Efficient removal of methylene blue in aqueous solution by freeze-dried calcium alginate beads

2016 ◽  
Vol 33 (11) ◽  
pp. 3141-3148 ◽  
Author(s):  
Guangxue Liu ◽  
Zonggao Hu ◽  
Rouwen Guan ◽  
Yafei Zhao ◽  
Hongsong Zhang ◽  
...  
F1000Research ◽  
2018 ◽  
Vol 7 ◽  
pp. 54 ◽  
Author(s):  
Christian Valdez ◽  
Yomaira Perengüez ◽  
Bence Mátyás ◽  
María Fernanda Guevara

Cadmium (Cd) is a metal that can negatively interfere with the metabolic systems of living beings. The objective of this work was to evaluate the capacity for cadmium removal in aqueous solutions by immobilized Chlorella sp. in calcium alginate beads. Beads without Chlorella sp. were used as a control. All the treatments were established in triplicate for 80 min, at four concentrations of cadmium (0, 20, 100 and 200 ppm), taking samples of aqueous solution every 10 min, to be read using atomic absorption equipment. The study determined that the treatment of alginate beads with immobilized Chlorella sp. removed 59.67% of cadmium at an initial concentration of 20 ppm, this being the best removal result.


2016 ◽  
Vol 12 (12) ◽  
pp. 5599-5612
Author(s):  
Ushadevi Balasubramani ◽  
Sangeetha Subramaniam ◽  
Liviu Mitu ◽  
Vairam Sundararajan

Activated carbon/Al2O3 nano-composite (ANC) was synthesized by simple pyrolysis after incorporating the aluminium acetate precursor in activated carbon (AC) matrix. The as-synthesized composite was characterized by FT-IR, XRD, BET isotherm, SEM, EDX, and TEM. The size of Al2O3 nanoparticles in carbon matrix was found to be in the range of 10-35 nm. Adsorption characteristics of nano-composite was evaluated using methylene blue dye (MB) by batch and column studies. In batch process, the effect of concentration, temperature and pH were investigated. Batch adsorption study was interpreted with Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (D-R) isotherms. Results showed that adsorption follows Freudlich isotherm model with an adsorption capacity of 116 mg/g at pH 7 at 30 °C and it increases with increase in pH. Kinetic data indicated that the adsorption of dye follows pseudo-second order kinetics model. The negative value of ΔG indicates the spontaneous nature of the adsorption process. For column study the nano-composite was fabricated into Calcium alginate beads (CAB). The performance of CAB was studied with different influent concentrations of MB, pH and bed depth and the results have been interpreted using Thomas and BDST models. The column shows an adsorption capacity of 285.57 mg/g of CAB at pH 7 with bed height of 10 cm and best fitted to BDST model. These outcomes indicate the capability of carbon/Al2O3 nano-composite for dye removal.


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