EOR that are currently being utilized or proposed— thermal processes, miscible and semi-miscible processes, chemical processes, and microbiological processes, and found that they could all have ongoing possibilities.Given appropriate environmental safeguards, EOR should become a major force in the production of energy for the United States over the next 20 years, and it seems reasonable to expect that much the same could apply to other parts of the world. However, it is important that safeguarding the environment should guide the DOE in terms of its incentive programmes for specific processes.


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