Constitutive Behavior of Sn3.8Ag0.7Cu and Sn1.0Ag0.5Cu Alloys at Creep and Low Strain Rate Regimes

Author(s):  
D. Bhate ◽  
D. Chan ◽  
G. Subbarayan ◽  
T. C. Chiu ◽  
V. Gupta ◽  
...  

Constitutive models for SnAgCu solder alloys are of great interest at the present. Commonly, constitutive models that have been successfully used in the past for Sn-Pb solders are used to describe the behavior of SnAgCu solder alloys. Two issues in the modeling of lead-free solders demand careful attention: (i) Lead-free solders show significantly different creep strain evolution with time, stress and temperature, and the assumption of evolution to steady state creep nearly instantaneously may not be valid in SnAgCu alloys and (ii) Models derived from bulk sample test data may not be reliable when predicting deformation behavior at the solder interconnection level for lead-free solders due to the differences in the inherent microstructures at these different scales. In addition, the building of valid constitutive models from test data derived from tests on solder joints must deconvolute the effects of joint geometry and its influence on stress heterogeneity. Such issues have often received insufficient attention in prior constitutive modeling efforts. In this study all of the above issues are addressed in developing constitutive models of Sn3.8Ag0.7Cu and Sn1.0Ag0.5Cu solder alloys, which represent the extremes of Ag composition that have been mooted at the present time. The results of monotonic testing are reported for strain rates ranging from 4.02E-6 to 2.40E-3 s−1. The creep behavior at stress levels ranging from 7.8 to 52 MPa are also described. Both types of tests were performed at temperatures of 25°C, 75°C and 125°C. The popular Anand model and the classical time-hardening creep model are fit to the data and the experimentally obtained model parameters are reported. The test data are compared against other reported data in the literature and conclusions are drawn on the plausible sources of error in the data reported in the prior literature.

2008 ◽  
Vol 62 (3) ◽  
pp. 160-163 ◽  
Author(s):  
Aleksandra Mitovski ◽  
Ljubisa Balanovic ◽  
Dragana Zivkovic ◽  
Sasa Marjanovic ◽  
Bata Marjanovic ◽  
...  

The results of structural and mechanical characteristics of lead-free Cu-Sn based solder alloys, produced in Company "11. mart" AD Srebrenica (Republic of Srpska), are presented in this paper. The results of investigation of samples - alloys CuSnl4, CuSnlFelAlO.5, CuSnlOFelAllMnO.5 and CuA110Fe3Mn produced by different processing methods, include the data obtained by optical microscopy and measurements of hardness, micro hardness and electroconductivity, in order to characterize mentioned alloys and define the influence of processing method applied on their structural and mechanical properties. Microstructural experimental results of samples produced by casting in a metal mould with fast water cooling showed clearly sharp dendritic structure. Samples obtained by casting in a sand mould, displayed structure with big crystals, higher amount of segregation and inclusions on the grain boundaries, as a result of the slow cooling process. Hardness and microhardness tests showed increasing values as the amount of tin raised. Sample 3 showed the lowest value, as a result of the crystallization process and lackness of additional thermal treatment. Experimental results of the electroconductivity test showed that mentioned sample has got the highest value, which can be also explained by its production method. Results presented in this paper can contribute to investigations of copper-tin lead-free alloys, having in mind that various potential lead-free solders still haven't been completely investigated from the aspects of their structural, mechanical and electrical properties.


2016 ◽  
Vol 5 (4) ◽  
pp. 266-274
Author(s):  
Takeharu HAYASHI ◽  
Hirohiko WATANABE ◽  
Masaaki TAKABE ◽  
Yoshinori EBIHARA ◽  
Tatsuhiko ASAI ◽  
...  

2015 ◽  
Vol 830-831 ◽  
pp. 265-269
Author(s):  
Satyanarayan ◽  
K.N. Prabhu

In the present work, the bond strength of Sn-0.7Cu, Sn-0.3Ag-0.7Cu, Sn-2.5Ag-0.5Cu and Sn-3Ag-0.5Cu lead free solders solidified on Cu substrates was experimentally determined. The bond shear test was used to assess the integrity of Sn–Cu and Sn–Ag–Cu lead-free solder alloy drops solidified on smooth and rough Cu substrate surfaces. The increase in the surface roughness of Cu substrates improved the wettability of solders. The wettability was not affected by the Ag content of solders. Solder bonds on smooth surfaces yielded higher shear strength compared to rough surfaces. Fractured surfaces revealed the occurrence of ductile mode of failure on smooth Cu surfaces and a transition ridge on rough Cu surfaces. Though rough Cu substrate improved the wettability of solder alloys, solder bonds were sheared at a lower force leading to decreased shear energy density compared to the smooth Cu surface. A smooth surface finish and the presence of minor amounts of Ag in the alloy improved the integrity of the solder joint. Smoother surface is preferable as it favors failure in the solder matrix.


