scholarly journals Photocurrent density and electrical properties of Bi0.5Na0.5TiO3-BaNi0.5Nb0.5O3 ceramics

Author(s):  
Mingqiang Zhong ◽  
Qin Feng ◽  
Changlai Yuan ◽  
Xiao Liu ◽  
Baohua Zhu ◽  
...  

AbstractIn this work, the (1−x)Bi0.5Na0.5TiO3-xBaNi0.5Nb0.5O3 (BNT-BNN; 0.00 ⩽ x ⩽ 0.20) ceramics were prepared via a high-temperature solid-state method. The crystalline structures, photovoltaic effect, and electrical properties of the ceramics were investigated. According to X-ray diffraction, the system shows a single perovskite structure. The samples show the normal ferroelectric loops. With the increase of BNN content, the remnant polarization (Pr) and coercive field (Ec) decrease gradually. The optical band gap of the samples narrows from 3.10 to 2.27 eV. The conductive species of grains and grain boundaries in the ceramics are ascribed to the double ionized oxygen vacancies. The open-circuit voltage (Voc) of ∼15.7 V and short-circuit current (Jsc) of ∼1450 nA/cm2 are obtained in the 0.95BNT-0.05BNN ceramic under 1 sun illumination (AM1.5G, 100 mW/cm2). A larger Voc of 23 V and a higher Jsc of 5500 nA/cm2 are achieved at the poling field of 60 kV/cm under the same light conditions. The study shows this system has great application prospects in the photovoltaic field.

2013 ◽  
Vol 743-744 ◽  
pp. 920-925
Author(s):  
Hong Zhou Yan ◽  
Jun You Yang ◽  
Shuang Long Feng ◽  
Ming Liu ◽  
Jiang Ying Peng ◽  
...  

TiO2 nanotubes array was fabricated by anodization. Effect of reaction duration on the morphology of TiO2 nanotube arrays was studied detailedly. The structure and morphology of the prepared nanotubes array was characterized by X-ray diffraction and scanning electron microscopy, respectively. The fabricated TiO2 arrays were peeled off and adhered to FTO glass with adhesive (mixture of tetrabutyl titanate and polyethylene glycol), then they were sintered at 450 for photoanode of DSSC. The photovoltaic performance of the prepared sample as the DSSC anode was investigated. An open circuit voltage of 0.69V and a short circuit current density of 7.78mA/cm2 were obtained, and the fill factor and the convert efficiency were 0.517 and 2.78%, respectively.


2007 ◽  
Vol 1031 ◽  
Author(s):  
Christopher Bailey ◽  
Cory Cress ◽  
Ryne Raffaelle ◽  
Seth Hubbard ◽  
William Maurer ◽  
...  

AbstractThe effects of strain within stacked layers of InAs quantum dots (QDs) were investigated. InAs QD test structures with and without strain compensation (SC) were analyzed using atomic force microscopy, transmission electron microscopy, and X-ray diffraction. The affects of strain compensation on test structure morphology and on GaAs-based QD solar cell performance was studied as a function of the thickness of the SC layer. X-ray diffraction analysis of the QD embedded test structures reveals a relationship between the SC thickness and the observed crystalline quality. Air mass zero illuminated current vs. voltage data and spectral responsivity measurements were used for the solar cell comparison. When SC is employed, QD insertion shows a lower open circuit voltage, in reference to a baseline device without QDs, but leads to an enhancement in the short circuit current of the device.


2019 ◽  
Vol 150 (11) ◽  
pp. 1921-1927 ◽  
Author(s):  
Stefan Weber ◽  
Thomas Rath ◽  
Birgit Kunert ◽  
Roland Resel ◽  
Theodoros Dimopoulos ◽  
...  

Abstract In this work, the influence of a partial introduction of bromide (x = 0–0.33) into MA0.75FA0.15PEA0.1Sn(BrxI1−x)3 (MA: methylammonium, FA: formamidinium, PEA: phenylethylammonium) triple cation tin perovskite on the material properties and photovoltaic performance is investigated and characterized. The introduction of bromide shifts the optical band gap of the perovskite films from 1.29 eV for the iodide-based perovskite to 1.50 eV for the perovskite with a bromide content of x = 0.33. X-ray diffraction measurements reveal that the size of the unit cell is also gradually reduced based on the incorporation of bromide. Regarding the photovoltaic performance of the perovskite films, it is shown that already small amounts of bromide (x = 0.08) in the perovskite system increase the open circuit voltage, short circuit current density and fill factor. The maximum power conversion efficiency of 4.63% was obtained with a bromide content of x = 0.25, which can be ascribed to the formation of homogeneous thin films in combination with higher values of the open circuit voltage. Upon introduction of a higher amount of bromide (x = 0.33), the perovskite absorber layers form pinholes, thus reducing the overall device performance. Graphic abstract


2015 ◽  
Vol 08 (05) ◽  
pp. 1550052
Author(s):  
Xiaobo Chen

In this work, we present an investigation of the photovoltaic properties of low-temperature (700°C annealing temperature) prepared P -doped Silicon nanocrystals ( Si   NCs ) in silicon nitride by ammonia sputtering followed by rapid thermal annealing (RTA). We examined how the flow rate of NH3influenced the structural properties of the annealed films by using Raman scattering, grazing incidence X-ray diffraction (GI XRD) and transmission electron microscopy (TEM), it was found that the appropriate flow rate of NH3is 3 sccm. For the sample deposited at the flow rate of 3 sccm, TEM image showed that Si   NCs were formed with a mean size about 3.7 nm and the density of ~ 2.1 × 1012cm-2; X-ray photoelectron spectroscopy (XPS) characterization showed the existence of Si – P bonds, indicating effective P doping; the average absorptance of higher than 65% and a significant amount of photocurrent makes it suitable for photoactive. Moreover, the experimental P -doped Si   NCs : Si3N4/ p - Si heterojunction solar cell has been fabricated, and the device performance was studied. The photovoltaic device fabricated exhibits an open-circuit voltage (VOC) and a short-circuit current density (JSC) of 470 mV and 3.25 mA/cm2, respectively.


