Catalytic gasification of digestate sludge in supercritical water on the pilot plant scale

2017 ◽  
Vol 7 (4) ◽  
pp. 415-424 ◽  
Author(s):  
Nikolaos Boukis ◽  
Elena Hauer ◽  
Sophia Herbig ◽  
Jörg Sauer ◽  
Frédéric Vogel
2011 ◽  
Vol 50 (22) ◽  
pp. 12512-12520 ◽  
Author(s):  
Violeta Vadillo ◽  
M. Belén García-Jarana ◽  
Jezabel Sánchez-Oneto ◽  
Juan R. Portela ◽  
Enrique J. Martínez de la Ossa

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 455
Author(s):  
Nikolaos Boukis ◽  
I. Katharina Stoll

Gasification of organic matter under the conditions of supercritical water (T > 374 °C, p > 221 bar) is an allothermal, continuous flow process suitable to convert materials with high moisture content (<20 wt.% dry matter) into a combustible gas. The gasification of organic matter with water as a solvent offers several benefits, particularly the omission of an energy-intensive drying process. The reactions are fast, and mean residence times inside the reactor are consequently low (less than 5 min). However, there are still various challenges to be met. The combination of high temperature and pressure and the low concentration of organic matter require a robust process design. Additionally, the low value of the feed and the product predestinate the process for decentralized applications, which is a challenge for the economics of an application. The present contribution summarizes the experience gained during more than 10 years of operation of the first dedicated pilot plant for supercritical water gasification of biomass. The emphasis lies on highlighting the challenges in process design. In addition to some fundamental results gained from comparable laboratory plants, selected experimental results of the pilot plant “VERENA” (acronym for the German expression “experimental facility for the energetic exploitation of agricultural matter”) are presented.


2009 ◽  
Vol 166 (2-3) ◽  
pp. 1530-1534 ◽  
Author(s):  
Ane Urtiaga ◽  
Ana Rueda ◽  
Ángela Anglada ◽  
Inmaculada Ortiz

2006 ◽  
Vol 138 (2) ◽  
pp. 363-369 ◽  
Author(s):  
M MALDONADO ◽  
S MALATO ◽  
L PEREZESTRADA ◽  
W GERNJAK ◽  
I OLLER ◽  
...  

2010 ◽  
Vol 73 ◽  
pp. 36-40 ◽  
Author(s):  
Ana Morán ◽  
Rubén Coto ◽  
Javier Belzunce ◽  
Jose Manuel Artímez

<span><span style="font-family: Times New Roman;">Ferritic/Martensitic steels, with chromium contents ranging between 9 and 12%, were introduced into fusion material programs due to their better creep resistance and excellent thermal and nuclear properties compared to austenitic stainless steels. Reduced activation ferritic/martensitic (RAFM) steels are considered promising candidates for the test blanket modules of the future International Thermonuclear Experimental Reactor (ITER), being EUROFER steel is the EU reference material. It is a 9 % Cr RAFM steel which exhibits a tempered martensitic <span style="font-family: Times New Roman;">microstructure and presently allows operation up to 550 </span><span style="font-family: Cambria Math;">⁰</span><span style="font-family: Times New Roman;">C. This paper shows the work carried out</span></span><span style="font-family: Times New Roman;"><span style="font-family: Times New Roman;"> to develop at a pilot plant scale a Reduced Activation Ferritic/Martensitic (RAFM) steel, Asturfer </span><span style="font-family: Times New Roman; font-size: xx-small;"><span style="font-family: Times New Roman; font-size: xx-small;">®</span></span><span style="font-family: Times New Roman;">,</span></span><span style="font-family: Times New Roman;"> with chemical composition and mechanical properties very close to EUROFER steel. </span>


2014 ◽  
Vol 44 ◽  
pp. 278-287 ◽  
Author(s):  
F. Rodríguez-Gómez ◽  
V. Romero-Gil ◽  
J. Bautista-Gallego ◽  
P. García-García ◽  
A. Garrido-Fernández ◽  
...  

2017 ◽  
Vol 140 (4) ◽  
Author(s):  
Hui Jin ◽  
Bin Chen ◽  
Xiao Zhao ◽  
Changqing Cao

Supercritical water gasification (SCWG) is an efficient and clean conversion of biomass due to the unique chemical and physical properties. Anthracene and furfural are the key intermediates in SCWG, and their microscopic reaction mechanism in supercritical water may provide information for reactor optimization and selection of optimal operating condition. Density functional theory (DFT) and reactive empirical force fields (ReaxFF) were combined to investigate the molecular dynamics of catalytic gasification of anthracene and furfural. The simulation results showed that Cu and Ni obviously increased the production of H radicals, therefore the substance SCWG process. Ni catalyst decreased the production of H2 with the residence time of 500 ps while significantly increased CO production and finally increased the syngas production. Ni catalyst was proved to decrease the free carbon production to prohibit the carbon deposition on the surface of active sites; meanwhile, Cu catalyst increased the production of free carbon.


1947 ◽  
Vol 69 (11) ◽  
pp. 2812-2818 ◽  
Author(s):  
F. H. Spedding ◽  
E. I. Fulmer ◽  
T. A. Butler ◽  
E. M. Gladrow ◽  
M. Gobush ◽  
...  

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