Effect of SiO2/TiO2 and ZnO Nanoparticle on Cardanol Oil Compatibilized PLA/PBAT Biocomposite Packaging Film

Silicon ◽  
2022 ◽  
Author(s):  
T. Thendral Thiyagu ◽  
G. Gokilakrishnan ◽  
V. C. Uvaraja ◽  
T. Maridurai ◽  
V. R. Arun Prakash
2016 ◽  
Vol 97 (7) ◽  
pp. 2023-2029 ◽  
Author(s):  
Biao Suo ◽  
Huarong Li ◽  
Yuexia Wang ◽  
Zhen Li ◽  
Zhili Pan ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 54
Author(s):  
Yu-Ming Chu ◽  
Hafiz Muhammad Asif Javed ◽  
Muhammad Awais ◽  
Muhammad Ijaz Khan ◽  
Sana Shafqat ◽  
...  

The photocatalytic pretreatment of lignocellulosic biomass to oxidize lignin and increase biomass stability has gained attention during the last few years. Conventional pretreatment methods are limited by the fact that they are expensive, non-renewable and contaminate the anaerobic digestate later on. The present study was focused to develop a metal-derived photocatalyst that can work with visible electromagnetic spectra light and oxidize commercial lignin liquor. During this project the advanced photocatalytic oxidation of lignin was achieved by using a quartz cube tungsten T3 Halogen 100 W lamp with a laboratory manufactured TiO2-ZnO nanoparticle (nanocomposite) in a self-designed apparatus. The products of lignin oxidation were confirmed to be vanillic acid (9.71 ± 0.23 mg/L), ferrulic acid (7.34 ± 0.16 mg/L), benzoic acid (6.12 ± 0.17 mg/L) and p-coumaric acid (3.80 ± 0.13 mg/L). These all products corresponded to 85% of the lignin oxidation products that were detectable, which is significantly more than any previously reported lignin pretreatment with even more intensity. Furthermore, all the pretreatment samples were supplemented in the form of feedstock diluent in uniformly operating continuously stirred tank reactors (CSTRs). The results of pretreatment revealed 85% lignin oxidation and later on these products did not hinder the CSTR performance at any stage. Moreover, the synergistic effects of pretreated lignin diluent were seen that resulted in 39% significant increase in the methane yield of the CSTR with constant operation. Finally, the visible light and nanoparticles alone could not pretreat lignin and when used as diluent, halted and reduced the methane yield by 37% during 4th HRT.


Chemosphere ◽  
2021 ◽  
pp. 130972
Author(s):  
Leila Abolghasemi Fakhri ◽  
Babak Ghanbarzadeh ◽  
Jalal Dehghannya ◽  
Farhang Abbasi ◽  
Said Dadashi

2021 ◽  
pp. 50947
Author(s):  
Yida Liu ◽  
Huie Zhu ◽  
Akira Watanabe ◽  
Shunsuke Yamamoto ◽  
Tokuji Miyashita ◽  
...  

2021 ◽  
Vol 28 (4) ◽  
Author(s):  
Amir Kazemi ◽  
Saied Nouri Khorasani ◽  
Mohammad Dinari ◽  
Shahla Khalili

Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2588
Author(s):  
Mansuri M. Tosif ◽  
Agnieszka Najda ◽  
Aarti Bains ◽  
Grażyna Zawiślak ◽  
Grzegorz Maj ◽  
...  

In recent years, scientists have focused on research to replace petroleum-based components plastics, in an eco-friendly and cost-effective manner, with plant-derived biopolymers offering suitable mechanical properties. Moreover, due to high environmental pollution, global warming, and the foreseen shortage of oil supplies, the quest for the formulation of biobased, non-toxic, biocompatible, and biodegradable polymer films is still emerging. Several biopolymers from varied natural resources such as starch, cellulose, gums, agar, milk, cereal, and legume proteins have been used as eco-friendly packaging materials for the substitute of non-biodegradable petroleum-based plastic-based packaging materials. Among all biopolymers, starch is an edible carbohydrate complex, composed of a linear polymer, amylose, and amylopectin. They have usually been considered as a favorite choice of material for food packaging applications due to their excellent forming ability, low cost, and environmental compatibility. Although the film prepared from bio-polymer materials improves the shelf life of commodities by protecting them against interior and exterior factors, suitable barrier properties are impossible to attain with single polymeric packaging material. Therefore, the properties of edible films can be modified based on the hydrophobic–hydrophilic qualities of biomolecules. Certain chemical modifications of starch have been performed; however, the chemical residues may impart toxicity in the food commodity. Therefore, in such cases, several plant-derived polymeric combinations could be used as an effective binary blend of the polymer to improve the mechanical and barrier properties of packaging film. Recently, scientists have shown their great interest in underutilized plant-derived mucilage to synthesize biodegradable packaging material with desirable properties. Mucilage has a great potential to produce a stable polymeric network that confines starch granules that delay the release of amylose, improving the mechanical property of films. Therefore, the proposed review article is emphasized on the utilization of a blend of source and plant-derived mucilage for the synthesis of biodegradable packaging film. Herein, the synthesis process, characterization, mechanical properties, functional properties, and application of starch and mucilage-based film are discussed in detail.


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