Investigating the Reliability of SnAgCu Solder Alloys at Elevated Temperatures in Microelectronic Applications

Author(s):  
Mathias Ekpu
Author(s):  
Sri Chaitra Chavali ◽  
Kaushik Mysore ◽  
Ganesh Subbarayan ◽  
Indranath Dutta

Aging affects both microstructure and behavior [1, 2]. Microstructural changes are driven by dislocation motion and diffusion processes. Together they affect the flow behavior in solder alloys. We address four aspects of solder microstructure and behavior as affected by aging (a) EDS studies on Ag dispersion in Sn matrix (b) a procedure for modeling intermetallic particle growth (c) a model for estimating effective viscosity of solder alloy (d) both primary and secondary creep models to predict aging effects on behavior. Solder samples were aged for different aging times (15, 30, 60, 90 days aging) and at different aging temperatures (25 C, 75 C, 125 C) prior to running creep tests. Another set of solder samples were similarly aged to characterize the microstructure. The creep data for the experiments are from a series of sixty four experiments performed using a micromechanical tester that is specially fitted with a sensitive capacitance gauge (with a resolution of 0.1 microns) to accurately measure viscoplastic responses of solder to applied loads.


Author(s):  
D. Bhate ◽  
D. Chan ◽  
G. Subbarayan ◽  
T. C. Chiu ◽  
V. Gupta ◽  
...  

Constitutive models for SnAgCu solder alloys are of great interest at the present. Commonly, constitutive models that have been successfully used in the past for Sn-Pb solders are used to describe the behavior of SnAgCu solder alloys. Two issues in the modeling of lead-free solders demand careful attention: (i) Lead-free solders show significantly different creep strain evolution with time, stress and temperature, and the assumption of evolution to steady state creep nearly instantaneously may not be valid in SnAgCu alloys and (ii) Models derived from bulk sample test data may not be reliable when predicting deformation behavior at the solder interconnection level for lead-free solders due to the differences in the inherent microstructures at these different scales. In addition, the building of valid constitutive models from test data derived from tests on solder joints must deconvolute the effects of joint geometry and its influence on stress heterogeneity. Such issues have often received insufficient attention in prior constitutive modeling efforts. In this study all of the above issues are addressed in developing constitutive models of Sn3.8Ag0.7Cu and Sn1.0Ag0.5Cu solder alloys, which represent the extremes of Ag composition that have been mooted at the present time. The results of monotonic testing are reported for strain rates ranging from 4.02E-6 to 2.40E-3 s−1. The creep behavior at stress levels ranging from 7.8 to 52 MPa are also described. Both types of tests were performed at temperatures of 25°C, 75°C and 125°C. The popular Anand model and the classical time-hardening creep model are fit to the data and the experimentally obtained model parameters are reported. The test data are compared against other reported data in the literature and conclusions are drawn on the plausible sources of error in the data reported in the prior literature.


Author(s):  
Maurice N. Collins ◽  
Jeff Punch ◽  
Richard Coyle ◽  
Michael Reid ◽  
Richard Popowich ◽  
...  

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