2010 ◽  
Vol 2010 (1) ◽  
pp. 000314-000318
Author(s):  
Tong Jiang ◽  
Fubin Song ◽  
Chaoran Yang ◽  
S. W. Ricky Lee

The enforcement of environmental legislation is pushing electronic products to take lead-free solder alloys as the substitute of traditional lead-tin solder alloys. Applications of such alloys require a better understanding of their mechanical behaviors. The mechanical properties of the lead-free solders and IMC layers are affected by the thermal aging. The lead-free solder joints on the pads subject to thermal aging test lead to IMC growth and cause corresponding reliability concerns. In this paper, the mechanical properties of the lead-free solders and IMCs were characterized by nanoindentation. Both the Sn-rich phase and Ag3Sn + β-Sn phase in the lead-free solder joint exhibit strain rate depended and aging soften effect. When lead-free solder joints were subject to thermal aging, Young's modulus of the (Cu, Ni)6Sn5 IMC and Cu6Sn5 IMC changed in very small range. While the hardness value decreased with the increasing of the thermal aging time.


Author(s):  
Todd Embree ◽  
Deassy Novita ◽  
Gary Long ◽  
Satish Parupalli

The continual drive toward smaller second level interconnect dimensions, along with the introduction of Halogen-Free circuit board materials and increased process temperatures of Lead-Free solders, have all contributed to a more frequent occurrence of Pad Crater damage in circuit board materials during manufacturing and test processes. This paper addresses the methodology and test data of some common industry methods used to evaluate Pad Crater strength in circuit board materials. Pad Crater test data is highly sensitive to sample design; as a result a discussion of sample design criteria is also included.


2008 ◽  
Vol 62 (3) ◽  
pp. 148-152
Author(s):  
Aleksandra Milosavljevic ◽  
Dragana Zivkovic ◽  
Dragan Manasijevic ◽  
Nadezda Talijan ◽  
Aleksandar Grujic ◽  
...  

Lead-free soldering has become very popular in the world recently, especially in electronics, because of high ecological demands in industry. Some of lead-free solder alloys are already used in electronic industry, but despite that investigations are still going in order to find suitable replacement for Pb-Sn standard solder. In this paper phase equilibria and characterization of Sn-In-Ag alloys in section In:Ag = 7:3 are investigated. The results of phase diagram calculation are obtained by ThermoCalc software, and characteristic temperatures by DSC method. The results of XRD analysis, optical microscopy, microhardness and electrical conductivity are also presented. These results are given in order to contribute the knowledge about lead-free solders, especially Sn-In-Ag solder alloys, which are potential candidates for replacement standard lead solders.


Author(s):  
Bryan Rodgers ◽  
Jeff Punch ◽  
Claire Ryan ◽  
Finbarr Waldron ◽  
Liam Floyd

A comparative evaluation of the leading lead-free solder candidate (95.5Sn3.8Ag0.7Cu) and traditional tin-lead solder (63Sn37Pb) under thermal cycling conditions was carried out. A test vehicle consisting of four daisy chained 10×10 array 0.8mm pitch plastic micro ball grid arrays (microBGA) mounted on an 8-layer FR4 printed wiring board was designed. The board finish was organic solder preservative (OSP) for the lead-free devices and hot air solder levelled (HASL) in the case of the eutectic devices. An event detector was used to monitor the continuity of each daisy chain during accelerated temperature cycling, where the test vehicles were cycled with a ramp rate of approximately 3°C per minute from −40°C to 125°C, with 10-minute dwells and a total cycle time of 2 hours 10 minutes. Results to date plotted using a Weibull distribution indicate that the SnAgCu solder is more reliable under these conditions. Experiments were also carried out on large-scale lead-free solder specimens to determine the parameters required for the Anand viscoplasticity model. The Anand model was then implemented in finite element analysis using ANSYS®, where the submodelling technique was employed to determine the viscoplastic work per thermal cycle for each solder joint along the package diagonal. Schubert’s fatigue life model was used to predict the number of cycles to failure of each joint, although it should be noted that the necessary model parameters for the may need to be calibrated. Results indicate that the joint under the die edge is likely to fail first and that the SnAgCu solder is more fatigue resistant. The numerical predictions underestimate the fatigue life in both cases.


2020 ◽  
Vol 2020 ◽  
pp. 1-25
Author(s):  
Shuai Li ◽  
Xingxing Wang ◽  
Zhongying Liu ◽  
Feng Mao ◽  
Yongtao Jiu ◽  
...  

With the miniaturization of solder joints and deterioration of serving environment, much effort had been taken to improve the properties of Sn-based lead-free solders. And the fabrication of Sn-based lead-free composite solder alloys by the addition of nanoparticles is one of the effective ways to enhance the properties. In this paper, the recent research progress on the Sn-based lead-free composite solder alloys is reviewed by summarizing the relevant results in representative ones of Sn-Ag-Cu (SAC), Sn-Bi, and other multielement lead-free composite solder alloys. Specifically speaking, the effect of the added nanoparticles on the evolution of wettability, microstructure morphology, and mechanical properties of Sn-based lead-free composite solder alloys are summarized. It is hoped that this paper could supply some beneficial suggestions in developing the novel Sn-based lead-free composite solder alloys. Additionally, the existed issues and future development trends in the exploitation of new novel Sn-based lead-free composite solder alloys are proposed.


PAMM ◽  
2002 ◽  
Vol 1 (1) ◽  
pp. 179 ◽  
Author(s):  
V.S. Nguyen ◽  
K.P. Herrmann ◽  
W.H. Müller

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