Author(s):  
Muneer H. Jadduaa ◽  
Nadir Fadhil Habubi ◽  
Alaa Z. Ckal

—In this study, (CdO) thin film, which was prepared by chemical method and deposited by drop casting technique on glass and silicon substrates have been studied . The structural, optical and chemical analysis were investigated. X-ray diffraction (XRD) measurements reveal that the (CdO) thin film was polycrystalline, cubic structure and there is no trace of the other material. UV-Vis measurements assure that the energy gap of (CdO) thin film was found to be 2.5eV. I-V characterization of the solar cell under illumination at 40mW/cm2 fluence was investigated . The open circuit voltage (Voc) was 4.1V and short-circuit current density (Isc) was 1.44 mA. These measurements show that the fill factor (FF) and the conversion efficiency (η) ,were 36.2% and 6.8% respectively.


Micromachines ◽  
2019 ◽  
Vol 10 (5) ◽  
pp. 302 ◽  
Author(s):  
Sujian You ◽  
Lingling Zhang ◽  
Jinzheng Gui ◽  
Heng Cui ◽  
Shishang Guo

Aligned P(VDF-TrFE) nanofibers are successfully fabricated by advanced electrospinning. The aligned feature of the nanofibers is achieved by using parallel electrodes, which is fabricated by lithography and wet etching, and a rotating drum collector. Scanning electron microscope (SEM) images show that the nanofibers are highly ordered with a smooth surface and uniform diameter. X-ray diffraction (XRD) and Fourier Transform Infrared spectrum (FTIR) tests indicate that the fibers contain high β phase content. The nanogenerator based on aligned P(VDF-TrFE) nanofibers exhibits good electric performance with a maximum output voltage as high as 12 V and peak-peak short circuit current about 150 nA, highlighting the potential application of P(VDF-TrFE) on self-powered and wearable devices.


Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4384
Author(s):  
Sajid Naseem ◽  
Bianca R. Gevers ◽  
Frederick J. W. J. Labuschagné ◽  
Andreas Leuteritz

This work highlights the use of Fe-modified MgAl-layered double hydroxides (LDHs) to replace dye and semiconductor complexes in dye-sensitized solar cells (DSSCs), forming a layered double hydroxide solar cell (LDHSC). For this purpose, a MgAl-LDH and a Fe-modified MgAl LDH were prepared. X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX) spectroscopy were used to analyze the structural properties, morphology, and success of the Fe-modification of the synthesized LDHs. Ultraviolet-visible (UV-Vis) absorption spectroscopy was used to analyze the photoactive behavior of these LDHs and compare it to that of TiO2 and dye-sensitized TiO2. Current-voltage (I–V) solar simulation was used to determine the fill factor (FF), open circuit voltage (VOC), short circuit current (ISC), and efficiency of the LDHSCs. It was shown that the MgFeAl-LDH can act as a simultaneous photoabsorber and charge separator, effectively replacing the dye and semiconductor complex in DSSCs and yielding an efficiency of 1.56%.


2001 ◽  
Vol 668 ◽  
Author(s):  
Akhlesh Gupta ◽  
I. Matulionis ◽  
J. Drayton ◽  
A.D. Compaan

ABSTRACTHigh efficiency CdTe solar cells are typically grown with CdTe thicknesses from 3 to 15 μm, although the thickness required for 90% absorption of the incident irradiation at 800 nm is only ∼1 μm. In this paper, we present the effect of CdTe thickness reduction on the performance of CdS/CdTe solar cells in which both the CdS and CdTe films were grown by sputtering. We produced a series of cells with different CdTe thickness (from 0.5 to 3.0 μm), and held the CdS thickness and back-contact-processing constant. The effect of CdTe thickness reduction on the diffusion of CdS into CdTe was studied using optical absorption and x-ray diffraction techniques. Only slight decreases occur in open-circuit voltage, short-circuit current, and fill factor with decrease in CdTe film thickness to 1.0 μm. Almost 10% efficient cells were obtained with 1 μm CdTe. Below 1 μm, all cell parameters decrease more rapidly, including the red quantum efficiency.


2012 ◽  
Vol 479-481 ◽  
pp. 166-169
Author(s):  
Peng Wang ◽  
Li Bo Fan ◽  
Zhen Hua Zhang ◽  
Yan Lei ◽  
Yan Ge Zhang ◽  
...  

Cubic-like lead sulfide (PbS) films were in situ fabricated on lead (Pb) foil on a large scale by solvothermal method. Ethanol and ethylenediamine were used as the solvent. The films were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), absorption and the Fourier transformation-infrared (FT-IR) spectra. A solar cell was made by the hybrid film of P3HT and cubic-like PbS. The solar cells are photosensitive in a large spectral range (visible and near infrared regions). The cell with the area of 0.20 cm2 without any special treatment has shown the values of open-circuit voltage (Voc) of 250 mV and short circuit current (Jsc) of 0.01 mA/cm2 with the efficiency of 0.01 % and the fill factor (FF) is 0.36 under illumination intensity of 100 mW/cm2.


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